Citation: Min-fang An, You Lv, Hao-jun Xu, Qun Gu, Zong-bao Wang. Structure and Properties of Gel-spun Ultra-high Molecular Weight Polyethylene Fibers with High Gel Solution Concentration[J]. Chinese Journal of Polymer Science, ;2017, 35(4): 524-533. doi: 10.1007/s10118-017-1883-z shu

Structure and Properties of Gel-spun Ultra-high Molecular Weight Polyethylene Fibers with High Gel Solution Concentration

Min-fang An ^a ,
You Lv ^a ,
Hao-jun Xu ^a ,
Qun Gu ^b ,
Zong-bao Wang ^a,,

a.
Ningbo Key Laboratory of Specialty Polymers, Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, China
b.
College of Material Engineering, Ningbo University of Technology, Ningbo 315211, China

Corresponding author: Zong-bao Wang, wangzongbao@nbu.edu.cn
Received Date: 31 July 2016
Revised Date: 30 August 2016
Accepted Date: 22 September 2016

Fund Project: Natural Science Foundation of Ningbo Municipal 2015A610021the National Natural Science Foundation of China 51273210

The gel-spun ultra-high molecular weight polyethylene (UHMWPE) fibers were prepared at the industrial production line with different gel solution concentrations of 15 wt%, 18 wt% and 24 wt%. The difference in ultimate structure and mechanical properties of UHMWPE fibers for different gel solution concentrations were analyzed by tensile testing, differential scanning calorimetry (DSC), wide angle X-ray diffraction (WAXD) and small angle X-ray scattering (SAXS). With the increase of gel solution concentration, the ultimate mechanical properties of UHMWPE fibers were decreased and the crystallization and orientation of UHMWPE fibers became inferior. Besides, both the average shish length ( < L_shish >) and shish misorientation (B_ϕ) of UHMWPE fibers were decreased with the increase of gel solution concentration. In addition, the appropriate increase of spinning temperature led to the further optimization of the ultimate structure and mechanical properties of UHMWPE fibers.
- UHMWPE fibers,
- Gel solution concentration,
- Orientation,
- Crystallization,
- Shish structure
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