Citation: Ji-xing Yang, Li-xia Ren, Yue-sheng Li. Ring-opening Metathesis Polymerization of Cis-5-norbornene-endo-2,3-dicarboxylic Anhydride Derivatives Using the Grubbs Third Generation Catalyst[J]. Chinese Journal of Polymer Science, ;2017, 35(1): 36-45. doi: 10.1007/s10118-017-1873-1 shu

Ring-opening Metathesis Polymerization of Cis-5-norbornene-endo-2,3-dicarboxylic Anhydride Derivatives Using the Grubbs Third Generation Catalyst

School of Materials Science and Engineering and Tianjin Key Laboratory of Composite and Functional Materials, Tianjin University, Tianjin 300072, China

Corresponding author: Li-xia Ren, lxren@tju.edu.cn
Received Date: 12 August 2016
Revised Date: 9 September 2016
Accepted Date: 12 September 2016

Fund Project: the National Natural Science Foundation of China 21234006

A series of cis-5-norbornene-endo-2,3-dicarboxylic anhydride (NDCA, M1) derivatives (M2-M4) with different types of nonpolar substituted groups were synthesized and characterized by ¹H/¹³C-NMR and mass spectrometry (MS). Ring-opening metathesis polymerization (ROMP) of these monomers using the Grubbs third generation catalyst (G3) generated high molecular weight polymers with much improved solubility compared with the NDCA's homopolymer. It was found that the solubility of these polymers increased with increased substituent's steric hindrance. The living polymerization of NDCA derivative containing the bulkiest substituent (M4) catalyzed by G3 in tetrahydrofuran was confirmed by the kinetic studies with low polydispersity indices (PDI) (<1.30). By using sequential ROMP, well-defined diblock copolymers containing anhydride groups were synthesized.
- Living polymerization,
- Ring-opening metathesis polymerization,
- Amphiphilic block copolymer,
- Anhydride group
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