Citation: Xiao Liu, Qian-shi Wei, Li-guo Chai, Jian-jun Zhou, Hong Huo, Da-dong Yan, Shou-ke Yan, Jun Xu, Lin Li. How Temperatures Affect the Number of Dislocations in Polymer Single Crystals[J]. Chinese Journal of Polymer Science, ;2017, 35(1): 78-86. doi: 10.1007/s10118-017-1872-2 shu

How Temperatures Affect the Number of Dislocations in Polymer Single Crystals

Xiao Liu ^a ,
Qian-shi Wei ^b ,
Li-guo Chai ^c ,
Jian-jun Zhou ^a,, ,
Hong Huo ^a ,
Da-dong Yan ^b ,
Shou-ke Yan ^c ,
Jun Xu ^d ,
Lin Li ^a,,

a.
Beijing Key Laboratory of Energy Conversion and Storage Materials, College of Chemistry, Beijing Normal University, Beijing 100875, China
b.
Department of Physics, Beijing Normal University, Beijing 100875, China
c.
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
d.
Advanced Materials Laboratory, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China

Corresponding author: Jian-jun Zhou, pla_zjj@bnu.edu.cn Lin Li, lilinll@bnu.edu.cn
Received Date: 20 June 2016
Revised Date: 5 August 2016
Accepted Date: 15 August 2016

Fund Project: the National Science and Technology Major Project of the Ministry of Science and Technology of China 2013ZX09J13110-11Bthe Fundamental Research Funds for the Central Universities,and the Program for Changjiang Scholars and Innovative Research Team in University.Jun Xu would like to thank the National Natural Science Foundation of China 21374054the National High Technology Research and Development Program of China 2015AA033801the National Natural Science Foundation of China 21434003

The influence of crystallization temperature (T_c) on the number of spiral growths on poly(butylene succinate) (PBS) single crystals, obtained by self-seeding method, was systematically studied. The studies show that the statistical average number of spiral growths formed on the PBS single crystals decays exponentially with respect to the T_c. Inspired by BCF (Bruton, Cabrera and Frank) theory and L-H (Lauritzen and Hoffman) theory, a thermodynamic model has been proposed, in which the origin of spiral growth was treated as a nucleation process. The model suggests that the nucleation rate of spiral growth depends on the inverse square of super-cooling degree, which predicted the density of spiral growth formed on lamellae, and was consistent with the experiments very well.
- Dislocation,
- Spiral growth,
- Single crystal,
- Nucleation
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