Citation: Quan-long Li, Lei Li, Hong-song Wang, Rui Wang, Wei Wang, Yong-jing Jiang, Qian Tian, Jia-ping Liu. The Doubly Thermo-responsive Triblock Copolymer Nanoparticles Prepared through Seeded RAFT Polymerization[J]. Chinese Journal of Polymer Science, ;2017, 35(1): 66-77. doi: 10.1007/s10118-016-1859-4 shu

The Doubly Thermo-responsive Triblock Copolymer Nanoparticles Prepared through Seeded RAFT Polymerization

Quan-long Li ^a,b ,
Lei Li ^a,b ,
Hong-song Wang ^a,b ,
Rui Wang ^a,b ,
Wei Wang ^a,b ,
Yong-jing Jiang ^a,b ,
Qian Tian ^a,b,, ,
Jia-ping Liu ^c,,

a.
State Key Laboratory of High Performance Civil Engineering Materials, Jiangsu Research Institute of Building Science, Nanjing 210008, China
b.
Jiangsu Sobute New Materials Co., Ltd., Nanjing 211103, China
c.
College of Materials Science and Engineering, Southeast University, Nanjing 211189, China

Corresponding author: Qian Tian, tianqian@cnjsjk.cn Jia-ping Liu, liujiaping@cnjsjk.cn
Received Date: 5 June 2016
Revised Date: 14 July 2016
Accepted Date: 15 July 2016

Fund Project: the National Natural Science Foundation of China 51408275the Provincial Science and Technology Cooperation Project of Jiangsu-Guangxi cooperation project BM2014050the National Science Fund for Distinguished Young Scholars 51225801973 Program of China,under the contract 2015CB655105

The doubly thermo-responsive triblock copolymer nanoparticles of polystyrene-block-poly(N-isopropylacrylamide)-block-poly[N,N-(dimethylamino) ethyl methacrylate] (PS-b-PNIPAM-b-PDMAEMA) are successfully prepared through the seeded RAFT polymerization in situ by using the PS-b-PNIPAM-TTC diblock copolymer nanoparticles as the seed. The seeded RAFT polymerization undergoes a pseudo-first-order kinetics procedure, and the molecular weight increases with the monomer conversion linearly. The hydrodynamic diameter (D_h) of the triblock copolymer nanoparticles increases with the extension of the PDMAEMA block. In addition, the double thermo-response behavior of the PS-b-PNIPAM-b-PDMAEMA nanoparticles is detected by turbidity analysis, temperature-dependent ¹H-NMR analysis, and DLS analysis. The seeded RAFT polymerization is believed as a valid method to prepare triblock copolymer nanoparticles containing two thermo-responsive blocks.
- Thermo-responsive,
- Seeded RAFT polymerization,
- Block copolymers
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