Citation: Quan-you Feng, Ye-long Han, Meng-na Yu, Bin Li, Ying Wei, Ling-hai Xie, Wei Huang. A Robust and Soluble Nanopolymer Based on Molecular Grid-based Nanomonomer[J]. Chinese Journal of Polymer Science, ;2017, 35(1): 87-97. doi: 10.1007/s10118-016-1856-7 shu

A Robust and Soluble Nanopolymer Based on Molecular Grid-based Nanomonomer

Quan-you Feng ^a ,
Ye-long Han ^a ,
Meng-na Yu ^a ,
Bin Li ^a ,
Ying Wei ^a ,
Ling-hai Xie ^a,, ,
Wei Huang ^a,b,,

a.
Center for Molecular Systems and Organic Devices(CMSOD), Key Laboratory for Organic Electronics and Information Displays & Institute of Advanced Materials(IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials(SICAM), Nanjing University of Posts & Telecommunications, Nanjing 210023, China
b.
Key Laboratory of Flexible Electronics(KLOFE) & Institute of Advanced Materials(IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials(SICAM), Nanjing Tech University(NanjingTech), Nanjing 211816, China

Corresponding author: Ling-hai Xie, iamlhxie@njupt.edu.cn Wei Huang, iamwhuang@njupt.edu.cn
Received Date: 16 May 2016
Revised Date: 22 June 2016
Accepted Date: 23 June 2016

Fund Project: Open Project from State Key Laboratory of Supramolecular Structure and Materials at Jilin University klssm201612Project funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD) and Nanjing University of Posts and Telecommunications Scientific Foundation (NUPTSF) NY214179Excellent Science and Technology Innovation Team of Jiangsu Higher Education Institutions 2013the National Natural Science Foundation of China 21274064the National Natural Science Funds for Excellent Young Scholar 21322402Synergetic Innovation Center for Organic Electronics and Information Displays,the Natural Science Foundation of Jiangsu Province BK20150834

Shape persistent conformations reduce the complexity of polymer materials. Herein, we propose a concept on the nanopolymer that is a nanoscale polymer chain with the repeat units of nanomonomers. In this article, a soluble organic nanopolymer of wide bandgap semiconductors was synthesized by the Yamamoto polymerization of nanogrid monomer as the repeat units with the rectangle size of ~1.7 nm×1.2 nm. The alkyl side chain substituent at 9-position of fluorenes guarantees the polygrid with excellent solubility. Tetrafluorenes in the conjugation-interrupted backbones of polygrid acts as the active light-emitting centers without obvious green band in the fluorescence spectra of the films after 10 h annealing at 180℃, indicating this nanopolymer exhibits excellent spectral stability. Such soluble nanopolymers will be the fifth-generation of macromolecular materials with a potential character of overall performance improvement.
- Conformation,
- Polyfluorenes,
- Polygirds,
- Nanopolymers,
- Nanomaterials,
- Stability
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