Citation: Bin Cui, Qing-Yun Wu, Lin Gu, Liang Shen, Hai-bin Yu. High Performance Bio-based Polyurethane Elastomers: Effect of Different Soft and Hard Segments[J]. Chinese Journal of Polymer Science, ;2016, 34(7): 901-909. doi: 10.1007/s10118-016-1811-7 shu

High Performance Bio-based Polyurethane Elastomers: Effect of Different Soft and Hard Segments

Bin Cui ^a,c ,
Qing-Yun Wu ^b ,
Lin Gu ^a,, ,
Liang Shen ^c ,
Hai-bin Yu ^a,,

a.
Key Laboratory of Marine Materials and Related Technologies, Key Laboratory of Marine Materials and Protective Technologies of Zhejiang Province, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
b.
Department of Polymer Science and Engineering, Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, China
c.
Department of Polymer and Coating, Jiangxi Science & Technology Normal University, Nanchang 330013, China

Corresponding author: Lin Gu, gulin1985@gmail.com Hai-bin Yu, haibinyu@nimte.ac.cn
Received Date: 29 January 2016
Revised Date: 23 February 2016
Accepted Date: 29 February 2016

Fund Project: Ningbo Natural Science Foundation 2015A610016Ningbo Key Scientific and Technological Project 2014B10023Ningbo Science and Technology Innovation Team 2015B11003Open Project of Key Laboratory of Marine Materials and Related Technologies 2016K07The research is financially supported by the National Natural Science Foundation of China 21404112

In this work, a series of high performance bio-based polyurethanes (bio-PUs) were synthesized from polylactide (PLA)-based diols, different diisocyanates (TDI, MDI, HDI, IPDI) and chain extender 1, 4-butanediol, in which different soft and hard segments are used to adjust their transition temperatures and mechanical properties. Poly(lactide-co-caprolactone) copolymer diols (co-PLAols) instead of PLA diols as the soft segment improved the thermal stability and mechanical properties of the synthesized bio-PUs. Among them, MDI-based bio-PUs have the highest T_g (43.8℃), tensile strength (23.5 MPa) and modulus (380.8 MPa), while HDI-based bio-PUs have the lowest T_g (21.4℃) and highest elongation at break (580%). Especially, the bio-PUs synthesized from co-PLAols and MDI demonstrate better mechanical properties, closed to petroleum-based commodities. Furthermore, the obtained bio-PUs display good shape memory properties at body temperature and cytocompatibility. Therefore, these bio-PUs are promising for applications in biomedical fields.
- Polylactide diols,
- Bio-based polyurethane,
- Shape memory,
- Biocompatibility
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