Citation: Zhao Li, Hai-bin Sun, Cong-yi Li, Yong-lai Lu, Wang Qiao, Nan-ying Ning, Li-qun Zhang, Ming Tian. Dispersion and Filler Network Structure of Fibrillar Silicates in Elastomers[J]. Chinese Journal of Polymer Science, ;2016, 34(7): 858-872. doi: 10.1007/s10118-016-1801-9 shu

Dispersion and Filler Network Structure of Fibrillar Silicates in Elastomers

Zhao Li ^b ,
Hai-bin Sun ^a ,
Cong-yi Li ^d ,
Yong-lai Lu ^a ,
Wang Qiao ^c ,
Nan-ying Ning ^a,, ,
Li-qun Zhang ^a ,
Ming Tian ^a,,

a.
State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China
b.
Aeolus Tyre Co., Ltd, Henan 454003, China
c.
Office of Scientific Research and Development, Beijing University of Chemical Technology, Beijing 100029, China
d.
PetroChina Sichuan Petrochemical Co. Ltd, Chengdu 611000, China

Corresponding author: Nan-ying Ning, ningny@mail.buct.edu.cn Ming Tian, tian71402@126.com
Received Date: 16 January 2016
Revised Date: 19 February 2016
Accepted Date: 28 February 2016

Fund Project: This work was financially supported by the National Science Fund for Distinguished Young Scholars of China 51525301the National Basic Research Program of China 2015CB654704the National Natural Science Foundation of China 51373012

The dispersion and filler network of fibrillar silicate (FS) in elastomers were studied. The results showed that a good dispersion of FS in matrix during mechanical blending in unvulcanized composites contributed to a strong FS filler network, different from that of traditional reinforcing fillers. Meanwhile, the filler re-aggregation during vulcanization caused by the overlapping and intertwining of FS further strengthened the filler network. The factors including Mooney viscosity and molecular polarity of elastomer, type and amount of silane coupling agents used for filler modification, that may influence the filler network, were studied. Our study helps us to understand the mechanism for the formation of filler network of FS in elastomers and provides guidance for the preparation of high performance FS/elastomer composites.
- Fibrillar silicates,
- Dispersion,
- Filler network,
- Elastomers
1. [1]
  Podsiadlo, P., Kaushik, A.K., Arruda, E.M., Waas, A.M., Shim, B.S., Xu, J., Nandivada, H., Pumplin, B.G., Lahann, J. and Ramamoorthy, A., Science, 2007, 318(5847): 80
2. [2]
  Ramanathan, T., Abdala, A., Stankovich, S., Dikin, D., Herrera-Alonso, M., Piner, R., Adamson, D., Schniepp, H., Chen, X. and Ruoff, R., Nature Nanotechnol., 2008, 3(6): 327
3. [3]
  Zou, H., Wu, S. and Shen, J., Chem. Rev, 2008, 108(9): 3893
4. [4]
  Lorenz, H., Fritzsche, J., Das, A., Stöckelhuber, K., Jurk, R., Heinrich, G. and Klüppel, M., Compos. Sci. Technol., 2009, 69(13): 2135
5. [5]
  Noguchi, T., Magario, A., Fukazawa, S., Shimizu, S., Beppu, J. and Seki, M., Mater. Trans., 2004, 45(2): 602
6. [6]
  Spitalsky, Z., Tasis, D., Papagelis, K. and Galiotis, C., Prog. Polym. Sci., 2010, 35(3): 357
7. [7]
  Ozbas, B., O'Neill, C.D., Register, R.A., Aksay, I.A., Prud'homme, R.K. and Adamson, D.H., J. Polym. Sci., Part B: Polym. Phys., 2012, 50(13): 910
8. [8]
  Chen, Z. and Lu, H., J. Mater. Chem., 2012, 22(25): 12479
9. [9]
  Liu, L., Qi, Z. and Zhu, X., J. Appl. Polym. Sci., 1999, 71(7): 1133
10. [10]
  Tian, M., Liang, W., Rao, G., Zhang, L. and Guo, C., Compos. Sci. Technol., 2005, 65(7): 1129
11. [11]
  Wang, L. and Sheng, J., Polymer, 2005, 46(16): 6243
12. [12]
  Murray, H.H., Appl. Clay Sci., 2000, 17(5): 207
13. [13]
  Yan, S., "Clay miner", Beijing Publisher, Beijing, 1981
14. [14]
  Xu, W. and He, P., J. Appl. Polym. Sci., 2001, 80(2): 304
15. [15]
  Gao, J., Zhang, Q., Wang, K., Fu, Q., Chen, Y., Chen, H., Huang, H. and Rego, J.M., Composites Part A: Appl. Sci. Manufact., 2012, 43(4): 562
16. [16]
  Tian, M., Qu, C., Feng, Y. and Zhang, L., J. Mater. Sci., 2003, 38(24): 4917
17. [17]
  Tian, M., Zhang, X., Zhang, L., Yin, S., Nishi, T. and Ning, N., Compos. Sci. Technol., 2013, 79: 21
18. [18]
  Payne, A.R., J. Appl. Polym. Sci., 1962, 6(19): 57
19. [19]
  Jeffery, G.B., "In proceedings of the royal society of london a: mathematical, physical and engineering sciencesed.", Vol. 102, The Royal Society, 1922, p.161
20. [20]
  Lin, C.J., Hergenrother, W., Alexanian, E. and Bohm, G., Rubber Chem. Technol., 2002, 75(5): 865
21. [21]
  Caravajal, G.S., Leyden, D.E., Quinting, G.R. and Maciel, G.E., Anal. Chem., 1988, 60(17): 1776
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