Citation: Hong Yao, Jia-li Niu, Jie Zhang, Nan-ying Ning, Xiao-qiu Yang, Ming Tian, Xiao-li Sun, Li-qun Zhang, Shou-ke Yan. Morphologies and Mechanical Properties of Cis-1,4-butadiene Rubber/Polyethylene Blends[J]. Chinese Journal of Polymer Science, ;2016, 34(7): 820-829. doi: 10.1007/s10118-016-1794-4 shu

Morphologies and Mechanical Properties of Cis-1,4-butadiene Rubber/Polyethylene Blends

a.
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
b.
Beijing National Laboratory for Molecular Sciences, Department of Polymer Science and Engineering & the Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
c.
Basic Research Service, MOST, Beijing 100862, China

Corresponding author: Ming Tian, tianm@mail.buct.edu.cn Shou-ke Yan, skyan@mail.buct.edu.cn
Received Date: 2 January 2016
Revised Date: 16 February 2016
Accepted Date: 16 February 2016

Fund Project: the National Natural Science Foundation of China 51221002the National Natural Science Foundation of China 21174014

The mechanical properties and phase morphologies of cis-1,4-butadiene rubber (BR) blended with polyethylene (PE) at different blend ratios were studied. The tensile test results show that the PE exhibits excellent reinforcing capabilities towards BR. Blending BR with PE results in a remarkable enhancement of tensile strength, modulus and the elongation at break simultaneously. An increment of tensile strength from 1.11 MPa to 16.26 MPa was achieved by incorporation of 40 wt% PE in the blends. The modulus and elongation at break of 40/60 PE/BR blends are also about 5 times higher than those of the pure BR treated under exactly the same conditions. The tear test indicates that the tear strength also increases with the increase of PE content. It reaches 58.38 MPa for the 40/60 PE/BR blend, which is approximately 10 times higher than that of the pure BR. Morphological study demonstrates that the PE forms elongated microdomains finely dispersed in the BR matrix when its content is over 30 wt%, which corresponds to the remarkably enhanced mechanical properties. According to the results, reinforcement mechanism of PE toward BR dependent on the microstructure has been discussed and two different mechanisms have been proposed.
- Polyethylene,
- Cis-1,4-butadiene rubber,
- Blend,
- Mechanical property,
- Morphology
1. [1]
  Ghosh, P., Chattopadhyay, B. and Sen, A.K., Polymer, 1994, 35(18): 3958
2. [2]
  Li, Y.J., Oono, Y., Kadowaki, Y.J., Inoue, T., Nakayama, K. and Shimizu, H., Macromolecules, 2006, 39: 4195
3. [3]
  Antunes, C.F., Machado, A.V. and van Duin, M., Eur. Polym. J., 2011, 47: 1447
4. [4]
  George, S., Ramamurthy, K., Anand, J.S., Groeninckx, G., Varughese, K.T. and Thomas, S., Polymer, 1999, 40: 4325
5. [5]
  George, J., Varughese, K.T. and Thomas, S., Polymer, 2000, 41: 1507
6. [6]
  Muraki, T. and Tajima, M., 1989, Eur. Pat., 324554 A1
7. [7]
  Mukai, U., 2000, U.S. Pat., 6028143A
8. [8]
  Buonerba, A., Cuomo, C., Speranza, V. and Grassi, A., Macromolecules, 2010, 43: 367
9. [9]
  Kumar, S., Rath, T., Mahaling, R.N., Das, C.K., Srivastava, R.B. and Yadaw, S.B., Polym. Compos., 2009, 30(5): 655
10. [10]
  Maiti, M., Jasra, R.V., Kusum, S.K. and Chaki, T.K., Ind. Eng. Chem. Res., 2012, 51(32): 10607
11. [11]
  Zou, Z., Sun, Z. and An, L., Chinese J. Polym. Sci., 2014, 32(3): 255
12. [12]
  Guo, K., Xiang, S., Sun, J. and Meng, C., Chinese J. Polym. Sci., 2014, 32(3): 315
13. [13]
  Kar, S. and Greenfield, M.L., Polymer, 2015, 62: 129
14. [14]
  Liu, W., Dong, X., Zou, F.S., Yang, J., Wang, D.J. and Han, C.C., Polymer, 2014, 55: 2744
15. [15]
  Rath, S.K., Aswal, V.K., Sharma, C., Joshi, K., Patri, M., Harikrishnan, G. and Khakhar, D.V., Polymer, 2014, 55: 5198
16. [16]
  Zhang, Y., Mark, J.E., Zhu, Y.W., Ruoff, R.S. and Schaefer, D.W., Polymer, 2014, 55: 5389
17. [17]
  Yao, H., Liu, J., Zhang, L. and Yan, S., Chinese J. Polym. Sci., 2015, 33(3): 386
18. [18]
  Gent, A.N. and Zhang, L.Q., J. Polym. Sci., Part B: Polym. Phys., 2001, 39: 811
19. [19]
  Liu, J., Wu, S., Zhang, L., Wang, W. and Cao, D., Phys. Chem. Chem. Phys., 2011, 13: 518
20. [20]
  Wang, Z., Liu, J., Wu, S., Wang, W. and Zhang, L., Phys. Chem. Chem. Phys., 2010, 12: 3014
21. [21]
  Minke, R. and Blackwell, J.J., Macromol. Sci., Phys.,1980, B18: 233
22. [22]
  Kausch, H.H., “Polymer fracture”, Springer-Verlag: Berlin, Heidelberg, New York, 1978
1. [1]
  Min Chen , Boyu Peng , Xuyun Guo , Ye Zhu , Hanying Li . Polyethylene interfacial dielectric layer for organic semiconductor single crystal based field-effect transistors. Chinese Chemical Letters, 2024, 35(4): 109051-. doi: 10.1016/j.cclet.2023.109051
2. [2]
  Feng Zheng , Ruxun Yuan , Xiaogang Wang . “Research-Oriented” Comprehensive Experimental Design in Polymer Chemistry: the Case of Polyimide Aerogels. University Chemistry, 2024, 39(10): 210-218. doi: 10.12461/PKU.DXHX202404027
3. [3]
  Zhongjie Li , Xiangyue Kong , Yuhao Liu , Huayu Qiu , Lingling Zhan , Shouchun Yin . Progress of additives for morphology control in organic photovoltaics. Chinese Chemical Letters, 2024, 35(6): 109378-. doi: 10.1016/j.cclet.2023.109378
4. [4]
  Kai Han , Guohui Dong , Ishaaq Saeed , Tingting Dong , Chenyang Xiao . Morphology and photocatalytic tetracycline degradation of g-C3N4 optimized by the coal gangue. Chinese Journal of Structural Chemistry, 2024, 43(2): 100208-100208. doi: 10.1016/j.cjsc.2023.100208
5. [5]
  Xin Lu , Haoran Sun , Xiaomeng Li , Chunrui Li , Jinfeng Wang , Dandan Zhou . C14-HSL limits the mycelial morphology of pathogen Trichosporon cells but enhances their aggregation: Mechanisms and implications. Chinese Chemical Letters, 2024, 35(6): 108936-. doi: 10.1016/j.cclet.2023.108936
6. [6]
  Qiang Cao , Xue-Feng Cheng , Jia Wang , Chang Zhou , Liu-Jun Yang , Guan Wang , Dong-Yun Chen , Jing-Hui He , Jian-Mei Lu . Graphene from microwave-initiated upcycling of waste polyethylene for electrocatalytic reduction of chloramphenicol. Chinese Chemical Letters, 2024, 35(4): 108759-. doi: 10.1016/j.cclet.2023.108759
7. [7]
  Xiaxia Xing , Xiaoyu Chen , Zhenxu Li , Xinhua Zhao , Yingying Tian , Xiaoyan Lang , Dachi Yang . Polyethylene imine functionalized porous carbon framework for selective nitrogen dioxide sensing with smartphone communication. Chinese Chemical Letters, 2024, 35(9): 109230-. doi: 10.1016/j.cclet.2023.109230
8. [8]
  Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444
9. [9]
  Pei Cao , Yilan Wang , Lejian Yu , Miao Wang , Liming Zhao , Xu Hou . Dynamic asymmetric mechanical responsive carbon nanotube fiber for ionic logic gate. Chinese Chemical Letters, 2024, 35(6): 109421-. doi: 10.1016/j.cclet.2023.109421
10. [10]
  Zhijia Zhang , Shihao Sun , Yuefang Chen , Yanhao Wei , Mengmeng Zhang , Chunsheng Li , Yan Sun , Shaofei Zhang , Yong Jiang . Epitaxial growth of Cu_2-xSe on Cu (220) crystal plane as high property anode for sodium storage. Chinese Chemical Letters, 2024, 35(7): 108922-. doi: 10.1016/j.cclet.2023.108922
11. [11]
  Hao Cai , Xiaoyan Wu , Lei Jiang , Feng Yu , Yuxiang Yang , Yan Li , Xian Zhang , Jian Liu , Zijian Li , Hong Bi . Lysosome-targeted carbon dots with a light-controlled nitric oxide releasing property for enhanced photodynamic therapy. Chinese Chemical Letters, 2024, 35(4): 108946-. doi: 10.1016/j.cclet.2023.108946
12. [12]
  Ziyi Liu , Xunying Liu , Lubing Qin , Haozheng Chen , Ruikai Li , Zhenghua Tang . Alkynyl ligand for preparing atomically precise metal nanoclusters: Structure enrichment, property regulation, and functionality enhancement. Chinese Journal of Structural Chemistry, 2024, 43(11): 100405-100405. doi: 10.1016/j.cjsc.2024.100405
13. [13]
  Xinpin Pan , Yongjian Cui , Zhe Wang , Bowen Li , Hailong Wang , Jian Hao , Feng Li , Jing Li . Robust chemo-mechanical stability of additives-free SiO₂ anode realized by honeycomb nanolattice for high performance Li-ion batteries. Chinese Chemical Letters, 2024, 35(10): 109567-. doi: 10.1016/j.cclet.2024.109567
14. [14]
  Zhiwei Chen , Heyun Sheng , Xue Li , Menghan Chen , Xin Li , Qiuling Song . Efficient capture of difluorocarbene by pyridinium 1,4-zwitterionic thiolates: A concise synthesis of difluoromethylene-containing 1,4-thiazine derivatives. Chinese Chemical Letters, 2024, 35(4): 108937-. doi: 10.1016/j.cclet.2023.108937
15. [15]
  Wujun Jian , Mong-Feng Chiou , Yajun Li , Hongli Bao , Song Yang . Cu-catalyzed regioselective diborylation of 1,3-enynes for the efficient synthesis of 1,4-diborylated allenes. Chinese Chemical Letters, 2024, 35(5): 108980-. doi: 10.1016/j.cclet.2023.108980
16. [16]
  Yan-Li Li , Zhi-Ming Li , Kai-Kai Wang , Xiao-Long He . Beyond 1,4-addition of in-situ generated (aza-)quinone methides and indole imine methides. Chinese Chemical Letters, 2024, 35(7): 109322-. doi: 10.1016/j.cclet.2023.109322

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(765)
HTML views(38)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142