Citation: Cheng He-li, Feng Qing-hua, Liao Chuan-an, Liu Yu, Wu Dong-bei, Wang Qi-gang. Removal of Methylene Blue with Hemicellulose/Clay Hybrid Hydrogels[J]. Chinese Journal of Polymer Science, ;2016, 34(6): 709-719. doi: 10.1007/s10118-016-1788-2 shu

Removal of Methylene Blue with Hemicellulose/Clay Hybrid Hydrogels

a.
Department of Chemistry, Tongji University, Shanghai 200092, China
b.
Key Laboratory of Pulp and Paper Science & Technology of Ministry of Education of China, Qilu University of Technology, Jinan 250353, China
c.
Institute of Pulp and Papermaking, Hubei University of Technology, Wuhan 430068, China
d.
Pharmaceutical College, Guangxi Medical University, Nanning 530021, China

Corresponding author: Wang Qi-gang, wangqg66@tongji.edu.cn
Received Date: 30 November 2015
Revised Date: 2 February 2016
Accepted Date: 3 February 2016

Fund Project: the National Natural Science Foundation of China Nos. 21274111, 51473123 and 51402215the Program for New Century Excellent Talents in University of Ministry of Education of China NECT-11- 0386the Recruitment Program of Global Experts, and the open fund of Key Laboratory of Pulp and Paper Science & Technology of Ministry of Education of China No. 08031341

In this study, we chose corn stover hemicellulose for the preparation of hydrogels with admirable adsorption properties under mild alkaline conditions. Clay nanosheets were introduced to this system and hemicellulose/clay hybrid hydrogels were prepared. Morphological, mechanical properties and the methylene blue adsorption behaviors of the prepared hydrogels were studied. Results suggested that the addition of clay not only improved the mechanical strength of hemicellulose-based hydrogels, but also increased the adsorption capacity on methylene blue. Moreover, the adsorptions were confirmed to follow pseudo-second order equation for both gels with and without clay. The maximum adsorption capacities on methylene blue for hemicellulose-based hydrogels with or without clay reached 148.8 and 95.6 mg/g, respectively. These results implied that hemicellulose-based hydrogels could be used as promising adsorbents for the removal of methylene blue from waste water.
- Hemicellulose,
- Hybrid hydrogel,
- Clay,
- Adsorption
1. [1]
  Ravikumar, K., Deebika, B. and Balu, K., J. Hazard. Mater., 2005, 122(1-2): 75
2. [2]
  Xu, D., Hein, S., Loo, L.S. and Wang, K., Ind. Eng. Chem. Res., 2011, 50(10): 6343
3. [3]
  Dou, X., Li, P., Zhang, D. and Feng, C.L., Soft Matter, 2012, 8: 3231
4. [4]
  Moghaddama, S.S., Moghaddama, M.R.A. and Aramib, M., J. Hazard. Mater., 2010, 175(1-3): 651
5. [5]
  Dalaran, M., Emik, S., Güçlü, G., İyim, T.B. and Özgümüş, S., Desalination, 2011, 279(1-3): 170
6. [6]
  Kim, T.H., Park, C., Yang, J. and Kim, S., J. Hazard. Mater., 2004, 112(1-2): 95
7. [7]
  Robinson, T., McMullan, G., Marchant, R. and Nigam, P., Bioresour. Technol., 2001, 77: 247
8. [8]
  Hoffman, A.S., Adv. Drug Deliver. Rev., 2012, 64: 18
9. [9]
  Seliktar, D., Science, 2012, 336: 1124
10. [10]
  Miao, Q., Wu, Z., Hai, Z., Tao, C., Yuan, Q., Gong, Y., Guan, Y., Jiang, J. and Liang, G., Nanoscale, 2015, 7: 2797
11. [11]
  Liu, W., Zhang, B., Lu, W. W., Li X., Zhu, D., Yao, K., Wang, Q., Zhao, C. and Wang, C., Biomaterials, 2004, 25(15): 3005
12. [12]
  Zheng, Y. and Wang, A.Q., J. Hazard. Mater., 2009, 171(1-3): 671
13. [13]
  Dragan, E.S. and Apopei, D.F., Chem. Eng. J., 2011, 178: 252
14. [14]
  Gad, Y.H., Aly, R.O. and Abdel-Aal, S.E., J. Appl. Polym. Sci., 2011, 120(4): 1899
15. [15]
  Crini, G., Prog. Polym Sci., 2005, 30(1): 38
16. [16]
  Paulino, A.T., Guilherme, M.R., Reis, A.V., Campese, G.M., Muniz, E.C. and Nozaki, J., J. Colloid Interf. Sci., 2006, 301(1): 55
17. [17]
  Vakili, M., Rafatullah, M., Salamatinia, B., Abdullah, A.Z., Ibrahim, M.H., Tan, K.B., Gholami, Z. and Amouzgar, P., Carbohydr. Polym., 2014, 113: 115
18. [18]
  Wang, L. and Li, J., Ind. Crop. Prod., 2013, 42: 153
19. [19]
  Sharma, R., Kaith, B.S., Kalia, S., Pathania, D., Kumar, A., Sharma, N., Street, R.M. and Schauer, C., J. Environ. Manage., 2015, 162: 37
20. [20]
  Cao, X., Peng, X., Zhong, L. and Sun, R., J. Agric. Food Chem., 2014, 62(41): 10000
21. [21]
  Sun, X.F., Gan, Z., Jing, Z., Wang, H., Wang, D. and Jin, Y., J. Appl. Polym. Sci., 2015, 132(10): 41606
22. [22]
  Sun, X.F., Wang, H., Jing, Z. and Mohanathas, R., Carbohydr. Polym., 2013, 92(2): 1357
23. [23]
  Zhao, W., Odelius, K., Edlund, U., Zhao, C. and Albertsson, A.C., Biomacromolecules, 2015, 16(8): 2522
24. [24]
  Kuzmenko, V., Hägg D., Toriz, G. and Gatenholm, P., Carbohydr. Polym., 2014, 102: 862
25. [25]
  Zhao, W., Glavas, L., Odelius, K., Edlund, U. and Albertsson, A.C., Chem. Mater., 2014, 26(14): 4265
26. [26]
  Peng, X.W., Zhong, L.X., Ren, J.L. and Sun, R.C., J. Agric. Food Chem., 2012, 60(15): 3909
27. [27]
  Ferrari, E., Ranucci, E., Edlund, U. and Albertsson, A.C., J. Appl. Polym. Sci., 2015, 132(12): 41695
28. [28]
  Xiang, Y., Peng, Z. and Chen, D., Eur. Polym. J., 2006, 42: 2125
29. [29]
  Haraguchi, K., Takehisa, T. and Fan, S., Macromolecules, 2002, 35: 10162
30. [30]
  Bao, S., Wu, D., Wang, Q. and Su T., PloS one, 2014, 9(2): e88802
31. [31]
  Gao, G., Du, G., Cheng, Y. and Fu, J., J. Mater. Chem. B., 2014, 2: 1539
32. [32]
  Wang, X., Li, D., Yang F., Shen, H., Li, Z. and Wu, D., Polym. Chem., 2013, 4: 4596
33. [33]
  Song, H., Liu, W., He, S., Yang, M., Gao, Y., Zhu, C. and Wu, L., Chinese J. Polym. Sci., 2008, 26(2): 213
34. [34]
  Öztürk, A. and Malkoc, E., Appl. Surf. Sci., 2014, 299: 105
35. [35]
  Martínez, Martínez, V., López, Arbeloa, F., Banuelos, Prieto, J. and Arbeloa, López, I., Chem. Mater., 2005, 17: 4134
36. [36]
  Mina, M.F. and Alam, M.M., Chinese J. Polym. Sci., 2005, 23(2): 269
37. [37]
  Feng, Q.H., Cheng, H.L., Chen, F.G., Zhou, X.S., Wang, P. and Xie, Y.M., J. Wood Chem. Technol., 2015, 36: 173
38. [38]
  Crini, G., Bioresour. Technol., 2006, 97: 1061
39. [39]
  Shen, C., Shen, Y., Wen, Y., Wang, H. and Liu, W., Water Res., 2011, 45(16): 5200
40. [40]
  Lagergren, S. and Svenska, B.K., Vetenskapsakad Handlingar., 1898, 24: 1
41. [41]
  Ho, Y.S. and McKay, G., Process Biochem., 1999, 34(5): 451
42. [42]
  Chatterjee, S., Chatterjee, S., Chatterjee, B.P., Das, A.R. and Guha, A.K., J. Colloid Interf. Sci., 2005, 288(1): 30
43. [43]
  Liu, F., Chung, S., Oh, G. and Seo, T.S., ACS Appl. Mater Inter., 2012, 4(2): 922
44. [44]
  Nethaji, S., Sivasamy, A., Thennarasu, G. and Saravanan, S., J. Hazard. Mater., 2010, 181: 271
45. [45]
  Sun, Q. and Yang, L., Water Res., 2003, 37(7): 1535
46. [46]
  Hameed, B. and El-Khaiary, M., J. Hazard. Mater., 2008, 153(1-2): 701
47. [47]
  Ho, Y.S., Carbon, 2004, 42(10): 2115
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6. [6]
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1.
沈阳化工大学材料科学与工程学院沈阳 110142