Citation: Cheng He-li, Feng Qing-hua, Liao Chuan-an, Liu Yu, Wu Dong-bei, Wang Qi-gang. Removal of Methylene Blue with Hemicellulose/Clay Hybrid Hydrogels[J]. Chinese Journal of Polymer Science, ;2016, 34(6): 709-719. doi: 10.1007/s10118-016-1788-2 shu

Removal of Methylene Blue with Hemicellulose/Clay Hybrid Hydrogels

a.
Department of Chemistry, Tongji University, Shanghai 200092, China
b.
Key Laboratory of Pulp and Paper Science & Technology of Ministry of Education of China, Qilu University of Technology, Jinan 250353, China
c.
Institute of Pulp and Papermaking, Hubei University of Technology, Wuhan 430068, China
d.
Pharmaceutical College, Guangxi Medical University, Nanning 530021, China

Corresponding author: Wang Qi-gang, wangqg66@tongji.edu.cn
Received Date: 30 November 2015
Revised Date: 2 February 2016
Accepted Date: 3 February 2016

Fund Project: the National Natural Science Foundation of China Nos. 21274111, 51473123 and 51402215the Program for New Century Excellent Talents in University of Ministry of Education of China NECT-11- 0386the Recruitment Program of Global Experts, and the open fund of Key Laboratory of Pulp and Paper Science & Technology of Ministry of Education of China No. 08031341

In this study, we chose corn stover hemicellulose for the preparation of hydrogels with admirable adsorption properties under mild alkaline conditions. Clay nanosheets were introduced to this system and hemicellulose/clay hybrid hydrogels were prepared. Morphological, mechanical properties and the methylene blue adsorption behaviors of the prepared hydrogels were studied. Results suggested that the addition of clay not only improved the mechanical strength of hemicellulose-based hydrogels, but also increased the adsorption capacity on methylene blue. Moreover, the adsorptions were confirmed to follow pseudo-second order equation for both gels with and without clay. The maximum adsorption capacities on methylene blue for hemicellulose-based hydrogels with or without clay reached 148.8 and 95.6 mg/g, respectively. These results implied that hemicellulose-based hydrogels could be used as promising adsorbents for the removal of methylene blue from waste water.
- Hemicellulose,
- Hybrid hydrogel,
- Clay,
- Adsorption
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1.
沈阳化工大学材料科学与工程学院沈阳 110142