Citation: Chakraborty Samarshi, Kumar Manish, Suresh Kelothu, Pugazhenthi G.. Investigation of Structural, Rheological and Thermal Properties of PMMA/ONi-Al LDH Nanocomposites Synthesized via Solvent Blending Method: Effect of LDH Loading[J]. Chinese Journal of Polymer Science, ;2016, 34(6): 739-754. doi: 10.1007/s10118-016-1786-4 shu

Investigation of Structural, Rheological and Thermal Properties of PMMA/ONi-Al LDH Nanocomposites Synthesized via Solvent Blending Method: Effect of LDH Loading

Department of Chemical Engineering, Indian Institute of Technology Guwahati, Guwahati 781039, India

Corresponding author: Pugazhenthi G., pugal@iitg.ernet.in
Received Date: 16 November 2015
Revised Date: 19 January 2016
Accepted Date: 24 January 2016

This article addresses the synthesis of organically tailored Ni-Al layered double hydroxide (ONi-Al LDH) and its use in the fabrication of exfoliated poly(methyl methacrylate) (PMMA) nanocomposites. The pristine Ni-Al LDH was initially synthesized by co-precipitation method and subsequently modified using sodium dodecyl sulfate to obtain ONi-Al LDH. Nanocomposites of PMMA containing various amounts of modified Ni-Al LDH (3 wt%-7 wt%) were synthesized via solvent blending method to investigate the influence of LDH content on the properties of PMMA matrix. Several characterization methods such as X-ray diffraction (XRD), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR), rheological analysis, differential scanning calorimetry (DSC) and thermo gravimetric analysis (TGA), were employed to examine the structural, viscoelastic and thermal properties of PMMA/OLDH nanocomposites. The results of XRD and TEM examination confirm the formation of partially exfoliated PMMA/OLDH nanocomposites. The FTIR results elucidate that the characteristic bands for both pure PMMA and modified LDH are present in the spectra of PMMA/OLDH nanocomposites. Rheological analyses were carried out to examine the adhesion between polymer matrix and fillers present in the nanocomposite sample. The TGA data indicate that the PMMA nanocomposites exhibit higher thermal stability when compared to pure PMMA. The thermal decomposition temperature of PMMA/OLDH nanocomposites increases by 28 K compared to that of pure PMMA at 15% weight loss as a point of reference. In comparison with pure PMMA, the PMMA nanocomposite containing 7 wt% LDH demonstrates improved glass transition temperature (T_g) of around 3 K. The activation energy (E_a), reaction orders (n) and reaction mechanism of thermal degradation of PMMA/OLDH nanocomposites were evaluated using different kinetic models. Water uptake capacity of the PMMA/OLDH nanocomposites is less than that of the pure PMMA.
- Ni-Al LDH,
- PMMA,
- XRD,
- FTIR,
- TGA,
- Kinetic model
1. [1]
  Alexandre, M, Dubois, P. Mater. Sci. Eng.[J]. R-Rep, 2000,281.
2. [2]
  Usuki, A., Kojima, Y., Kawasumi, M., Okada, A., Fukushima, Y., Kurauchi, T. and Kamigaito, O., J. Mater. Res., 1993, 8: 1179
3. [3]
  Lan, T. and Pinnavaia, T.J., Chem. Mater., 1994, 6: 2216
4. [4]
  Giannelis, E.P., Adv. Mater., 1996, 8: 29
5. [5]
  Messersmith, P.B. and Giannelis, E.P., Chem. Mater., 1994, 6: 1719
6. [6]
  Kojima, Y., Fukumori, K., Usuki, A., Okada, A. and Kurauchi, T., J. Mater. Sci. Lett., 1993, 12: 889
7. [7]
  Wang, L., Xie, X., Su, S., Feng, J. and Wilkie, C.A., Polym. Degrad. Stab., 2010, 95: 572
8. [8]
  Chen, W. and Qu, B., Chem. Mater., 2003, 15: 3208
9. [9]
  Paul, D. and Robeson, L., Polymer, 2008 49: 3187
10. [10]
  Wang, D.Y., Das, A., Leuteritz, A., Boldt, R., Häußler, L., Wagenknecht, U. and Heinrich, G., Polym. Degrad. Stab., 2011, 96: 285
11. [11]
  Du, L., Qu, B. and Zhang, M., Polym. Degrad. Stab., 2007, 92: 497
12. [12]
  Qiu, L., Chen, W. and Qu, B., Colloid. Polym. Sci., 2005, 283: 1241
13. [13]
  Wang, G.A., Wang, C.C. and Chen, C.Y., Polym. Degrad. Stab., 2006, 91: 2443
14. [14]
  Qiu, L. and Qu, B., J. Colloid Interface Sci., 2006, 301: 347
15. [15]
  Huskić, M. and Žigon, M., Eur. Polym. J., 2007, 43: 4891
16. [16]
  Krishna, S.V. and Pugazhenthi, G., J. Exp. Nanosci., 2012, 8: 19
17. [17]
  Sahu, B. and Pugazhenthi, G., J. Appl. Polym. Sci., 2011, 120: 2485
18. [18]
  Strawhecker, K.E. and Manias, E., Chem. Mater., 2000, 12: 2943
19. [19]
  Unnikrishnan, L., Mohanty, S., Nayak, S.K. and Ali, A., Mater. Sci. Eng., A, 2011, 528: 3943
20. [20]
  Leroux, F. and Besse, J.P., Chem. Mater., 2001, 13: 3507
21. [21]
  Nalawade, P., Aware, B., Kadam, V. and Hirlekar, R., J. Sci. Ind. Res., 2009, 68: 267
22. [22]
  Hong, N., Song, L., Wang, B., Stec., A.A., Hull, T.R., Zhan, J. and Hu, Y., Mater. Res. Bull., 2014, 49: 657
23. [23]
  Li., M., Zhu, J.E., Zhang, L., Chen, X., Zhang, H., Zhang, F., Xu, S. and Evans, D.G., Nanoscale, 2011, 3: 4240
24. [24]
  Wimalasiri, Y., Fan, R., Zhao, X.S. and Zou, L., Electrochim. Acta, 2014, 134: 127
25. [25]
  Zhu, H., Liu, Q., Li, Z., Liu, J., Jing, X., Zhang, H. and Wang, J., RSC Adv., 2015, 5: 49204
26. [26]
  Nyambo, C., Chen, D., Su, S. and Wilkie, C.A., Polym. Degrad. Stab., 2009, 94: 1298
27. [27]
  Manzi-Nshuti, C., Wang, D., Hossenlopp, J.M. and Wilkie, C.A., Polym. Degrad. Stab., 2009, 94: 705
28. [28]
  Li, B., Hu, Y., Liu, J., Chen, Z. and Fan, W., Colloid. Polym. Sci., 2003, 281: 998
29. [29]
  Chen, W. and Qu, B., Polym. Degrad. Stab., 2005, 90: 162
30. [30]
  Zhou, Z., Wang, S., Lu, L., Zhang, Y. and Zhang, Y., Compos. Sci. Technol., 2007, 67: 1861
31. [31]
  Ivanov, I., Muke, S., Kao, N. and Bhattacharya, S.N., Polymer, 2001, 42: 9809
32. [32]
  Al-Saleh, M.H. and Sundararaj, U., Composites Part A, 2011, 42: 2126
33. [33]
  Ding, P. and Qu, B., J. Colloid Interface Sci., 2005, 291: 13
34. [34]
  Gilman, J.W., Jackson, C.L., Morgan, A.B., Harris, Jr. R., Manias, E., Giannelis, E. P., Wuthenow, M., Hilton, D. and Philips, S.H., Chem. Mater., 2002, 12: 1886
35. [35]
  Tomar, A., Mahendia, S. and Kumar, S., Adv. Appl. Sci. Res., 2011, 2: 65
36. [36]
  Morgan, A.B. and Gilman, J.W., J. Appl. Polym. Sci., 2003, 87: 1329
37. [37]
  Mohanty, S. and Nayak, S.K., J. Thermoplast. Compos., 2010, 23: 623
38. [38]
  Shen, Z., Simon, G.P. and Cheng, Y.B., J. Appl. Polym. Sci., 2004, 92: 2101
39. [39]
  Stretz, H.A., Paul, D.R., Li, R., Keskkula, H. and Cassidy, P.E., Polymer, 2005, 46: 2621
40. [40]
  Coats, A.W. and Redfern, J.P., Nature, 1964, 201: 68
41. [41]
  Chen, Y. and Wang, Q., Polym. Degrad. Stab., 2007, 92: 280
42. [42]
  Krishna, S. and Pugazhenthi, G., J. Appl. Polym. Sci., 2011, 120: 1322
43. [43]
  Criado, J.M., Málek, J. and Ortega, A., Thermochim. Acta, 1989, 147: 377
44. [44]
  Senum, G.I. and Yang, R.T., J. Therm. Anal., 1977, 11: 445
45. [45]
  Flynn, J.H., Thermochim. Acta, 1997, 300: 83
46. [46]
  Park, S.J., Li, K. and Hong, S.K., J. Ind. Eng. Chem., 2005, 11: 561
47. [47]
  Zhang, H.B., Zheng, W.G., Yan, Q., Jiang, Z.G. and Yu, Z.Z., Carbon, 2012, 50: 5117
48. [48]
  Majid, M., Hassan, E.D., Davoud, A. and Saman, M., Composites Part B, 2011, 42: 2038
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