Citation: Lin Wu, Tao Pang, Ye-bin Guan. Miniemulsion Cross-linking: A Convenient Route to Hollow Polymeric Nanocapsule with a Liquid Core[J]. Chinese Journal of Polymer Science, ;2016, 34(5): 523-531. doi: 10.1007/s10118-016-1784-6 shu

Miniemulsion Cross-linking: A Convenient Route to Hollow Polymeric Nanocapsule with a Liquid Core

Lin Wu ^a,b,, ,
Tao Pang ^a ,
Ye-bin Guan ^a,b

a.
Anhui Key Laboratory of Functional Coordination Compounds, School of Chemistry and Chemical Engineering, Anqing Normal University, Anqing 246011, China
b.
Anhui Collaborative Innovation Center for Petrochemical New Materials, Anqing 246011, China

Corresponding author: Lin Wu, wulinaqsfxy@163.com
Received Date: 8 September 2015
Revised Date: 30 October 2016
Accepted Date: 5 January 2016

Fund Project: the Natural Science Foundation of Anhui Province Education Department AQKJ2015B002This work was financially supported by the National Natural Science Foundation of China 41402037the Natural Science Foundation of Anhui Province Education Department KJ2014A141

Miniemulsion stabilized by poly(2-(dimethylamino) ethyl methacrylate)-block-poly(butyl methylacrylate) (PDMAEMA- b-PBMA) diblock copolymers has been used as liquid templates for the synthesis of polymer nanocapsules via quaternization cross-linking of PDMAEMA segments of the copolymer by 1,2-bis(2-iodoethoxy)ethane (BIEE) crosslinkers. PDMAEMA- b-PBMAs here as a stabilizer in miniemulsion with different molecular weights led to a size variation in diameters of nanocapsules, demonstrating the capsules have potential design capability of this technique. The solution behavior of the capsules has been also investigated in this paper.
- Cross-linking,
- Miniemulsion,
- Nanocapsule,
- Block copolymer
1. [1]
  El-Gogary, R.I., Rubio, N., Wang, J.T.W., Al-Jamal, W.T., Bourgognon, M., Kafa, H., Naeem, M., Klippstein, R., Abbate, V., Leroux, F., Bals, S., Van Tendeloo, G., Kamel, A.O., Awad, G.A.S., Mortada, N.D. and Al-Jamal, K.T., ACS Nano, 2014, 8(2): 1384 doi: 10.1021/nn405155b
2. [2]
  Yang, X., Grailer, J.J., Rowland, I.J., Javadi, A., Hurley, S.A., Matson, V.Z., Steeber, D.A. and Gong, S., ACS Nano, 2010, 4(11): 6805 doi: 10.1021/nn101670k
3. [3]
  Hu, J., Xiao, Z., Zhou, R., Li, Z., Wang, M. and Ma, S., Flavour Fragr. J., 2011, 26(3): 162 doi: 10.1002/ffj.v26.3
4. [4]
  Elsabahy, M., Heo, G.S., Lim, S.M., Sun, G. and Wooley, K.L., Chem. Rev., 2015, 115(19): 10967 doi: 10.1021/acs.chemrev.5b00135
5. [5]
  Morinaga, T., Ohkura, M., Ohno, K., Tsujii, Y. and Fukuda, T., Macromolecules, 2007, 40(4): 1159 doi: 10.1021/ma062230p
6. [6]
  Duan, H., Kuang, M., Zhang, G., Wang, D., Kurth, D.G. and Möhwald, H., Langmuir, 2005, 21(24): 11495 doi: 10.1021/la051638x
7. [7]
  Boyer, C., Whittaker, M.R., Nouvel, C. and Davis, T.P., Macromolecules, 2010, 43(4): 1792 doi: 10.1021/ma902663n
8. [8]
  Thurmond, K.B., Kowalewski, T. and Wooley, K.L., J. Am. Chem. Soc., 1996, 118(30): 7239 doi: 10.1021/ja961299h
9. [9]
  Wang, M., Jiang, M., Ning, F., Chen, D., Liu, S. and Duan, H., Macromolecules, 2002, 35(15): 5980 doi: 10.1021/ma0201330
10. [10]
  Sanji, T., Nakatsuka, Y., Ohnishi, S. and Sakurai, H., Macromolecules, 2000, 33(23): 8524 doi: 10.1021/ma0011892
11. [11]
  Bütün, V., Lowe, A.B., Billingham, N.C. and Armes, S.P., J. Am. Chem. Soc., 1999, 121(17): 4288 doi: 10.1021/ja9840596
12. [12]
  Zhang, Q., Remsen, E.E. and Wooley, K.L., J. Am. Chem. Soc., 2000, 122(15): 3642 doi: 10.1021/ja993941o
13. [13]
  Liu, S. and Armes, S.P., J. Am. Chem. Soc., 2001, 123(40): 9910 doi: 10.1021/ja011206i
14. [14]
  Sugihara, S., Armes, S.P. and Lewis, A.L., Angew. Chem. Int. Ed., 2010, 49(20): 3500 doi: 10.1002/anie.201000095
15. [15]
  Luo, Y. and Gu, H., Macromol. Rapid Commun., 2006, 27(1): 21 doi: 10.1002/(ISSN)1521-3927
16. [16]
  McHale, R., Ghasdian, N., Liu, Y., Ward, M.B., Hondow, N.S., Wang, H., Miao, Y., Brydson, R. and Wang, X., Chem. Commun., 2010, 46(25): 4574 doi: 10.1039/c0cc00003e
17. [17]
  Liang, G., Xu, J. and Wang, X., J. Am. Chem. Soc., 2009, 131(15): 5378 doi: 10.1021/ja900516a
18. [18]
  Utama, R.H., Stenzel, M.H. and Zetterlund, P.B., Macromolecules, 2013, 46(6): 2118 doi: 10.1021/ma4002148
19. [19]
  Utama, R.H., Jiang, Y., Zetterlund, P.B. and Stenzel, M.H., Biomacromolecules, 2015, 16(7): 2144 doi: 10.1021/acs.biomac.5b00545
20. [20]
  Luo, Y. and Gu, H., Polymer, 2007, 48(11): 3262 doi: 10.1016/j.polymer.2007.03.042
21. [21]
  Mayadunne, R.T.A., Rizzardo, E., Chiefari, J., Chong, Y.K., Moad, G. and Thang, S.H., Macromolecules, 1999, 32(21): 6977 doi: 10.1021/ma9906837
22. [22]
  Read, E.S. and Armes, S.P., Chem. Commun., 2007, (29): 3021 doi: 10.1039/b701217a
23. [23]
  Roy, D., Knapp, J.S., Guthrie, J.T. and Perrier, S., Biomacromolecules, 2008, 9(1): 91 doi: 10.1021/bm700849j
24. [24]
  Li, W., Matyjaszewski, K., Albrecht, K. and Möller, M., Macromolecules, 2009, 42(21): 8228 doi: 10.1021/ma901574y
1. [1]
  Yiwen Lin , Yijie Chen , Chunhui Deng , Nianrong Sun . Integration of resol/block-copolymer carbonization and machine learning: A convenient approach for precise monitoring of glycan-associated disorders. Chinese Chemical Letters, 2024, 35(12): 109813-. doi: 10.1016/j.cclet.2024.109813
2. [2]
  Xue Zhao , Rui Zhao , Qian Liu , Henghui Chen , Jing Wang , Yongfeng Hu , Yan Li , Qiuming Peng , John S Tse . A p-d block synergistic effect enables robust electrocatalytic oxygen evolution. Chinese Chemical Letters, 2024, 35(11): 109496-. doi: 10.1016/j.cclet.2024.109496
3. [3]
  Changlin Su , Wensheng Cai , Xueguang Shao . Water as a probe for the temperature-induced self-assembly transition of an amphiphilic copolymer. Chinese Chemical Letters, 2025, 36(4): 110095-. doi: 10.1016/j.cclet.2024.110095
4. [4]
  Qian Wang , Ting Gao , Xiwen Lu , Hangchao Wang , Minggui Xu , Longtao Ren , Zheng Chang , Wen Liu . Nanophase separated, grafted alternate copolymer styrene-maleic anhydride as an efficient room temperature solid state lithium ion conductor. Chinese Chemical Letters, 2024, 35(7): 108887-. doi: 10.1016/j.cclet.2023.108887
5. [5]
  Shan Jiang , Lingchen Meng , Wenyue Ma , Qingkai Qi , Wei Zhang , Bin Xu , Leijing Liu , Wenjing Tian . Corrigendum to 'Morphology controllable conjugated network polymers based on AIE-active building block for TNP detection' [Chin. Chem. Lett. 32 (2021) 1037-1040]. Chinese Chemical Letters, 2024, 35(12): 108998-. doi: 10.1016/j.cclet.2023.108998
6. [6]
  Jing Wang , Zhongliao Wang , Jinfeng Zhang , Kai Dai . Single-layer crystalline triazine-based organic framework photocatalysts with different linking groups for H2O2 production. Chinese Journal of Structural Chemistry, 2023, 42(12): 100202-100202. doi: 10.1016/j.cjsc.2023.100202
7. [7]
  Shicheng Dong , Jun Zhu . Could π-aromaticity cross an unsaturated system to a fully saturated one?. Chinese Chemical Letters, 2024, 35(6): 109214-. doi: 10.1016/j.cclet.2023.109214
8. [8]
  Kai An , Qinglong Qiao , Lovelesh , Syed Ali Abbas Abedi , Xiaogang Liu , Zhaochao Xu . "Superimposed" spectral characteristics of fluorophores arising from cross-conjugation hybridization. Chinese Chemical Letters, 2025, 36(1): 109786-. doi: 10.1016/j.cclet.2024.109786
9. [9]
  Baokang Geng , Xiang Chu , Li Liu , Lingling Zhang , Shuaishuai Zhang , Xiao Wang , Shuyan Song , Hongjie Zhang . High-efficiency PdNi single-atom alloy catalyst toward cross-coupling reaction. Chinese Chemical Letters, 2024, 35(7): 108924-. doi: 10.1016/j.cclet.2023.108924
10. [10]
  Lang Gao , Cen Zhou , Rui Wang , Feng Lan , Bohang An , Xiaozhou Huang , Xiao Zhang . Unveiling inverse vulcanized polymers as metal-free, visible-light-driven photocatalysts for cross-coupling reactions. Chinese Chemical Letters, 2024, 35(4): 108832-. doi: 10.1016/j.cclet.2023.108832
11. [11]
  Yuhan Liu , Jingyang Zhang , Gongming Yang , Jian Wang . Highly enantioselective carbene-catalyzed δ-lactonization via radical relay cross-coupling. Chinese Chemical Letters, 2025, 36(1): 109790-. doi: 10.1016/j.cclet.2024.109790
12. [12]
  Binyang Qin , Mengqi Wang , Shimei Wu , Yining Li , Chilin Liu , Yufei Zhang , Haosen Fan . Carbon dots confined nanosheets assembled NiCo₂S₄@CDs cross-stacked architecture for enhanced sodium ion storage. Chinese Chemical Letters, 2024, 35(7): 108921-. doi: 10.1016/j.cclet.2023.108921
13. [13]
  Yuemin Chen , Yunqi Wu , Guoao Wang , Feihu Cui , Haitao Tang , Yingming Pan . Electricity-driven enantioselective cross-dehydrogenative coupling of two C(sp³)-H bonds enabled by organocatalysis. Chinese Chemical Letters, 2024, 35(9): 109445-. doi: 10.1016/j.cclet.2023.109445
14. [14]
  Lili Zhang , Hui Gao , Gong Zhang , Yuning Dong , Kai Huang , Zifan Pang , Tuo Wang , Chunlei Pei , Peng Zhang , Jinlong Gong . Cross-section design of the flow channels in membrane electrode assembly electrolyzer for CO₂ reduction reaction through numerical simulations. Chinese Chemical Letters, 2025, 36(1): 110204-. doi: 10.1016/j.cclet.2024.110204
15. [15]
  Peng Guo , Shicheng Dong , Xiang-Gui Zhang , Bing-Bin Yang , Jun Zhu , Ke-Yin Ye . Cobalt-catalyzed migratory carbon-carbon cross-coupling of borabicyclo[3.3.1]nonane (9-BBN) borates. Chinese Chemical Letters, 2025, 36(4): 110052-. doi: 10.1016/j.cclet.2024.110052
16. [16]
  Qinghong Zhang , Qiao Zhao , Xiaodi Wu , Li Wang , Kairui Shen , Yuchen Hua , Cheng Gao , Yu Zhang , Mei Peng , Kai Zhao . Visible-light-induced ring-opening cross-coupling of cycloalcohols with vinylazaarenes and enones via β-C-C scission enabled by proton-coupled electron transfer. Chinese Chemical Letters, 2025, 36(2): 110167-. doi: 10.1016/j.cclet.2024.110167
17. [17]
  Xianchen Hu , Junli Yang , Fang Gao , Zhiyong Zhao , Simin Liu . Highly selective [4+4] cross-photodimerization of (4a-azonia)anthracenes driven by confinement of D-A hetero-guest pair in cucurbit[10]uril host. Chinese Chemical Letters, 2025, 36(3): 109967-. doi: 10.1016/j.cclet.2024.109967

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(691)
HTML views(27)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142