Citation: Lin Wu, Tao Pang, Ye-bin Guan. Miniemulsion Cross-linking: A Convenient Route to Hollow Polymeric Nanocapsule with a Liquid Core[J]. Chinese Journal of Polymer Science, ;2016, 34(5): 523-531. doi: 10.1007/s10118-016-1784-6 shu

Miniemulsion Cross-linking: A Convenient Route to Hollow Polymeric Nanocapsule with a Liquid Core

Lin Wu ^a,b,, ,
Tao Pang ^a ,
Ye-bin Guan ^a,b

a.
Anhui Key Laboratory of Functional Coordination Compounds, School of Chemistry and Chemical Engineering, Anqing Normal University, Anqing 246011, China
b.
Anhui Collaborative Innovation Center for Petrochemical New Materials, Anqing 246011, China

Corresponding author: Lin Wu, wulinaqsfxy@163.com
Received Date: 8 September 2015
Revised Date: 30 October 2016
Accepted Date: 5 January 2016

Fund Project: the Natural Science Foundation of Anhui Province Education Department AQKJ2015B002This work was financially supported by the National Natural Science Foundation of China 41402037the Natural Science Foundation of Anhui Province Education Department KJ2014A141

Miniemulsion stabilized by poly(2-(dimethylamino) ethyl methacrylate)-block-poly(butyl methylacrylate) (PDMAEMA- b-PBMA) diblock copolymers has been used as liquid templates for the synthesis of polymer nanocapsules via quaternization cross-linking of PDMAEMA segments of the copolymer by 1,2-bis(2-iodoethoxy)ethane (BIEE) crosslinkers. PDMAEMA- b-PBMAs here as a stabilizer in miniemulsion with different molecular weights led to a size variation in diameters of nanocapsules, demonstrating the capsules have potential design capability of this technique. The solution behavior of the capsules has been also investigated in this paper.
- Cross-linking,
- Miniemulsion,
- Nanocapsule,
- Block copolymer
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