Citation: Hong-mei Zhang, Shu-hua Zhang, Polite Stewart, Chen-hui Zhu, Wei-jun Liu, Alexander Hexemer, Eric Schaible, Cheng Wang. Thermal Stability and Thermal Aging of Poly(vinyl chloride)/MgAl Layered Double Hydroxides Composites[J]. Chinese Journal of Polymer Science, ;2016, 34(5): 542-551. doi: 10.1007/s10118-016-1778-4 shu

Thermal Stability and Thermal Aging of Poly(vinyl chloride)/MgAl Layered Double Hydroxides Composites

a.
College of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai 201620, China
b.
Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley 94720, USA
c.
College of Mechanical Engineering, Shanghai University of Engineering Science, Shanghai 201620, China

Corresponding author: Shu-hua Zhang, zhangsh@sues.edu.cn Cheng Wang, cwang2@lbl.gov
Received Date: 28 October 2015
Revised Date: 30 November 2015
Accepted Date: 27 December 2015

Fund Project: This work was financially supported by the Shanghai Municipal Education Commission with “Twelfth Five” scientific connotation construction project nhky-2012-05foreign visiting scholar fellowship program B-8938-12-0406

MgAl-LDH (layered double hydroxides) were prepared with CO(NH₂)₂, NH₄Cl and NH₃·H₂O by the co-precipitation method, respectively. Corresponding composite membranes were prepared by the coating method. LDHs were characterized by WAXS, CO₂-TPD and SEM. The morphology of the PVC/LDHs composite membranes were characterized by means of SEM. The thermal stability of the membranes was analyzed by air aging box and TGA-FTIR. The SEM results show that nano-particles can be compatible with poly(vinyl chloride) (PVC) matrix homogeneously by the stirring-ultrasound blend method with two steps. Furthermore, the air aging box results proved that MgAl-CO(NH₂)₂-LDH has the best effect on thermal stability of PVC. TGA-FTIR results show that MgAl-CO(NH₂)₂-LDH could adsorb more HCl that resulted from the degradation of PVC and improve the pyrolysis temperature of the first degradation stage by 15 K compared with PVC.
- Poly(vinyl chloride),
- Layered double hydroxide,
- Thermal stability,
- TGA-FTIR
1. [1]
  Wen, R.J., Yang, Z.H., Chen, H.Y., Hu, Y.W. and Duan, J.A., J. Rare Earth , 2012, 30: 895 doi: 10.1016/S1002-0721(12)60151-3
2. [2]
  Pagacz, J., Chrzanowski, M., Krucińska, I. and Pielichowski, K., J. Appl. Polym. Sci., 2015: 132: 42090
3. [3]
  Liu, J., Chen, G.M. and Yang, J.P., Polymer, 2008, 49: 3923 doi: 10.1016/j.polymer.2008.07.014
4. [4]
  Basu, D., Das, A., Stöckelhuber, K.W., Wagenknecht, U. and Heinrich, G., Prog. Polym. Sci., 2014, 39: 594 doi: 10.1016/j.progpolymsci.2013.07.011
5. [5]
  He, S., An, Z., Wei, M., Evans, D.G. and Duan, X., Chem. Commun., 2013, 49: 5912 doi: 10.1039/c3cc42137f
6. [6]
  Zhao, M.Q., Zhang, Q., Huang, J.Q. and Wei, F., Adv. Funct. Mater., 2012, 22: 675 doi: 10.1002/adfm.201102222
7. [7]
  Yi, S., Yang, Z.H., Wang, S.W., Liu, D.R., Wang, S.Q., Liu, Q.Y. and Chi, W.W., J. Appl. Polym. Sci., 2011, 119: 2620 doi: 10.1002/app.v119.5
8. [8]
  Lin, Y.J., Li, D.Q., Evans, D.G. and Duan, X., Polym. Degrad. Stab., 2005, 88: 286 doi: 10.1016/j.polymdegradstab.2004.11.007
9. [9]
  Hu, Z.Q. and Chen, G.M., Adv. Mater., 2014, 26: 5950 doi: 10.1002/adma.201400179
10. [10]
  Cao, T.C., Xu, K.L., Chen, G.M. and Guo, C.Y., RSC Adv.,2013, 3: 6282 doi: 10.1039/c3ra23321a
11. [11]
  Hu, Z.Q. and Chen, G.M., J. Mater. Chem. A, 2014, 2: 13593 doi: 10.1039/C4TA01590H
12. [12]
  Fu, P.F., Xu, K.L., Song, H.Z., Chen, G.M., Yang, J.P. and Niu, Y.H., J. Mater. Chem., 2010, 20: 3869 doi: 10.1039/b927391c
13. [13]
  Zhang, X.F., Zhao, T.B., Pi, H. and Guo, S.Y., J. Appl. Polym. Sci., 2012, 124: 5180
14. [14]
  Wang, Q. and O'hare, D., Chem. Rev., 2012, 112: 4124 doi: 10.1021/cr200434v
15. [15]
  Ma, R.Z., Liu, Z.P., Li, L., Lyi, L. and Sasaki, T., J. Mater. Chem., 2006, 16: 3809 doi: 10.1039/b605422f
16. [16]
  Ferencz, Z., Szabados, M., Adok-Sipiczki, M., Kukovecz, A., Konya, Z., Sipos, P. and Palinko, I., J. Mater. Sci., 2014, 49: 8478 doi: 10.1007/s10853-014-8558-8
17. [17]
  Liu, J., Chen, G.M., Yang, J.P. and Ding, L.P., J. Appl. Polym. Sci., 2010, 116: 2058
18. [18]
  Rajamathi, M. and Kamath, P.V., Int. J. Inorg. Mater., 2001, 3: 901 doi: 10.1016/S1466-6049(01)00090-3
19. [19]
  Lei, X., Yang, L., Zhang, F. and Duan, X., Chem. Eng. Sci., 2006, 61: 2730 doi: 10.1016/j.ces.2005.11.053
20. [20]
  Guo, Y., Liu, J., Zhang, S.H., Yang, S.Y., Zhang, K.F. and Liao, J.J., Adv. Mater. Res., 2012, 549: 353 doi: 10.4028/www.scientific.net/AMR.549
21. [21]
  Zhang, X.F., Zhou, L.C., Pi, H., Guo, S.Y. and Fu, J.W., Polym. Degrad. Stab., 2014, 102: 204 doi: 10.1016/j.polymdegradstab.2014.01.003
22. [22]
  Intissar, M., Seron, A., Giovannelli, F., Autret, C., Motelica-Heino, M. and Delorme, F., J. Mater. Sci., 2015, 50: 1427 doi: 10.1007/s10853-014-8702-5
23. [23]
  Zhou, H., Meng, A.H., Long, Y.Q., Li, Q.H. and Zhang, Y.G., J. Anal. Appl. Pyrol., 2014, 108:19 doi: 10.1016/j.jaap.2014.05.024
24. [24]
  Fonseca, J.D., Grause, G., Kameda, T. and Yoshioka, T., Polym. Degrad. Stab., 2015, 117: 8 doi: 10.1016/j.polymdegradstab.2015.03.011
25. [25]
  Jiang, Y., Gu, X.Y., Zhang, S., Tang, W.F. and Zhao, J.R., Mater. Lett., 2015, 150: 31 doi: 10.1016/j.matlet.2014.12.096
26. [26]
  Rozov, K., Curtius, H. and Bosbach, D., Radiochim. Acta, 2015, 103: 369
27. [27]
  Nangoi, I.M., Vaiss, V.S., Souza, W.F., Sandra, S.X. and Alexandre, A.L., Appl. Clay Sci., 2015, 107: 131 doi: 10.1016/j.clay.2015.01.014
28. [28]
  Perez-Barrado, E., Pujol, M.C., Aguilo, M., Llorca, J., Cesteros, Y., Diaz, F., Pallares, J., Marsal, L.F. and Salagre, P., Chem. Eng. J., 2015, 264: 547 doi: 10.1016/j.cej.2014.11.117
29. [29]
  Abdel-NAby, A.S., Al-Ghamdi, R.F. and Al-Ghamdi, A.A., J. Viny. Addit. Techn., 2010, 16: 15 doi: 10.1002/vnl.v16:1.n
30. [30]
  Zhu, H., Wang, W. and Liu, T.X., J. Appl. Polym. Sci., 2011, 122: 273 doi: 10.1002/app.v122.1
31. [31]
  Di Cosimo, J.I., Díez, V.K., Xu, M.E., Iglesia, E. and Apesteguía, C.R., J. Catal., 1998, 178:499 doi: 10.1006/jcat.1998.2161
32. [32]
  Corma, A., Fornes, V., Martin-Aranda, M.R. and Rey, F., J. Catal., 1992, 134: 58 doi: 10.1016/0021-9517(92)90209-Z
33. [33]
  Kanezaki, E., Avilés, Y., Borau, V., Luque, J.M., Marinas, J.M. and Ruiz, J.R., J. Mater.Chem., 1999, 9: 1603 doi: 10.1039/a900535h
34. [34]
  Kanezaki, E., Solid State Ionics, 1998, 106: 279 doi: 10.1016/S0167-2738(97)00494-3
35. [35]
  Yoshida, M., Koilraj, P., Qiu, X.H., Hirajima, T. and Sasaki, K., J. Environ. Chem. Eng., 2015, 3: 1614 doi: 10.1016/j.jece.2015.05.016
36. [36]
  Wang, Y.Z., Luo, S.H., Wang, Z.G. and Fu, Y., Appl. Clay Sci., 2013, 80-81: 334 doi: 10.1016/j.clay.2013.05.015
37. [37]
  Wu, J.L., Chen, T.J., Luo, X.T., Luo, X.T., Han, D.Z., Wang, Z.Q. and Wu, J.H., Waste Manage., 2014, 34: 676 doi: 10.1016/j.wasman.2013.12.005
38. [38]
  Zhu, H.M., Jiang, X.G., Yan, J.H., Chi, Y. and Cen, K.F., J. Anal. Appl. Pyrol., 2008, 82: 1 doi: 10.1016/j.jaap.2007.11.011
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1.
沈阳化工大学材料科学与工程学院沈阳 110142