Citation: Zhi-dong Wang, Xiao-zhong Qu, Bi-qing Jin, Yi Shi, Zhi-tian Liu, Xi-gao Jin. Effect of Polymer Matrix on Temperature Sensitivity of Temperature Sensitive Paints[J]. Chinese Journal of Polymer Science, ;2015, 33(10): 1351-1358. doi: 10.1007/s10118-015-1684-1 shu

Effect of Polymer Matrix on Temperature Sensitivity of Temperature Sensitive Paints

Zhi-dong Wang ^1,2,3 ,
Xiao-zhong Qu ⁴ ,
Bi-qing Jin ⁵ ,
Yi Shi ⁶ ,
Zhi-tian Liu ⁵ ,
Xi-gao Jin ⁶

1.
1. School of Material Science and Engineering, Wuhan Institute of Technology, Wuhan 430073, China
2.
2. State Key Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
3.
4.
University of Chinese Academy of Sciences, Beijing 100049, China
5.
School of Material Science and Engineering, Wuhan Institute of Technology, Wuhan 430073, China
6.
State Key Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China

Received Date: 3 March 2015
Revised Date: 10 April 2015

Fund Project: This work was financially supported by the Hubei Province Youth Chenguang Program of Science and Technology (No. 2014.5), Applied Basic Research Programs of Wuhan (No. 2015010101010018), Soft Science Research Program of Wuhan (No. 2015040606010250), Educational Commission of Hubei Province of China (No. D20151505), Graduate Innovative Fund of Wuhan Institute of Technology (No. CX2013088).

The thermal quenching behaviors of the temperature sensitivity paints (TSP) composed of europium(III) thenoyltrifluoroacetonate (EuTTA) and Eu-phenanthrene complex (Eu-2) in polystyrene (PS), polymethylmethacrylate (PMMA) and epoxy resin (EP) were investigated. It is found that both the emission intensity and temperature sensitivity were not only affected by the luminescence probes, but also by the polymer matrix. The interaction between probes and matrix results in the alteration of both the non-radiation decay rate and the activation energy of the non-radiative process for the thermal quenching process, i.e. larger activation energy of the non-radiative process shows higher temperature sensitivity and less emission intensity. Therefore, it was confirmed that the temperature sensitivity and luminescent intensity of TSP depended not only on the luminescence probes but also on the polymer matrix.
- Temperature sensitive paints,
- Europium complex,
- Thermal quenching,
- Polymer matrix,
- Temperature sensitivity
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