Citation: Xiong-fa Yang, Cheng Cao, Zhong-hong Chen, Jia Liu, Meng-xian Luo, Guo-qiao Lai. Synthesis of Ladder-like Polyphenylsilsesquioxanes with Fairly High Regularity Using 1,2-Ethylenediamine as Endo-template[J]. Chinese Journal of Polymer Science, ;2015, 33(9): 1305-1312. doi: 10.1007/s10118-015-1678-z shu

Synthesis of Ladder-like Polyphenylsilsesquioxanes with Fairly High Regularity Using 1,2-Ethylenediamine as Endo-template

Received Date: 9 February 2015
Revised Date: 26 March 2015

Fund Project: This work was financially supported by the Zhejiang Provincial Natural Science Foundation (No. LY14E030008), the Commonweal Technology Application Research Project of Zhejiang Province (No. 2013C31079), the National Natural Science Foundation of China (No. 51353003) and the China Postdoctoral Science Foundation (No. 2013 M531455).

Ladder-like polyphenylsilsesquioxanes with fairly high regularity were synthesized using an endo-template 1,2-ethylenediamine at mild temperature via direct co-hydrolysis and condensation reactions in the presence of acid catalysts in the mixture of 1,4-dioxane/H2O. The features for synthesis of ladder-like polyphenylsilsesquioxanes were investigated in detail. The products obtained were characterized by FTIR, SEC, XRD and NMR.
- Ladder-like,
- Poly(phenyl silsesquioxanes),
- Endo-template
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沈阳化工大学材料科学与工程学院沈阳 110142