Citation: Liang-jiu Bai, Wen-xiang Wang, Ming-hua Wang, Jin-ming Sun, Hou Chen. Triphenylphosphine as Reducing Agent for Copper(II)-catalyzed AGET ATRP[J]. Chinese Journal of Polymer Science, ;2015, 33(9): 1260-1270. doi: 10.1007/s10118-015-1676-1 shu

Triphenylphosphine as Reducing Agent for Copper(II)-catalyzed AGET ATRP

1.
School of Chemistry and Materials Science, Ludong University, Yantai 264025, China

Received Date: 27 January 2015
Revised Date: 24 March 2015

Fund Project: This work was financially supported by the National Natural Science Foundation of China (Nos. 21404051 and 21404052), the Natural Science Foundation of Shandong Province (Nos. ZR2014BQ016 and BS2014CL040), the Talent Introduction Special Funds of Ludong University (Nos. 2014012 and 2014017), the Program for Scientific research Innovation Team in Colleges and universities of Shandong Province and Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application (Soochow University).

Triphenylphosphine (TPP) was used as reducing agent to continuously generate the Cu(I) activator in copper(II)-catalyzed activators generated by electron transfer atom transfer radical polymerization (AGET ATRP). For example, the polymers prepared with a molar ratio of [MMA]0/[EBiB]0/[CuCl2]0/[PMDETA]0/[TPP]0 = 500/1/0.1/0.5/0.5 had controlled molecular weights and low molecular weight distribution (Mw/Mn) values (~1.2). TPP as a commercial reducing agent provides a convenient copper-catalyzed AGET ATRP procedure for the preparation of well-defined polymers.
- ATRP,
- AGET ATRP,
- Reducing agent,
- Triphenylphosphine (TPP)
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
33. [33]
34. [34]
35. [35]
36. [36]
37. [37]
38. [38]
39. [39]
40. [40]
41. [41]
42. [42]
43. [43]
44. [44]
45. [45]
46. [46]
47. [47]
48. [48]
49. [49]
50. [50]
1. [1]
  Tao LIU , Yuting TIAN , Ke GAO , Xuwei HAN , Ru'nan MIN , Wenjing ZHAO , Xueyi SUN , Caixia YIN . A photothermal agent with high photothermal conversion efficiency and high stability for tumor therapy. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1622-1632. doi: 10.11862/CJIC.20240107
2. [2]
  Huaran Zhang , Yuting Huang , Yingjie Tang , Dekun Kong , Yi Zou . Genome mining of multi-substituted alkylresorcinols from a hybrid highly reducing- and type Ⅲ- polyketide pathway. Chinese Chemical Letters, 2024, 35(7): 108968-. doi: 10.1016/j.cclet.2023.108968
3. [3]
  Hui Zhang , Rong Feng , Wanyi Yu , Hongbei Wei , Tianhong Wu , Peng Zhang , Wenhai Bian , Xin Li , Di Gao , Guojun Weng , Zhe Yang , Tony D. James , Xiaolong Sun . Evaluating the global thiols redox state in living cells using a reducing sulfur species responsive fluorescence switching platform. Chinese Chemical Letters, 2025, 36(4): 110528-. doi: 10.1016/j.cclet.2024.110528

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(673)
HTML views(18)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return