Citation: Xi-xian Ke, Jun-ting Xu, Bin-yang Du, Zhi-qiang Fan. Morphology and Thermoresponsive Behavior of Hybrid Micelles of Polystyrene-b-Poly((N-isopropyl acrylamide)-co-(4-vinylbenzyl chloride)) with Prussian Blue[J]. Chinese Journal of Polymer Science, ;2015, 33(7): 1038-1047. doi: 10.1007/s10118-015-1656-5 shu

Morphology and Thermoresponsive Behavior of Hybrid Micelles of Polystyrene-b-Poly((N-isopropyl acrylamide)-co-(4-vinylbenzyl chloride)) with Prussian Blue

Received Date: 6 November 2014
Revised Date: 27 November 2014

Fund Project: This work was financially supported by the National Natural Science Foundation of China (No. 21274130).

The hybrid micelles of polystyrene-b-poly((N-isopropyl acrylamide)-co-(4-vinylbenzyl chloride)) block copolymer (PS-b-P(NIPAM-co-VBC)) with Prussian blue (PB) in the corona were prepared by reaction of pentacyano(4-(dimethylamino)-pyridine)ferrate (Fe-DMAP)-attached PS-b-P(NIPAM-co-VBC) with FeCl3. The formation of the PB framework inside the micelles was verified by UV-Vis, FTIR and TGA. The morphology of the hybrid micelles was studied by TEM and compared with that of the neat and Fe-DMAP-attached PS-b-P(NIPAM-co-VBC). It is found that attachment of Fe-DMAP may change the short rod-like micelles of the neat PS-b-P(NIPAM-co-VBC) into spherical ones and lead to a smaller micelle size. The morphology of the hybrid micelles may be altered or remain unchanged after formation of the PB framework, depending on the chain structure of PS-b-P(NIPAM-co-VBC) and starting concentration. The thermoresponsive behavior of different micelles was studied using DLS. It is observed that attachment of Fe-DMAP can improve the hydrophilicity of the P(NIPAM-co-VBC) block, leading to weaker hysteresis of the micelle size during the heating and cooling cycle. However, the crosslinked PB framework in the micellar corona may result in a more evident hysteresis phenomenon and blur the two-stepwise change of the micellar size with temperature.
- Block copolymer,
- Thermosensitivity,
- Prussian blue,
- Micelle,
- Hybrid
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
33. [33]
34. [34]
35. [35]
36. [36]
37. [37]
38. [38]
39. [39]
40. [40]
41. [41]
42. [42]
43. [43]
1. [1]
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沈阳化工大学材料科学与工程学院沈阳 110142