Citation: Yong Shen, Zhibo Li, Harm-Anton Klok. Polypeptide Brushes Grown via Surface-initiated Ring-opening Polymerization of -Amino Acid N-Carboxyanhydrides[J]. Chinese Journal of Polymer Science, ;2015, 33(7): 931-946. doi: 10.1007/s10118-015-1654-7 shu

Polypeptide Brushes Grown via Surface-initiated Ring-opening Polymerization of -Amino Acid N-Carboxyanhydrides

Yong Shen ¹ ,
Zhibo Li ^2,3,4 ,
Harm-Anton Klok ⁵

1.
Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
2.
1. School of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
3.
2. Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
4.
5.
É

Received Date: 16 March 2015
Revised Date: 22 March 2015

Fund Project: This work was financially supported by the Sino-Swiss Science and Technology Cooperation (No. EG41-092011) as well as the Chinese Academy of Sciences (Visiting Professorship for Senior International Scientists to H.A.K.).

Polypeptide brushes are attractive platforms to generate functional and responsive interfaces that are of potential interest due to their possible biodegradability, biocompatibility and tunable secondary structures. Surface-initiated ring-opening polymerization (SI-ROP) of -amino acid N-carboxyanhydrides represents a powerful and versatile strategy to generate polypeptide brushes. This review is an attempt to capture the state-of-the-art in this field and highlights the latest developments in several selected areas. In addition to presenting an overview of the synthetic methods that have been used to generate polypeptide brushes via SI-ROP, this article will discuss the preparation of patterned polypeptide brushes, the conformational properties of surface-tethered polypeptides, ways to control chain orientation at surfaces as well as properties and applications of these thin polymer films.
- Polypeptide brushes,
- Surface,
- -Amino acid N-carboxyanhydrides,
- Ring-opening polymerization,
- Secondary structure
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