Citation: Long-mei Wu, Shuang-quan Liao, Sheng-jun Zhang, Xiao-ying Bai, Xue Hou. Enhancement of Mechanical Properties of Natural Rubber with Maleic Anhydride Grafted Liquid Polybutadiene Functionalized Graphene Oxide[J]. Chinese Journal of Polymer Science, ;2015, 33(7): 1058-1068. doi: 10.1007/s10118-015-1652-9 shu

Enhancement of Mechanical Properties of Natural Rubber with Maleic Anhydride Grafted Liquid Polybutadiene Functionalized Graphene Oxide

1.
College of Agriculture, Hainan University, Haikou 570228, China
2.
College of Materials and Chemical Engineering, Hainan University, Haikou 570228, China

Received Date: 29 November 2014
Revised Date: 25 February 2015

Fund Project: This work was financially supported by the National Natural Science Foundation of China (No. 51363006), Science and Technology innovation key project of Hainan province (No. ZDXM20120090), National Science and Technology support project (No. 2013BAF08B02).

An effective procedure has been developed to synthesize the functionalized graphene oxide grafted by maleic anhydride grafted liquid polybutadiene (MLPB-GO). Fourier transform spectroscopy and X-ray photoelectron spectroscopy indicate the successful functionalization of GO. The NR/MLPB-GO composites were then prepared by the co-coagulation process. The results show that the mechanical properties of NR/MLPB-GO composites are obviously superior to those of NR/GO composites and neat NR. Compared with neat NR, the tensile strength, modulus at 300% strain and tear strength of NR composite containing 2.12 phr MLPB-GO are significantly increased by 40.5%, 109.1% and 85.0%, respectively. Dynamic mechanical analysis results show that 84% increase in storage modulus and 2.9 K enhancement in the glass transition temperature of the composite have been achieved with the incorporation of 2.12 phr MLPB-GO into NR. The good dispersion of GO and the strong interface interaction in the composites are responsible for the unprecedented reinforcing efficiency of MLPB-GO towards NR.
- Enhancement,
- Maleic anhydride-grafted liquid polybutadiene,
- Graphene oxide,
- Composites,
- Mechanical properties
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沈阳化工大学材料科学与工程学院沈阳 110142