Citation: Ismail A. Alkskas, Bashir A. El-gnidi, Khadija M. Ghalieo, Faizul Azam. Synthesis and Characterization of Polyesters Based on Diethylketone Moiety[J]. Chinese Journal of Polymer Science, ;2014, 32(11): 1450-1459. doi: 10.1007/s10118-014-1531-9 shu

Synthesis and Characterization of Polyesters Based on Diethylketone Moiety

1.
Polymer Lab, Department of Chemistry, Faculty of Science, Misurata University, Misurata, P.O. Box 2247, Libya
2.
Faculty of Pharmacy, Misurata University, Misurata, Libya

Corresponding author: Ismail A. Alkskas,
Received Date: 3 January 2013
Revised Date: 10 February 2014

A new class of unsaturated polyesters based on diethylketone have been prepared by interfacial polymerization of 2, 4-bis(4-hydroxybenzylidene)-3-pentanone (Ⅰ) and 2, 4-bis(4-hydroxy-3-methoxybenzylidene)-3-pentanone (Ⅱ) with 4, 4'-azodibenzoyl chloride and 3, 3'-azodibenzoyl chloride at ambient temperature. The model compounds were synthesized by reaction of (Ⅰ) and (Ⅱ) with benzoyl chloride. The new monomers, model compounds and polyesters have been characterized by different spectral analyses. The polyesters have inherent viscosity of 0.55-0.80 dL/g and moderate number average molecular weight (Mn) in the range of 6150-7400 g/mol. Most of the compounds exhibited their solubility in aprotic solvents while partial solubility in various halogenated organic solvents was observed. The temperatures of 10% weight loss were high (225-330℃) in nitrogen, indicating that these polyesters have excellent thermal stability. Doping with iodine dramatically raised the conductivity and produced brown colored semiconductive polymers with a maximum conductivity of 2.7 10-6 -1cm-1. Moreover, the morphological properties of selected example of polyesters were detected by SEM.
- Diethylketone,
- Azo,
- Polyesters,
- Conductivity
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