Citation: Zhong-qiu Tong, Hai-ming Lv, Jiu-peng Zhao, Yao Li. Near-infrared and Multicolor Electrochromic Device Based on Polyaniline Derivative[J]. Chinese Journal of Polymer Science, ;2014, 32(8): 1040-1051. doi: 10.1007/s10118-014-1483-0 shu

Near-infrared and Multicolor Electrochromic Device Based on Polyaniline Derivative

1.
Center for Composite Materials and Structure, Harbin Institute of Technology, Harbin 150001, China
2.
School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin 150001, China

Received Date: 22 November 2013
Revised Date: 13 March 2014

Fund Project: This work was financially supported by the National Natural Science Foundation of China (Nos. 51010005, 91216123 and 51174063), Natural Science Funds for Distinguished Young Scholar of Heilongjiang Province and the project of International Cooperation supported by Ministry of Science and Technology of China (2013DFR10630).

Electroactive conducting copolymers of aniline (ANI) and diphenylamine (DPA) are prepared on indium tin oxide (ITO) surface from 1 mol/L H2SO4 aqueous solution with different feed ratios of ANI to DPA by using a potentiostatic method. FTIR spectra and SEM measurements are used to confirm the formation of copolymers. Due to the combination of the N,N-diphenyl benzidine and aniline units in the molecular chain, the copolymer films exhibit improved electrochemical and electrochromic properties, compared to PANI and PDPA. The copolymer [marked as P(ANI9-co-DPA1)] film prepared at a ratio of 9:1 (ANI/DPA) exhibits novel transmittance modulation both in visible and near-infrared (NIR) region between -0.8 V and 0.8 V (52% and 67% respectively) and fast response time (3.6 s for coloration and 2.3 s for bleaching at 600 nm). An electrochromic device (ECD) based on P(ANI9-co-DPA1) and PEDOT:PSS is also fabricated and shows a multicolor electrochromic performance, with a good optical contrast (29% in visible region and 40% in NIR region), acceptable response time (8.3 s for coloration and 7.5 s for bleaching at 600 nm) and long-term stability. Clear color changes from transparent (-0.8 V), bright green (0 V), seagreen (0.4 V) to dark slate gray (0.8 V) are demonstrated.
- Conjugated polymer,
- Spectroelectrochemistry,
- Electrochromic device,
- Polyaniline
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沈阳化工大学材料科学与工程学院沈阳 110142