Citation: Xu Jiang, Bing-chang Li, Yong-hui Song, Zhi-liang Gao, Bei-bei Nan. Synthesis and Characterization of Polyaniline/Partially Phosphorylated Poly(vinyl alcohol) Nanoparticles[J]. Chinese Journal of Polymer Science, ;2014, 32(1): 35-42. doi: 10.1007/s10118-014-1390-4 shu

Synthesis and Characterization of Polyaniline/Partially Phosphorylated Poly(vinyl alcohol) Nanoparticles

1.
Research Institute of Energy Chemical Industry, Xianyang Vocational Technical College, Xianyang 712000, China
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Department of Energy engineering, Shaanxi Energy Institute, Xianyang 712000, China
3.
Research Center of Metallurgical Engineering &
4.
Research Institute of Shaanxi Yanchang Petroleum (group) Co. Ltd., Xi'an 710075, China

Received Date: 29 January 2013
Revised Date: 19 April 2013

The polyaniline/partially phosphorylated poly(vinyl alcohol)(PANI/P-PVA) nanoparticles were prepared by the chemical oxidative dispersion polymerization of aniline monomer in 0.5 mol/L HCl aqueous media with the partially phosphorylated poly(vinyl alcohol) (P-PVA) as the stabilizer and co-dopant. The PANI/P-PVA nanoparticles were characterized by transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR), thermal gravimetric analysis (TGA), X-ray diffraction (XRD), electrical conductivity measurements and re-dispersion stability testing. All the results were compared with the properties of the conventional polyaniline in the emeraldine salt form (PANI ES). It was found that the feeding ratio of P-PVA obviously affected the morphology, re-dispersion stability and electrical conductivity of the PANI/P-PVA nanoparticles. When the feeding ratio of P-PVA ranged from 40 wt% to 50 wt%, the PANI/P-PVA nanoparticles showed spherical shape with good uniformity, significant re-dispersion stability in aqueous media and good electrical conductivity.
- Conducting polyaniline,
- Phosphorylated poly(vinyl alcohol),
- Colloidal dispersion
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沈阳化工大学材料科学与工程学院沈阳 110142