Citation: Yong Zhang, Jia-jia Chen, Geng-hui Zhang, Bai-zhu Chen, Hu-sheng Yan. PREPARATION OF SINGLE-HOLE HOLLOW POLYMER NANOSPHERES BY RASPBERRY-LIKE TEMPLATE METHOD[J]. Chinese Journal of Polymer Science, ;2013, 31(2): 294-301. doi: 10.1007/s10118-013-1190-2 shu

PREPARATION OF SINGLE-HOLE HOLLOW POLYMER NANOSPHERES BY RASPBERRY-LIKE TEMPLATE METHOD

Received Date: 16 April 2012
Revised Date: 22 May 2012

Fund Project: This work was supported by the National Natural Science Foundation of China (No. 20974052) and the Natural Science Foundation of Tianjin Municipality (No. 09JCZDJC22900).

Single-hole hollow polymer nanospheres were fabricated by raspberry-like template method using graft-from strategy through atom transfer radical polymerization (ATRP). Nanometer-sized silica spheres were covalently attached onto the surfaces of micrometer-sized silica spheres. Crosslinked polymer shells on the nano-sized spheres outside the attached area were formed by graft-from strategy through ATRP. After removal of the silica cores, single-hole hollow crosslinked polymer nanospheres were obtained. In this strategy, most of ATRP monomers may be used and thus many functional groups can be easily incorporated into the single-hole hollow crosslinked polymer nanospheres.
- Single-hole
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