Citation: M. Yadollahi, H. Bouhendi, M.J. Zohuriaan-Mehr, K. Kabiri. SPECTRAL AND CHEMICAL MONITORING OF CYCLO-ADDITION REACTION OF CO2 WITH POLY(MMA-co-GMA) COPOLYMERS[J]. Chinese Journal of Polymer Science, ;2012, 30(5): 727-734. doi: 10.1007/s10118-012-1174-7 shu

SPECTRAL AND CHEMICAL MONITORING OF CYCLO-ADDITION REACTION OF CO2 WITH POLY(MMA-co-GMA) COPOLYMERS

Corresponding author: H. Bouhendi,
Received Date: 12 December 2011
Revised Date: 27 February 2012

This paper deals with the monitoring cyclo-addition of CO2 to methyl methacrylate (MMA)-glycidyl methacrylate (GMA) copolymers using spectral (1H-NMR and FTIR) and chemical (elemental analysis and titration) methods. Thus, poly(MMA-co-GMA), was first prepared via solution polymerization. The copolymer was then treated with CO2 gas flow in the presence of cetyltrimethyl ammoniumbromide as a catalyst. In terms of the carbonation reaction time, the terpolymer poly(MMA-co-GMA-co-2-oxo-1,3-dioxolane-4-yl-methyl methacrylate) was prepared in various yield of CO2 fixation ( 90%). The peak intensity changes in the 1H-NMR and FTIR spectra provided excellent demonstrative techniques to monitor the carbonation reaction progression. In a comparative analytical viewpoint, the NMR and elemental analysis were recognized to be the most accurate ways to follow the cyclo-addition reaction progression. However, titration was recognized to be the most preferred method, because it is a very inexpensive, facile and available method with a reasonable cost-accuracy balance.
- Carbon dioxide
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