Citation: Wei-Cheng Xiong, Li Chen, Bin Zhao, De-Yi Wang, Yu-Zhong Wang. POLYAMIDE 6 WITH A FLAME RETARDANT ENCAPSULATED BY POLYAMIDE 66: FLAME RETARDATION, THERMO-DECOMPOSITION AND THE POTENTIAL MECHANISM[J]. Chinese Journal of Polymer Science, ;2012, 30(2): 297-307. doi: 10.1007/s10118-012-1126-2 shu

POLYAMIDE 6 WITH A FLAME RETARDANT ENCAPSULATED BY POLYAMIDE 66: FLAME RETARDATION, THERMO-DECOMPOSITION AND THE POTENTIAL MECHANISM

Received Date: 30 May 2011
Revised Date: 14 July 2011

Fund Project: This work was financially supported by the Key Project of National Science Foundation of China (No. 50933005) and Program for Changjiang Scholars and Innovative Research Team in University (IRT. 1026).

A novel encapsulated flame retardant containing phosphorus-nitrogen (MSMM-Al-P) was prepared by encapsulating with polyamide 66 (PA66-MSMM-Al-P) for the flame retardation of polyamide 6 (PA6). The structure and thermal properties of PA66-MSMM-Al-P were characterized by Fourier-transform infrared spectroscopy, X-ray photoelectron spectroscopy and thermogravimetric analysis. The flammability of PA6 containing flame retardants (MSMM-Al-P and PA66-MSMM-Al-P) was investigated by the limiting oxygen index test, vertical burning test and cone calorimeter. The flame retardancy and cone calorimetric analyses suggested a synergistic effect between PA66 and MSMM-Al-P in the flame-retardant PA6. Thermal stability of the flame-retardant PA6 was also investigated.
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