Citation: Shadpour Mallakpour, Mehdi Hatami. NEW COHORT OF OPTICALLY ACTIVE NANOSTRUCTURE POLY(AMIDEIMIDE) S: PRODUCTION AND PROPERTIES[J]. Chinese Journal of Polymer Science, ;2011, 29(6): 639-649. doi: 10.1007/s10118-011-1077-z shu

NEW COHORT OF OPTICALLY ACTIVE NANOSTRUCTURE POLY(AMIDEIMIDE) S: PRODUCTION AND PROPERTIES

Shadpour Mallakpour ^, ,
Mehdi Hatami

Corresponding author: Shadpour Mallakpour,
Received Date: 9 October 2010
Revised Date: 18 November 2010

Novel aromatic-aliphatic poly(amide-imide)s containing chiral units in the main chain and hydroxyl benzamide units in the side chain have been obtained from the step-growth polymerization of 3,5-diamino-N-(4-hydroxyphenyl) benzamide (2) with different chiral diacid chlorides (1a-1e). Theoretical calculations were done by means of computational chemistry methods to narrate the stable conformation and orientation of each diacid chloride monomers under reaction conditions. These polymers were characterized by conventional techniques. The resulting polymers show good thermal stability. Other physical properties of polymers including crystallinity, inherent viscosity and morphological characteristics were also studied.
- Optically active poly(amide-imide)s,
- Amino acid,
- Benzamide units,
- Nano scale
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