Citation: Lai-bao Zhang, Yi-xian Wu, Peng Zhou, Guan-ying Wu, Wan-tai Yang, Ding-sheng Yu. Synthesis of Highly Reactive Polyisobutylenes with BF3Cyclohexanol Initiating System[J]. Chinese Journal of Polymer Science, ;2011, 29(3): 360-367. doi: 10.1007/s10118-011-1042-x shu

Synthesis of Highly Reactive Polyisobutylenes with BF3Cyclohexanol Initiating System

Received Date: 19 April 2010
Revised Date: 16 June 2010

The selective cationic polymerization of isobutylene (IB) initiated by a BF3-20C. The effects of CL concentration, BF3 concentration, solvent for preparing BF3-3600) polyisobutylenes (PIBs) with large proportion of exo-double bond end groups were obtained.The exo-double bond content in PIB chain ends increased by increasing CL concentration or by decreasing solvent polarity in initiating system, BF3 concentration and polymerization time. The Mn and MWD of the resulting PIBs were dependent on the concentrations of CL and BF3. Highly reactive PIBs with around 90 mol% of exo-double bonds were successfully synthesized by the selective polymerization of IB from the mixed C4 fraction feed, providing a potentially practical process for its simplicity and low costs.CL complex and polymerization time on the chemical structure of end groups, number-average molecular weight (Mn) and molecular weight distribution (MWD, Mw/Mn) of the resulting polymers were investigated. The experimental results indicate that the BF3CL complex initiating system exhibited an extremely high selectivity toward the cationic polymerization of IB in the mixed C4 fraction feed and low molecular weight (Mn = 900cyclohexanol (CL) complex was carried out from the mixed C4 fraction feed containing the 4C saturated and unsaturated hydrocarbons at
- Reactivity,
- Polyisobutylene,
- Initiator,
- Cationic polymerization
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