Citation: Ji-ming Chen a, b, Zai-jun Lu a, Guang-qin Pan b, Yong-xin Qi b, Jian-jun Yi b, Hai-jian Bai b. SYNTHESIS OF HYDROXYL-TERMINATED POLYBUTADIENE POSSESSING HIGH CONTENT OF 1,4-UNITS VIA ANIONIC POLYMERIZATION[J]. Chinese Journal of Polymer Science, ;2010, 28(5): 715-720. doi: 10.1007/s10118-010-9121-y shu

SYNTHESIS OF HYDROXYL-TERMINATED POLYBUTADIENE POSSESSING HIGH CONTENT OF 1,4-UNITS VIA ANIONIC POLYMERIZATION

Received Date: 17 August 2009
Revised Date: 2 October 2009

The hydroxyl-terminated polybutadiene (HTPB) possessing high content of 1,4-units was synthesized by anionic polymerization of butadiene, using alkyllithium containing silicon-protected hydroxyl group as initiator and cyclohexane as solvent. The polymers were characterized by GPC, IR and 1H-NMR. The mechanical properties of cured films were also evaluated. The results show that the content of 1,4-units for HTPBs made by anionic polymerization reaches up to 90%. The molecular weight distribution is very narrow (≤ 1.05). The functionality of hydroxyl groups approaches 2. Compared with free radical HTPB, the elongation at break of anionic HTPB films increased by 70%, while the tensile strength remained nearly unchanged. This new HTPB can be very useful in solid propellant.
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