Citation: Ibrahim Erol, Cemal Cifci. SYNTHESIS AND CHARACTERIZATION OF A METHACRYLATE POLYMER WITH SIDE CHAIN KETONE AND ITS DERIVATIVES[J]. Chinese Journal of Polymer Science, ;2011, 29(1): 101-110. doi: 10.1007/s10118-010-1005-7 shu

SYNTHESIS AND CHARACTERIZATION OF A METHACRYLATE POLYMER WITH SIDE CHAIN KETONE AND ITS DERIVATIVES

Received Date: 30 December 2009
Revised Date: 8 February 2010

A new type of methacrylate monomer, 2-(4-benzoylphenoxy)-2-oxoethyl methylacrylate (BOEMA) was synthesized. The radical homopolymerization of BOEMA was performed at 65C in a 1,4-dioxane solution with benzoyl peroxide as an initiator. The oxime and thiosemicarbazone derivatives of poly[2-(4-benzoylphenoxy)-2-oxoethyl methylacrylate] poly(BOEMA) were prepared with hydroxylamine hydrochloride, and thiosemicarbazone hydrochloride, respectively. The monomer and its homopolymer were characterized with Fourier transform infrared and NMR techniques. The thermal stabilities of poly(BOEMA) and its derivatives were investigated with thermogravimetric analysis and differential scanning calorimetry. The ultraviolet stability of the polymers was compared. The antibacterial and antifungal effects of the monomer and the polymer and its derivatives were also investigated on various bacteria and fungi. The activation energies of the thermal degradation of the polymers were calculated with the Ozawa and Kissinger methods.
- Acetyl group,
- Ethylene dimethacrylate,
- Oxime,
- Thermal stability,
- Biological activity,
- Activation energies
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