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2005 Volume 16 Issue 1
2005, 16(1): 1-3
Abstract:
4-Amino-5-(pyridin-3-yl)-4H-1,2,4-triazole-3-thiol 1 were condensed with 2-bromo-1-(substituted phenyl) ethanone to give pyridinyltriazolothiadiazines 2a~c, which were quaternarized with methyl iodide and oxidized with 30% hydrogen peroxide to afford the corresponding methyl pyridinium salts 3a~c and pyridine-l-oxides 4a~c, respectively. The reduction of compounds 3 and 4 with NaBH4 in methanol produced the target compounds 1-methyl-1, 2, 5, 6-tetrahydropyridin-3-yl)-6-aryl-s-triazolothiadiazines 5a~c and 3-(1-hydroxyl-1, 2, 5, 6-tetrahydropyridin-3-yl)-6-aryl-s-triazolothiadiazines 6a~c, respectively. The endothelium vascular relaxing activity of the target compounds was screened.
4-Amino-5-(pyridin-3-yl)-4H-1,2,4-triazole-3-thiol 1 were condensed with 2-bromo-1-(substituted phenyl) ethanone to give pyridinyltriazolothiadiazines 2a~c, which were quaternarized with methyl iodide and oxidized with 30% hydrogen peroxide to afford the corresponding methyl pyridinium salts 3a~c and pyridine-l-oxides 4a~c, respectively. The reduction of compounds 3 and 4 with NaBH4 in methanol produced the target compounds 1-methyl-1, 2, 5, 6-tetrahydropyridin-3-yl)-6-aryl-s-triazolothiadiazines 5a~c and 3-(1-hydroxyl-1, 2, 5, 6-tetrahydropyridin-3-yl)-6-aryl-s-triazolothiadiazines 6a~c, respectively. The endothelium vascular relaxing activity of the target compounds was screened.
2005, 16(1): 4-6
Abstract:
Grubbs' catalyst was used to prepare a series of carbosilane dendrimers with silacyclopentene peripheral groups. It was found that ring closing metathesis reaction was influenced strongly by the reaction temperature and the amount of catalyst.
Grubbs' catalyst was used to prepare a series of carbosilane dendrimers with silacyclopentene peripheral groups. It was found that ring closing metathesis reaction was influenced strongly by the reaction temperature and the amount of catalyst.
2005, 16(1): 7-10
Abstract:
The reactions of cryptotanshinone and tanshinone ⅡA with cadaverine and putrescine were investigated. Six new compounds, four with imidazole functional groups and two with oxazole groups, were obtained. The possible reaction mechanism was proposed.
The reactions of cryptotanshinone and tanshinone ⅡA with cadaverine and putrescine were investigated. Six new compounds, four with imidazole functional groups and two with oxazole groups, were obtained. The possible reaction mechanism was proposed.
2005, 16(1): 11-14
Abstract:
Two series of territrem B analogues (10a-10c and 18) have been designed and synthesized from jujubogenin 5a which was prepared from jujubogenin glycosides 5b obtained from the leaves of Zizyphus jujuba. The structures of the new compounds were confirmed by 1H-,13C-NMR and MS data. Compounds 10c and 18 showed weak inhibitory effect on AChE at 10-4mol/L.
Two series of territrem B analogues (10a-10c and 18) have been designed and synthesized from jujubogenin 5a which was prepared from jujubogenin glycosides 5b obtained from the leaves of Zizyphus jujuba. The structures of the new compounds were confirmed by 1H-,13C-NMR and MS data. Compounds 10c and 18 showed weak inhibitory effect on AChE at 10-4mol/L.
2005, 16(1): 15-16
Abstract:
(-)-cis-1, 3-Dibenzyl-hexahydrofuro[3, 4-d]imidazole-2, 4-dione was prepared by a new synthesis method from meso dicarboxylic acid and dehydroabietylamine by asymmetric reduction in good yield with up to 91.6% e.e. value.
(-)-cis-1, 3-Dibenzyl-hexahydrofuro[3, 4-d]imidazole-2, 4-dione was prepared by a new synthesis method from meso dicarboxylic acid and dehydroabietylamine by asymmetric reduction in good yield with up to 91.6% e.e. value.
2005, 16(1): 17-19
Abstract:
Eleven (S)-(-)-bishydrocarbyl-(1-alkanoylpyrrolidin-2-yl)-methanol derivatives of three types were synthesized from L-proline, asymmtrically selective alkylation products were obtained by LDA treatment and alkylation using methyl 2-bromoethyl ether, and three types of chiral α-substituted-γ-butyrolactones were obtained by hydrolyzing the alkylation products, with%e.e.being up to 89 percent.
Eleven (S)-(-)-bishydrocarbyl-(1-alkanoylpyrrolidin-2-yl)-methanol derivatives of three types were synthesized from L-proline, asymmtrically selective alkylation products were obtained by LDA treatment and alkylation using methyl 2-bromoethyl ether, and three types of chiral α-substituted-γ-butyrolactones were obtained by hydrolyzing the alkylation products, with%e.e.being up to 89 percent.
2005, 16(1): 20-22
Abstract:
6, 9, 11-Trihydroxy-6a, 12a-dehydrorotenoid 1 (coccineone B) was synthesized from 2-hydroxybenzaldehyde 2 and phloroglucinol.
6, 9, 11-Trihydroxy-6a, 12a-dehydrorotenoid 1 (coccineone B) was synthesized from 2-hydroxybenzaldehyde 2 and phloroglucinol.
2005, 16(1): 23-26
Abstract:
Optically pure L-butyl lactate was synthesized by normal transesterification using nafion-H catalyst in moderate yield. Various reaction conditions were investigated, including the reaction temperature, reaction time, ratio of the starting material and amount of the nafion catalyst.
Optically pure L-butyl lactate was synthesized by normal transesterification using nafion-H catalyst in moderate yield. Various reaction conditions were investigated, including the reaction temperature, reaction time, ratio of the starting material and amount of the nafion catalyst.
2005, 16(1): 27-30
Abstract:
The EDTA dianhydride reacted with diazacrown ethers to obtain the water-soluble EDTA-diazacrown ether polymers 1~3. The effects of crown ether ring in the polymer chains including its cavity size on the solubilization of barium sulfate to water were investigated by comparison with the crown ring-free analogue 4. The result shows that the polymer 2 is the efficient solubilizer of BaSO4 and the highest solubilization efficiency of the BaSO4 to water is up to 72.5%.
The EDTA dianhydride reacted with diazacrown ethers to obtain the water-soluble EDTA-diazacrown ether polymers 1~3. The effects of crown ether ring in the polymer chains including its cavity size on the solubilization of barium sulfate to water were investigated by comparison with the crown ring-free analogue 4. The result shows that the polymer 2 is the efficient solubilizer of BaSO4 and the highest solubilization efficiency of the BaSO4 to water is up to 72.5%.
2005, 16(1): 31-34
Abstract:
Three peptide alcohols and four peptidyl N-akyl-amides were prepared by a series-connection procedure consisting of n-1 sequencial assembly on solid support followed by ammonolysis with glycinol, benzylamine or n-butylamine, and successive extractionelution through C-18 layer. All products were obtained from this procedure without further purification,in an overall yield of 75-86%.
Three peptide alcohols and four peptidyl N-akyl-amides were prepared by a series-connection procedure consisting of n-1 sequencial assembly on solid support followed by ammonolysis with glycinol, benzylamine or n-butylamine, and successive extractionelution through C-18 layer. All products were obtained from this procedure without further purification,in an overall yield of 75-86%.
2005, 16(1): 35-37
Abstract:
The novel organometallic compounds, 3-[4' (or 2')-(4"-fluorophenyl)] phenyl-1-ferrocenyl-2-propen-1-ones 5 were synthesized for nonlinear optical chromophores by Pd (0) catalyzed Suzuki cross-coupling reaction. Their structures were established with elemental analysis, MS, IR and 1H NMR spectroscopies.
The novel organometallic compounds, 3-[4' (or 2')-(4"-fluorophenyl)] phenyl-1-ferrocenyl-2-propen-1-ones 5 were synthesized for nonlinear optical chromophores by Pd (0) catalyzed Suzuki cross-coupling reaction. Their structures were established with elemental analysis, MS, IR and 1H NMR spectroscopies.
2005, 16(1): 38-40
Abstract:
Four 10-propionyl docetaxel analogues (11a-d) with 2α-amido substituents were prepared, and their antitumor activity against three solid tumor cell lines and their drug-resistant counterparts were determined.
Four 10-propionyl docetaxel analogues (11a-d) with 2α-amido substituents were prepared, and their antitumor activity against three solid tumor cell lines and their drug-resistant counterparts were determined.
2005, 16(1): 41-44
Abstract:
Hybrid polymers, poly (vinyl pyrrolidone-co-isobutyl styryl polyhedral oligomeric silsesquioxanes)s (PVP-POSS) were synthesized by one step polymerization and characterized using GPC and DSC. Addition of POSS significantly increases the Tg of polyvinylpyrrolidone at a fair high POSS content and obtained high molecular weight polymers with very narrow molecular distribution. The POSS content in the resulted hybrids can be controlled by varying the POSS feed ratio.
Hybrid polymers, poly (vinyl pyrrolidone-co-isobutyl styryl polyhedral oligomeric silsesquioxanes)s (PVP-POSS) were synthesized by one step polymerization and characterized using GPC and DSC. Addition of POSS significantly increases the Tg of polyvinylpyrrolidone at a fair high POSS content and obtained high molecular weight polymers with very narrow molecular distribution. The POSS content in the resulted hybrids can be controlled by varying the POSS feed ratio.
2005, 16(1): 45-48
Abstract:
Three polymerizable vinyl thiamphenicol esters with different acyl donor carbon chain length (C4, C6, C10) were regioselectivly synthesized by Lipozyme® (immobilized from mucor miehei) in acetone at 50℃ for 12 h to give 73%, 81%, 63% yield, respectively. The products were valuable monomers for preparation of macromolecular antibiotic.
Three polymerizable vinyl thiamphenicol esters with different acyl donor carbon chain length (C4, C6, C10) were regioselectivly synthesized by Lipozyme® (immobilized from mucor miehei) in acetone at 50℃ for 12 h to give 73%, 81%, 63% yield, respectively. The products were valuable monomers for preparation of macromolecular antibiotic.
2005, 16(1): 49-52
Abstract:
A new sesquiterpenoid lactone, 3,6,9-trimethyl-pyrano[2,3,4-de] chromen-2-one (1) and a novel sesquiterpenoid quinone, 6-[2-(5-acetyl-2,7-dimethyl-8-oxo-bicyclo [4.2.0] octa-l,3,5-trien-7-yl)-2-oxo-ethyl]-3,9-dimethylnaphtho[1,8-bc]pyran-7,8-dione (2) together with a known perezone (3) were isolated from the roots of Helicteres angustifolia. The structures were elucidated as mainly on the basis of 1D and 2D NMR spectroscopic data.
A new sesquiterpenoid lactone, 3,6,9-trimethyl-pyrano[2,3,4-de] chromen-2-one (1) and a novel sesquiterpenoid quinone, 6-[2-(5-acetyl-2,7-dimethyl-8-oxo-bicyclo [4.2.0] octa-l,3,5-trien-7-yl)-2-oxo-ethyl]-3,9-dimethylnaphtho[1,8-bc]pyran-7,8-dione (2) together with a known perezone (3) were isolated from the roots of Helicteres angustifolia. The structures were elucidated as mainly on the basis of 1D and 2D NMR spectroscopic data.
2005, 16(1): 53-56
Abstract:
A nonasaccharide saponin, new hederagenin saponin, had been isolated from the bark of Kalopanax septemlobus (Thunb.) Koidz., and its structure was elucidated by HRESI-MS, NMR experiments and chemical analyses as 3-O-β-D-xylopyranosyl-(1→4)-β-D-xylopyranosyl-(1→3)-α-L-rhamnopyranosyl-(1→2)-α-L-arabinopyranosyl hederagenin 28-O-β-D-xylopyranosyl-(1→3)-β-D-xylopyranosyl-(1→2)-[α-L-rhamnopyranosyl-(1→4)-β-D-glucopyranosyl-(1→6)]-β-D-glucopyranoside.
A nonasaccharide saponin, new hederagenin saponin, had been isolated from the bark of Kalopanax septemlobus (Thunb.) Koidz., and its structure was elucidated by HRESI-MS, NMR experiments and chemical analyses as 3-O-β-D-xylopyranosyl-(1→4)-β-D-xylopyranosyl-(1→3)-α-L-rhamnopyranosyl-(1→2)-α-L-arabinopyranosyl hederagenin 28-O-β-D-xylopyranosyl-(1→3)-β-D-xylopyranosyl-(1→2)-[α-L-rhamnopyranosyl-(1→4)-β-D-glucopyranosyl-(1→6)]-β-D-glucopyranoside.
2005, 16(1): 57-60
Abstract:
Three new diarylpropanes were isolated from the dried rhizomes of Dioscorea composita Hemsl., and their structures were determined as 1, 3-bis-(2-hydroxy-4-methoxyphenyl)propane (1), 1, 3-bis-(2, 4-dihydroxyphenyl)propane (2), 1-(2'-hydroxy-4'-O-β-D-glucopyranosyphenyl)-3-(2", 4"-dihydroxyphenyl)propane (3), by spectroscopic analysis, respectively.
Three new diarylpropanes were isolated from the dried rhizomes of Dioscorea composita Hemsl., and their structures were determined as 1, 3-bis-(2-hydroxy-4-methoxyphenyl)propane (1), 1, 3-bis-(2, 4-dihydroxyphenyl)propane (2), 1-(2'-hydroxy-4'-O-β-D-glucopyranosyphenyl)-3-(2", 4"-dihydroxyphenyl)propane (3), by spectroscopic analysis, respectively.
2005, 16(1): 61-63
Abstract:
Chemical investigation of Erigeron annus afforded two new eudesmenes, which were identified as 1β, 5α-dihydroxyeudesma-4 (15)-en (1) and 1β, 7α-dihydroxyeudesma-4 (15)-en (2).Their structures were established by spectroscopic methods including 2D NMR experiments.
Chemical investigation of Erigeron annus afforded two new eudesmenes, which were identified as 1β, 5α-dihydroxyeudesma-4 (15)-en (1) and 1β, 7α-dihydroxyeudesma-4 (15)-en (2).Their structures were established by spectroscopic methods including 2D NMR experiments.
2005, 16(1): 64-66
Abstract:
IrO2/Ta2O5 (70%:30%, molar ratio) electrodes (ITEs) were prepared by the thermal decomposition method. Typical "mud-cracked" surface and surface enrichment of Ta were observed. The determination of dopamine (DA) was carried out in the presence of ascorbic acid (AA). The detection limit of DA was 5×10-5 mol/L without the interference of AA.
IrO2/Ta2O5 (70%:30%, molar ratio) electrodes (ITEs) were prepared by the thermal decomposition method. Typical "mud-cracked" surface and surface enrichment of Ta were observed. The determination of dopamine (DA) was carried out in the presence of ascorbic acid (AA). The detection limit of DA was 5×10-5 mol/L without the interference of AA.
2005, 16(1): 67-70
Abstract:
A new method was developed for the determination of the size distribution of nano-particles by capillary zone electrophoresis (CZE). Scattering effect of nanoparticles was studied. This method for the determination of size distribution was statistical.
A new method was developed for the determination of the size distribution of nano-particles by capillary zone electrophoresis (CZE). Scattering effect of nanoparticles was studied. This method for the determination of size distribution was statistical.
2005, 16(1): 71-74
Abstract:
The interaction of cordycepin with calf thymus DNA was investigated at physiological pH with drug/DNA molar ratio of 8. The Raman spectroscopy results indicated that the intercalation of high concentration cordycepin and the interaction of cordycepin with PO2 group led to a major reduction of B-form DNA structure in favor of A-form DNA.
The interaction of cordycepin with calf thymus DNA was investigated at physiological pH with drug/DNA molar ratio of 8. The Raman spectroscopy results indicated that the intercalation of high concentration cordycepin and the interaction of cordycepin with PO2 group led to a major reduction of B-form DNA structure in favor of A-form DNA.
2005, 16(1): 75-77
Abstract:
The macromolecular structures on nitinol surfaces were prepared by ECR microwave cold-plasma of tetraglyme conditions. The surface chemistry was characterized by high resolution ESCA. The results showed that the modified nitinol surfaces were built up mainly of-CH2-CH2-O-linkages and were particularly effective in preventing platelet adhesion.
The macromolecular structures on nitinol surfaces were prepared by ECR microwave cold-plasma of tetraglyme conditions. The surface chemistry was characterized by high resolution ESCA. The results showed that the modified nitinol surfaces were built up mainly of-CH2-CH2-O-linkages and were particularly effective in preventing platelet adhesion.
2005, 16(1): 78-80
Abstract:
Crystals of Na-Pb-O and Na-Pb-Bi-O were electrosynthesized on the anode from molten salts. The resulting crystals have a hexagonal structure, in which the base ions (Pb and Bi) are in high oxidation states. By using KOH/NaOH (atomic ratio K:Na=1:1) mixture as a flux,incorporation of K ions into the lattice is inhibited while incorporation of Bi ions is enhanced. The magnetic measurement shows that the Na-Pb-Bi-O crystals are dominated by diamagnetism.
Crystals of Na-Pb-O and Na-Pb-Bi-O were electrosynthesized on the anode from molten salts. The resulting crystals have a hexagonal structure, in which the base ions (Pb and Bi) are in high oxidation states. By using KOH/NaOH (atomic ratio K:Na=1:1) mixture as a flux,incorporation of K ions into the lattice is inhibited while incorporation of Bi ions is enhanced. The magnetic measurement shows that the Na-Pb-Bi-O crystals are dominated by diamagnetism.
2005, 16(1): 81-84
Abstract:
Cleavage of DNA pUC19 by [Cu (saldien) (NH3)]Cl2 (here, saldien=bis (salicylicdene)-diethylenetriamine) was investigated at different pHs, times, concentrations, and 37℃. It was found that the copper (Ⅱ) complex could cleave DNA without added coreactants.
Cleavage of DNA pUC19 by [Cu (saldien) (NH3)]Cl2 (here, saldien=bis (salicylicdene)-diethylenetriamine) was investigated at different pHs, times, concentrations, and 37℃. It was found that the copper (Ⅱ) complex could cleave DNA without added coreactants.
2005, 16(1): 85-88
Abstract:
Two new compounds involving a thiophene moiety named as 2,5-bis [4-(N,N- diphenylamino) styryl]thiophene (BPST) and 2,5-bis [4-(N,N-diethylamino) styryl]thiophene (BEST) have been synthesized. The two-photon absorption cross section of BPST was measured as large as 256×10-50 cm4·s/photon, when it was excited by 800 nm femtosecond laser.
Two new compounds involving a thiophene moiety named as 2,5-bis [4-(N,N- diphenylamino) styryl]thiophene (BPST) and 2,5-bis [4-(N,N-diethylamino) styryl]thiophene (BEST) have been synthesized. The two-photon absorption cross section of BPST was measured as large as 256×10-50 cm4·s/photon, when it was excited by 800 nm femtosecond laser.
2005, 16(1): 89-92
Abstract:
Two novel high valent complexes [M2(Ⅲ, Ⅲ)L(μ-OAc)2]·PF6(M=Mn, Fe; 9) were prepared, where L was the tri-anion of 2,6-bis{[(2-hydroxy-3-(morpholin-4-yl methyl)-5-tert-butyl benzyl) (pyridyl-2-methyl)amino]methyl}-4-methyl phenol which contained additional phenolic, tert-butyl and morpholin-4-yl methyl groups compared to its parent [Mn2(Ⅱ, Ⅱ) (bpmp) (μ-OAc2)·CLO4 (10).These improvements decreascd the difference beteween the mew mode and (Mn)4 cluster (OEC in nature).
Two novel high valent complexes [M2(Ⅲ, Ⅲ)L(μ-OAc)2]·PF6(M=Mn, Fe; 9) were prepared, where L was the tri-anion of 2,6-bis{[(2-hydroxy-3-(morpholin-4-yl methyl)-5-tert-butyl benzyl) (pyridyl-2-methyl)amino]methyl}-4-methyl phenol which contained additional phenolic, tert-butyl and morpholin-4-yl methyl groups compared to its parent [Mn2(Ⅱ, Ⅱ) (bpmp) (μ-OAc2)·CLO4 (10).These improvements decreascd the difference beteween the mew mode and (Mn)4 cluster (OEC in nature).
2005, 16(1): 93-96
Abstract:
In this study, Mn (Ⅱ) as a mimetic enzyme of horseradish peroxidase (HRP) was applied to the determination of hydrogen peroxide (H2O2). The method introduced in this paper is based on Mn (Ⅱ)'s catalytic effect on the oxidation of 4-aminoantipyrine (4-AAP) with modified Trinder's reagent N-ethyl-N-(2-hydroxy-3-sulfopropyl)-3, 5-dimethoxyaniline (DAOS) by H2O2.By coupling this mimetic catalytic reaction with the catalytic reaction of glucose oxidase (GOD),glucose can be detected. Under optimum conditions, the calibration graphs for the determination of H2O2 and glucose are in the range of 1.0×10-3-1.0×10-1 mol/L and 1.0×10-3-14×10-3 mol/L respectively. The detection limit is 5.9×10-4 mol/L for H2O2 and is 9.2×10-4 mol/L for glucose.The feasibility of Mn (Ⅱ) as a HRP mimetic enzyme in practical clinical analysis has been proven in the determination of glucose in human serum. So far, Mn (Ⅱ) is the simplest and the most inexpensive mimetic enzyme.
In this study, Mn (Ⅱ) as a mimetic enzyme of horseradish peroxidase (HRP) was applied to the determination of hydrogen peroxide (H2O2). The method introduced in this paper is based on Mn (Ⅱ)'s catalytic effect on the oxidation of 4-aminoantipyrine (4-AAP) with modified Trinder's reagent N-ethyl-N-(2-hydroxy-3-sulfopropyl)-3, 5-dimethoxyaniline (DAOS) by H2O2.By coupling this mimetic catalytic reaction with the catalytic reaction of glucose oxidase (GOD),glucose can be detected. Under optimum conditions, the calibration graphs for the determination of H2O2 and glucose are in the range of 1.0×10-3-1.0×10-1 mol/L and 1.0×10-3-14×10-3 mol/L respectively. The detection limit is 5.9×10-4 mol/L for H2O2 and is 9.2×10-4 mol/L for glucose.The feasibility of Mn (Ⅱ) as a HRP mimetic enzyme in practical clinical analysis has been proven in the determination of glucose in human serum. So far, Mn (Ⅱ) is the simplest and the most inexpensive mimetic enzyme.
2005, 16(1): 97-99
Abstract:
A three-way catalyst comprised novel oxygen storage components for emission control in natural gas powered engines was prepared. The addition of novel oxygen storage components to the Pd/γ-A12O3 catalysts resulted in improved activities of the fresh and aged catalyst by lowering the light-off temperature for methane in natural gas engines exhaust.
A three-way catalyst comprised novel oxygen storage components for emission control in natural gas powered engines was prepared. The addition of novel oxygen storage components to the Pd/γ-A12O3 catalysts resulted in improved activities of the fresh and aged catalyst by lowering the light-off temperature for methane in natural gas engines exhaust.
2005, 16(1): 100-102
Abstract:
A Nd promoted-Rh catalysts supported on polymer-derived carbon beads for vapor-phase methanol carbonylation was developed. Rh-Nd bimetallic catalysts obviously have higher activity than that of supported Rh catalyst under similar reaction condition. The difference between the activity of above two catalyst systems is clearly caused by the intrinsic properties generated by the introduction of Nd.
A Nd promoted-Rh catalysts supported on polymer-derived carbon beads for vapor-phase methanol carbonylation was developed. Rh-Nd bimetallic catalysts obviously have higher activity than that of supported Rh catalyst under similar reaction condition. The difference between the activity of above two catalyst systems is clearly caused by the intrinsic properties generated by the introduction of Nd.
2005, 16(1): 103-106
Abstract:
The propylene epoxidation over TS-1/SiO2 catalyst hydrothermally treated was investigated. It was found by EPR characterization that two types of Ti (Ⅳ)-superoxide radicals,A (gz=2.0271; gy=2.0074; gx=2.0010) and B (gz=2.0247; gy=2.0074; gx=2.0010), were observed for TS-1/SiO2. The superoxo species A converted to B after TS-1/SiO2 catalyst was hydrothermally treated. The results show that over TS-1/SiO2 catalyst hydrothermally treated at 170℃, about 95% conversion of H2O2 with above 94% PO selectivity is obtained during continuous running for 300 h under the conditions of reaction temperature 45℃, 0.5 h-1 WHSV of propylene.
The propylene epoxidation over TS-1/SiO2 catalyst hydrothermally treated was investigated. It was found by EPR characterization that two types of Ti (Ⅳ)-superoxide radicals,A (gz=2.0271; gy=2.0074; gx=2.0010) and B (gz=2.0247; gy=2.0074; gx=2.0010), were observed for TS-1/SiO2. The superoxo species A converted to B after TS-1/SiO2 catalyst was hydrothermally treated. The results show that over TS-1/SiO2 catalyst hydrothermally treated at 170℃, about 95% conversion of H2O2 with above 94% PO selectivity is obtained during continuous running for 300 h under the conditions of reaction temperature 45℃, 0.5 h-1 WHSV of propylene.
2005, 16(1): 107-110
Abstract:
The viability and biological activity of Absidia coerulea in compressed or supercritical CO2 and C2H4 were studied. The specific activity ofAbsidia coerulea in 7.5MPa CO2 and C2H4 at 306K can reach to 23% and 75% respectively, leading to the feasibility of using supercritical C2H4as an alternative to the organic solvent in the hydroxylation of Reichsterin's substance acetate.
The viability and biological activity of Absidia coerulea in compressed or supercritical CO2 and C2H4 were studied. The specific activity ofAbsidia coerulea in 7.5MPa CO2 and C2H4 at 306K can reach to 23% and 75% respectively, leading to the feasibility of using supercritical C2H4as an alternative to the organic solvent in the hydroxylation of Reichsterin's substance acetate.
2005, 16(1): 111-114
Abstract:
The catalytic performance of a series of cobalt (Ⅱ) hydroxamates (CoL2) and the synergistic catalytic action of the cobalt complexes combined with N-hydroxyphthalimide (NHPI) in the aerobic oxidation of p-xylene to p-toluic acid (PTA) were investigated. The results showed that the existing synergistic action in the catalytic oxidation can shorten the induction period of the radical reaction and improve the yield of PTA.
The catalytic performance of a series of cobalt (Ⅱ) hydroxamates (CoL2) and the synergistic catalytic action of the cobalt complexes combined with N-hydroxyphthalimide (NHPI) in the aerobic oxidation of p-xylene to p-toluic acid (PTA) were investigated. The results showed that the existing synergistic action in the catalytic oxidation can shorten the induction period of the radical reaction and improve the yield of PTA.
2005, 16(1): 115-118
Abstract:
Catalytic properties of ZSM-5 zeolite samples pretreated with NaOH solution have been investigated. The samples are characterized by XRD, SEM, chemical analysis, and N2 adsorption.The results indicate that mesopores are created in ZSM-5 crystals under alkali treatment without change the microporous structure and acidic strength of the zeolite, but the crystallinity is greatly decreased under severe treatment. IR indicates that the concentration of silanol is greatly enriched by alkali treatment. The etherification activities of ZSM-5 zeolites are greatly increased by alkali-treatment. The noticeably improved catalytic activity of treated samples is ascribed to the formation of mesopores and greatly enriched silanol group.
Catalytic properties of ZSM-5 zeolite samples pretreated with NaOH solution have been investigated. The samples are characterized by XRD, SEM, chemical analysis, and N2 adsorption.The results indicate that mesopores are created in ZSM-5 crystals under alkali treatment without change the microporous structure and acidic strength of the zeolite, but the crystallinity is greatly decreased under severe treatment. IR indicates that the concentration of silanol is greatly enriched by alkali treatment. The etherification activities of ZSM-5 zeolites are greatly increased by alkali-treatment. The noticeably improved catalytic activity of treated samples is ascribed to the formation of mesopores and greatly enriched silanol group.
2005, 16(1): 119-122
Abstract:
A laser flash photolysis study of the reactivity of Cl with glyoxai, glyoxal mono-and dibisulfite adducts, 1-hydroxy-2, 2-diol-ethanesulfonate and 1, 2-dihydroxy-1, 2-ethanedi sulfonate in the aqueous phase was carried out. The obtained rate constants can be used for atmospheric modeling.
A laser flash photolysis study of the reactivity of Cl with glyoxai, glyoxal mono-and dibisulfite adducts, 1-hydroxy-2, 2-diol-ethanesulfonate and 1, 2-dihydroxy-1, 2-ethanedi sulfonate in the aqueous phase was carried out. The obtained rate constants can be used for atmospheric modeling.
2005, 16(1): 123-126
Abstract:
Biodegradable chitosan-g-poly (D, L-lactic acid) copolymers were prepared via two methods. (1) The lactide was grafted onto hydroxyl groups of chitosan by using macromolecular initiator sodium of trimethylsilyl-chitosan, (2) poly (D,L-lactic acid) (PLA) with low molecular weight can be linked to the amino group by coupling activated PLA to trimethylsilyl-chitosan. Two graft copolymers had hydrophilic-hydrophobic character and can be applied as carriers for drug delivery.
Biodegradable chitosan-g-poly (D, L-lactic acid) copolymers were prepared via two methods. (1) The lactide was grafted onto hydroxyl groups of chitosan by using macromolecular initiator sodium of trimethylsilyl-chitosan, (2) poly (D,L-lactic acid) (PLA) with low molecular weight can be linked to the amino group by coupling activated PLA to trimethylsilyl-chitosan. Two graft copolymers had hydrophilic-hydrophobic character and can be applied as carriers for drug delivery.
2005, 16(1): 127-130
Abstract:
A novel liquid crystal compound with a carboxyl group at one end, cholest-5-en-3-ol-(3β) hydrogen decanedioate (1) was successfuly prepared by the reaction of cholesterol with sebacoyl chloride. Its chemical structure and liquid crystalline properties were characterized by FTIR, 13CNMR, 1HNMR, POM and DSC. The compound with an active carboxyl group shows themortropic liquid crystalline behaviour.
A novel liquid crystal compound with a carboxyl group at one end, cholest-5-en-3-ol-(3β) hydrogen decanedioate (1) was successfuly prepared by the reaction of cholesterol with sebacoyl chloride. Its chemical structure and liquid crystalline properties were characterized by FTIR, 13CNMR, 1HNMR, POM and DSC. The compound with an active carboxyl group shows themortropic liquid crystalline behaviour.
2005, 16(1): 131-134
Abstract:
Effect of various counterions of tartrate on the crystallization of calcium oxalate in gel system was investigated using scanning electron microscopy and X-ray diffraction. Various tartrates with hydrogen (H2tart), sodium (Na2tart), potassium (K2tart), ammonium ((NH4)2tart), and a mixture of sodium and potassium cations (NaKtart) were considered. For H2tart, Na2tart, and (NH4)2tart, calcium oxalate dihydrate (COD) was induced. However, for K2tart and NaKtart,calcium oxalate trihydrate (COT) was obtained.
Effect of various counterions of tartrate on the crystallization of calcium oxalate in gel system was investigated using scanning electron microscopy and X-ray diffraction. Various tartrates with hydrogen (H2tart), sodium (Na2tart), potassium (K2tart), ammonium ((NH4)2tart), and a mixture of sodium and potassium cations (NaKtart) were considered. For H2tart, Na2tart, and (NH4)2tart, calcium oxalate dihydrate (COD) was induced. However, for K2tart and NaKtart,calcium oxalate trihydrate (COT) was obtained.
2005, 16(1): 135-138
Abstract:
Urease was immobilized onto the glutaraldehyde cross-linked chitosan beads that were prepared under microwave irradiation. The activity and the yield of activity of immobilized urease was 10.83 U/g B and 47.7%, respectively. The conditions of urease immobilization were optimized. The properties of the immobilized urease were investigated and compared with that of the free enzyme.
Urease was immobilized onto the glutaraldehyde cross-linked chitosan beads that were prepared under microwave irradiation. The activity and the yield of activity of immobilized urease was 10.83 U/g B and 47.7%, respectively. The conditions of urease immobilization were optimized. The properties of the immobilized urease were investigated and compared with that of the free enzyme.
2005, 16(1): 139-142
Abstract:
The small angle X-ray scattering of organically modified MSU-X silica prepared by co-condensation of tetraethoxysilane (TEOS) and methyltriethoxysilane (MTES) show negative deviation from Debye's theory due to the existence of the organic interface layer. By exerting correction of the scattering negative deviation, Debye relation may be recovered, and the average wall thickness of the material may be evaluated.
The small angle X-ray scattering of organically modified MSU-X silica prepared by co-condensation of tetraethoxysilane (TEOS) and methyltriethoxysilane (MTES) show negative deviation from Debye's theory due to the existence of the organic interface layer. By exerting correction of the scattering negative deviation, Debye relation may be recovered, and the average wall thickness of the material may be evaluated.
