2019 Volume 34 Issue 2

2019, 34(2):
[Abstract](1814) [FullText HTML] [PDF 296KB](7)
Abstract:
Introduction of Hypervalent Iodine Chemistry and Its Application
LIU Dan , HE Jiahao , ZHANG Chi
2019, 34(2): 1-16  doi: 10.3866/PKU.DXHX201806019
[Abstract](1566) [FullText HTML] [PDF 13411KB](82)
Abstract:
In recent decades, hypervalent iodine chemistry has witnessed its explosive development. Hypervalent iodine reagents have drawn considerable attentions and their reactivities have been continuously explored. Hypervalent iodine reagents, featuring fac...
Exploration on Innovative Teaching of Graduate Practical Course of “Chemical Power Manufacturing Engineering”
MA Yulin , CHENG Xinqun , HUO Hua , YIN Geping
2019, 34(2): 17-21  doi: 10.3866/PKU.DXHX201806007
[Abstract](1158) [FullText HTML] [PDF 1099KB](10)
Abstract:
The practice and innovation ability of professional masters are the important goal during the professional master training process. In this paper, the practice course of “chemical power manufacturing engineering” in Harbin Institute of Technology has...
A Preliminary Study on the Chemical Business Management Related Graduation Thesis of Applied Chemistry Major
TAO Hu , DING Liwen , ZHAI Longfei
2019, 34(2): 22-25  doi: 10.3866/PKU.DXHX201807008
[Abstract](1118) [FullText HTML] [PDF 336KB](12)
Abstract:
With the development modes of chemical industries in China being transformed from the simple capacity-expansion to comprehensive connotative development of manufacture, quality control, market and environmental protection, the importance for undergra...
Practical Exploration of Innovation and Teaching Skill Training for Teacher-Oriented Chemistry-Majoring Students
QUAN Zhengjun , LI Yan , WANG Xicun , YANG Zhiwang
2019, 34(2): 26-29  doi: 10.3866/PKU.DXHX201807019
[Abstract](1144) [FullText HTML] [PDF 570KB](16)
Abstract:
We focused on strengthening the cultivation of students' teaching practice ability and innovation ability through a variety of initiatives such as the plan for improving teachers' educational ability and the plan for enhancing scientific innovation a...
X-Ray Crystallography in General Education of University
SU Hao , WANG Pengfei , LI Hui
2019, 34(2): 30-36  doi: 10.3866/PKU.DXHX201806020
[Abstract](1143) [FullText HTML] [PDF 1893KB](18)
Abstract:
X-ray crystallography is the study of the structures of crystallized materials. X-ray diffraction analysis is the most important technology to measure and provide the more detailed structural information. In this paper, the brief history of X-ray cry...
The Scientific and Meticulous Preparation for Basic Chemistry Laboratory Teaching
ZHANG Chunyan , LÜ Yinyun , PAN Rui , WENG Yuhua , RUAN Chanzi , OUYANG Xiaoqing , DONG Zhiqiang , XU Zhenling , YAN Changming , REN Yanping
2019, 34(2): 37-43  doi: 10.3866/PKU.DXHX201807006
[Abstract](1176) [FullText HTML] [PDF 2169KB](22)
Abstract:
It is one of the contents of the connotation construction of laboratory construction and management to complete the meticulous preparation of basic chemistry experiments scientifically and provide more efficient services for the laboratory teaching. ...
Three Modes of Instrument Management in Basic Chemistry Laboratory
LAI Rong , XU Xianfang , ZHU Kejia , PENG Min , LI lianyun , WANG Zhou , ZHENG Saili , CHEN Liuping
2019, 34(2): 44-48  doi: 10.3866/PKU.DXHX201806012
[Abstract](1091) [FullText HTML] [PDF 651KB](10)
Abstract:
We present three management modes to enhance the management to the medium-scale and small-scale instruments in basic chemistry laboratory, such as the whole-process management, classification management and internet plus auxiliary management. These m...
Improving Experiment on Determining the Empirical Formula of Hexamine Cobalt(III) Chloride: Measuring the Chlorine Content by Potentiometric Titration
WANG Zhou , SHI Jianxin , PENG Min , ZHENG Saili , LI Lianyun , LAI Rong , ZHU Kejia
2019, 34(2): 49-54  doi: 10.3866/PKU.DXHX201806014
[Abstract](1282) [FullText HTML] [PDF 935KB](34)
Abstract:
The experiment on preparation and empirical formula determination of hexamine cobalt(Ⅲ) chloride is a comprehensive experiment in the basic chemistry laboratory. The coordination compound was prepared by the reaction of CoCl2 with H2O2 as the oxidant...
Discussion on the Derivation of Kelvin Formula by Isothermal Cycle Method
LIANG Jiashu , GUO Dongsheng
2019, 34(2): 55-60  doi: 10.3866/PKU.DXHX201807046
[Abstract](1184) [FullText HTML] [PDF 2142KB](23)
Abstract:
Isothermal cycle is a classical method to solve thermodynamic problems in physical chemistry textbooks. In this paper, it is pointed out that The Gibbs free energy change of the reversible phase transformation of the droplet into the gas should be gi...
Discussing on Criteria of Living Polymerization
GUO Lihua
2019, 34(2): 61-64  doi: 10.3866/PKU.DXHX201807040
[Abstract](1187) [FullText HTML] [PDF 1033KB](18)
Abstract:
Living polymerization, particularly the criteria of living polymerization, plays an important role in the course of polymer chemistry. In this paper, we summarize the criteria of living polymerization and analyze the sources of each criterion careful...
Deep Analysis and Teaching Practice on Diagram Data in Physical Chemistry: Taking the Chapter of Electrolyte Solution as an Example
XING Shuangxi , WANG Yiming
2019, 34(2): 65-69  doi: 10.3866/PKU.DXHX201811004
[Abstract](1141) [FullText HTML] [PDF 758KB](18)
Abstract:
Taking the chapter of electrolyte solution as an example, multiple kinds of treatments on the data listed in tables in physical chemistry textbook are introduced in this article. Data supplement, diagram with curves, data difference calculation and t...
Vision of Volumetric Titration Analysis
YIN Xuebo
2019, 34(2): 70-75  doi: 10.3866/PKU.DXHX201806033
[Abstract](1122) [FullText HTML] [PDF 2210KB](21)
Abstract:
Volumetric titration analysis is an important content of chemical analysis; but it is traditionally considered to use large amount sample, take long analysis time, have low sensitivity, and involve harsh analytical conditions. This paper provides per...
The Use of Subjunctive Mood in Chemical Literatures
ZHANG Wenqing , YANG Guang
2019, 34(2): 76-80  doi: 10.3866/PKU.DXHX201806015
[Abstract](1167) [FullText HTML] [PDF 354KB](19)
Abstract:
The subjunctive mood plays an important role in expressing wishes, doubts and uncertainties. In this paper, we analyze and summarize the use of subjunctive mood in several examples selected from chemical literatures. It is proposed that attention sho...
Study of Enzymatic Reaction with the Combination of Bioinformatics and Organic Chemistry: An Introduction and Discussion of an Undergraduate Experiment Abroad
TIAN Jie , WANG Zhipeng A. , MA Xinyu , JIANG Zhenxiong , XU Bing
2019, 34(2): 81-89  doi: 10.3866/PKU.DXHX201805027
[Abstract](1365) [FullText HTML] [PDF 2094KB](15)
Abstract:
The 21st century witnesses the most rapid development of life science and computer science. As the core of current scientific research, chemistry forms an integration in close combination with other subjects including biology and information science....
Problem Analysis for the Preliminary Test of the 32nd Chinese Chemistry Olympiad (Part I)
YU Zidi
2019, 34(2): 90-98  doi: 10.3866/PKU.DXHX2018110191
[Abstract](1649) [FullText HTML] [PDF 555KB](152)
Abstract:
The problems in the preliminary test of the 32nd Chinese Chemistry Olympiad were resolved. The problem-solving techniques and calculations were developed, and the background and bibliography involved were also provided.
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