2019 Volume 34 Issue 1

2019, 34(1):
[Abstract](419) [FullText HTML] [PDF 314KB](8)
Abstract:
A Brief Introduction to Nobel Prize in Chemistry 2018: Harnessing the Power of Evolution
ZHOU Ying , ZHU Liyuan , ZOU Peng
2019, 34(1): 1-6  doi: 10.3866/PKU.DXHX201811008
[Abstract](1273) [FullText HTML] [PDF 1715KB](58)
Abstract:
In living organisms, protein functions are constantly evolving over generations throughout the history. Through iterative rounds of genetic mutations and natural selection of fit phenotypes, protein functions have been gradually optimized. This proce...
Application of GB/T19001 Quality Management System in Management of Teaching Laboratory in Universities
KONG Xuanfeng , XI Zhonghua , YU Xiaodong
2019, 34(1): 7-13  doi: 10.3866/PKU.DXHX201804032
[Abstract](486) [FullText HTML] [PDF 408KB](13)
Abstract:
This paper introduces new practices in improving laboratory management system for teaching laboratory in universities. The novel practices are based on GB/T19001-2016 quality management system (QMS). The first principle as well as the term 9.1.2 and ...
Construction and Practice of Teaching Resources of Organic Chemistry Laboratory
CHENG Shaoling , YANG Yinghua , ZHANG Haili , MA Xiaohong
2019, 34(1): 14-17  doi: 10.3866/PKU.DXHX201805043
[Abstract](628) [FullText HTML] [PDF 342KB](12)
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The construction of teaching resources is an important work in university teaching reform. Aiming at improving the quality of laboratory teaching and cultivating students' creative ability, the discussion on the teaching resources of organic chemistr...
Construction of Chemical Biology Comprehensive Laboratory Teaching Material
CHEN Yuqing
2019, 34(1): 18-23  doi: 10.3866/PKU.DXHX201805023
[Abstract](564) [FullText HTML] [PDF 384KB](9)
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High quality laboratory teaching material is an important guarantee for undergraduate laboratory teaching and plays an important role in the cultivation of innovative talents. The article introduces the construction of comprehensive experimental teac...
Discussion on Introducing Amino Acid Metabolism into Bioorganic Chemistry and Chemical Biology Education
WANG Zhipeng A. , MA Xinyu , YAN Huijuan , TIAN Jie
2019, 34(1): 24-32  doi: 10.3866/PKU.DXHX201804024
[Abstract](781) [FullText HTML] [PDF 2347KB](14)
Abstract:
The manuscript starts from fundamental knowledge of amino acid metabolism, followed by the analysis of how and why we incorporate it into current biochemistry education. These metabolic processes containing different biochemical reaction mechanisms a...
Reasons for the Low Frictional Coefficient of Ice Surface: Progress and Model Analysis
WANG Guangzhen , WANG Wenliang , GAO Xin , ZHANG Shuyong
2019, 34(1): 33-38  doi: 10.3866/PKU.DXHX201805022
[Abstract](598) [FullText HTML] [PDF 701KB](22)
Abstract:
Low friction is the most outstanding feature of ice surface. The existence of liquid water on ice surface, which serves as lubricant, has been taken as the main cause for its low friction. Three main hypotheses for the formation of liquid water on ic...
Development of Carborane Chemistry
ZHAO Weijia , HE Jiajun , LU Changsheng
2019, 34(1): 39-47  doi: 10.3866/PKU.DXHX201805030
[Abstract](633) [FullText HTML] [PDF 2266KB](34)
Abstract:
Carboranes exhibit three-dimensional aromaticity as well as stable physical and chemical properties due to their unique molecular cages, which not only enable the wide application in organoboron and organometallic chemistry, but also result in increa...
Synthesis and Characterization of Tetraphenylethylene and Its Application for Explosive Detection: An Introduction of a Comprehensive Chemical Experiment
HE Tian , GU Zhengye , YIN Shouchun
2019, 34(1): 48-53  doi: 10.3866/PKU.DXHX201805007
[Abstract](534) [FullText HTML] [PDF 681KB](19)
Abstract:
Tetraphenylethylene and its derivatives with propeller structure have excellent fluorescence properties, which can be applied to the fields of organic photo-electric materials, fluorescence sensing and biological imaging due to the aggregation-induce...
Design and Application of Mobile-Phone Photometer Based on Light Sensor
XI Zhonghua , KONG Xuanfeng , YU Xiaodong , ZHANG Wenwei
2019, 34(1): 54-57  doi: 10.3866/PKU.DXHX201806029
[Abstract](598) [FullText HTML] [PDF 846KB](14)
Abstract:
By using the light sensor of smartphone, a simple photometer was designed. Also, an Android APP was developed to show the online signal and calculate the absorbance automatically. This photometer uses a flow cell of HPLC UV-detector as sample absorpt...
Preparation of Gold Nanoparticles and Their Optical Properties
NAN Caiyun , ZHANG Yu , LI Yufeng , ZHAO Yunling
2019, 34(1): 58-63  doi: 10.3866/PKU.DXHX201806030
[Abstract](702) [FullText HTML] [PDF 989KB](24)
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This paper designed a facile comprehensive experiment based on the frontier research topic of gold nanoparticles. The well-dispersed gold suspensions were synthesized by the reduction of chloroauric acid with sodium citrate and their size-dependent o...
Exploration on the Construction of Information Network of Hazardous Waste Management in Colleges and Universities
LAN Jingfeng , MA Hong
2019, 34(1): 64-71  doi: 10.3866/PKU.DXHX201806031
[Abstract](699) [FullText HTML] [PDF 2777KB](8)
Abstract:
Advanced network technology can help form an effective closed loop for the management of hazardous wastes in universities, reduce the harm to chemistry from chemistry teaching and research activities, and roughly understand the teaching and research ...
Science in Hot Pot: Determining the Heat-Up Duration Using Model of Unsteady Heat Transfer
LI Xiaoyu , LIU Ke , ZHANG Shuyong
2019, 34(1): 72-76  doi: 10.3866/PKU.DXHX201804037
[Abstract](450) [FullText HTML] [PDF 805KB](29)
Abstract:
Hot pot is a famous traditional Chinese cuisine. During hot pot, people usually judge whether or not the meat is well done by observation. This way for making judgement lacks scientific support and may possibly cause safety risks. In this paper, we s...
Suggestions on Description of Freezing Point Depression in College Chemistry Textbooks and Teaching Methodology
QIAO Zhengping , GONG Menglian , CHAO Hui
2019, 34(1): 77-81  doi: 10.3866/PKU.DXHX201804008
[Abstract](450) [FullText HTML] [PDF 2109KB](16)
Abstract:
Two different kinds of expressions about freezing point depression were shown in current college chemistry textbooks, leading to the confusion of teachers and students in teaching and learning. Suggestions were put forward with graphic analysis and i...
Proton Nuclear Magnetic Resonance Spectroscopy of Active Hydrogen
YANG Jie , ZHANG Shiping , SUN Wei , BAI Yinjuan
2019, 34(1): 82-88  doi: 10.3866/PKU.DXHX201806008
[Abstract](2730) [FullText HTML] [PDF 1794KB](80)
Abstract:
Proton nuclear magnetic resonance spectroscopy is one of the most commonly used spectral methods for the characterization of organic compounds. It provides proton information on chemical shifts, integral areas, and coupling splits of organic compound...
A Discussion about Extraction Limit
WU Yadong
2019, 34(1): 89-91  doi: 10.3866/PKU.DXHX201806005
[Abstract](609) [FullText HTML] [PDF 305KB](29)
Abstract:
Extraction separation is a common operation in chemical experiments. According to the distribution law, the Lagrangian multiplier method is used to derive and prove that the extraction efficiency can be optimized only in the case of using same aliquo...
Derivation and Experimental Verification of Colligative Equations of Dilute Strong Electrolyte Solution
CHEN Meiting , GU Cong , YAO Zhe , CHEN Feiwu , ZHANG Hengjian , XIONG Chuqiang
2019, 34(1): 92-97  doi: 10.3866/PKU.DXHX201804041
[Abstract](547) [FullText HTML] [PDF 716KB](17)
Abstract:
Colligative properties of dilute strong electrolyte solution, i.e., freezing point depression, boiling point elevation and osmotic pressure, are discussed. As an example, the freezing point depression equation of dilute strong electrolyte solution is...
Remote Control and Monitoring of Laboratory Equipment and Operation Using Mobile Devices
ZHANG Weiqing , ZHANG Jianhui , YU Xiaolan
2019, 34(1): 98-103  doi: 10.3866/PKU.DXHX201803047
[Abstract](542) [FullText HTML] [PDF 773KB](6)
Abstract:
This paper proposes a method of using free software on mobile phones or tablets to remotely control and monitor laboratory equipment. The Ezviz Studio video software is used to monitor laboratory environment and the surrounding of equipment, which pr...
Analysis on the Concept of Intermolecular Interactions and van der Waals Force in the Teaching of University Chemistry
HUA Shugui , JI Jiao , SHAN Jingshu , YAN Jun
2019, 34(1): 104-107  doi: 10.3866/PKU.DXHX201803015
[Abstract](630) [FullText HTML] [PDF 9829KB](25)
Abstract:
This paper discussed the differences between intermolecular interactions and van der Waals force. Based on the physical models of different interactions, some important and confusing concepts were clarified.
Quantitative Analysis and Graphical Visualization Interpretation of Mono-substituted Benzene Ring Localization Effect
LI Qianggen , LI Xuanying , MAO Shuang
2019, 34(1): 108-115  doi: 10.3866/PKU.DXHX201805042
[Abstract](583) [FullText HTML] [PDF 2838KB](23)
Abstract:
Currently,the interpretation of the location effect of electrophilic substitution reaction on benzene ring is mainly based on the qualitative explanation of the experiment. In this paper, we chose five typical mono-substituted benzene molecules (incl...
Calculation Method and Application of Multi-Equilibrium Standard Equilibrium Constant
LIU Xia
2019, 34(1): 116-121  doi: 10.3866/PKU.DXHX201805033
[Abstract](1568) [FullText HTML] [PDF 379KB](55)
Abstract:
This paper introduces the skillful calculation formula and application scope of multi-equilibrium standard equilibrium constant. It is a simple, fast and accurate approach to solve problems. Moreover, it can also intuitively estimate the directionali...
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