2015 Volume 31 Issue 10

Cover and Table of Contents for Vol.31 No. 10
2015, 31(10):
[Abstract](350) [FullText HTML] [PDF 30133KB](179)
Abstract:
Progress of White Organic Light-Emitting Diodes
LIU Bai-Quan , GAO Dong-Yu , WANG Jian-Bin , WANG Xi , WANG Lei , ZOU Jian-Hua , NING Hong-Long , PENG Jun-Biao
2015, 31(10): 1823-1852  doi: 10.3866/PKU.WHXB201506192
[Abstract](1048) [FullText HTML] [PDF 14517KB](1297)
Abstract:

White organic light-emitting diodes (WOLEDs) are now approaching mainstream display markets, and they are also being aggressively investigated for next-generation lighting applications because of their extraordinary characteristics, such as high effi...

Thermodynamic Assessment of the M -P2O5 and CaO-P2O5 Systems
DING Guo-Hui , XIE Wei , JUNG In-Ho , QIAO Zhi-Yu , DU Guang-Wei , CAO Zhan-Min
2015, 31(10): 1853-1863  doi: 10.3866/PKU.WHXB201508121
[Abstract](534) [FullText HTML] [PDF 610KB](201)
Abstract:

The M -P2O5 and CaO-P2O5 systems have been thermodynamically assessed based on the available phase diagram and thermodynamic data using the Calculation of Phase Diagram (CALPHAD) method. The liquid phase is described by the modified quasichemical mod...

Reaction Mechanism and the Regioselectivity of Cu-Catalyzed Silacarboxylation of Internal Alkynes: a Density Functional Theory Study
ZHAO Yi , ZHOU Jin , LIU Hui , ZHUO Shu-Ping
2015, 31(10): 1864-1871  doi: 10.3866/PKU.WHXB201508281
[Abstract](565) [FullText HTML] [PDF 10600KB](133)
Abstract:

Transition metal-catalyzed carbon-carbon bond formation utilizing CO2 is of great importance. The heteroatom functionality and CO2 are simultaneously and catalytically incorporated into unsaturated substrates to form highly functionalized carboxylic ...

Density Functional Theory and Surface Enhanced Raman Spectroscopy Studies of Dicyandiamide Adsorbed on Au Clusters
DENG Shu-Fen , HUANG Wei , ZHANG Ji-Fang , LIN Ling , HE Jia-Wei , BIAN Xun-Tao , CHEN Wen-Kai , SUN Jian-Jun
2015, 31(10): 1872-1879  doi: 10.3866/PKU.WHXB201509072
[Abstract](634) [FullText HTML] [PDF 3841KB](143)
Abstract:

Dicyandiamide is a dimer of cyanamide that generally isomerizes into imino and amino forms. The behaviors of tautomeric dicyandiamide adsorbed on ld surface were studied by the density functional theory method combined with surface enhanced Raman sp...

Simulation of Tensile Deformation of Twin Silver Nanowires Based on Molecular Dynamics
SUN Yin-Lu , GAO Ya-Jun , SUN Qian , ZHAO Jian-Wei
2015, 31(10): 1880-1887  doi: 10.3866/PKU.WHXB201509063
[Abstract](497) [FullText HTML] [PDF 31577KB](119)
Abstract:

This study investigated the deformation behavior of <111> twin Ag nanowires with differing parallel twin boundary (TB) densities under tensile loading via molecular dynamics (MD) simulations. The effect of TB density on the ultimate stress of nanowir...

Electrochemical and Electrochromic Properties of Multichromic Pendritic Poly(3,6-dithienycarbazole) and Its Copolymer
BIAN Gao-Feng , HU Bin , OUYANG Mi , WANG Ping-Jing , Lü Xiao-Jing , DAI Yu-Yu , ZHANG Cheng
2015, 31(10): 1888-1894  doi: 10.3866/PKU.WHXB201509062
[Abstract](507) [FullText HTML] [PDF 5481KB](139)
Abstract:

A novel dendritic carbazole derivative (BTCPh) was designed and synthesized by simple chemical route. Its homopolymer and copolymer of BTCPh with (3,4-ethoxylene dioxythiophene) (EDOT) were electrochemically synthesized and characterized. Cyclic volt...

Enhancement of the Photoelectrochemical Activity of α-Fe2O3 Materials by Surface Modification with Vanadium
YAO Li-Zhen , KONG De-Sheng , DU Jiu-Yao , WANG Ze , ZHANG Jing-Wei , WANG Na , LI Wen-Juan , FENG Yuan-Yuan
2015, 31(10): 1895-1904  doi: 10.3866/PKU.WHXB201509074
[Abstract](1739) [FullText HTML] [PDF 3917KB](184)
Abstract:

Surface modification of semiconductor materials is an effective way to improve their photocatalysis and photo-conversion activities. Bare and V-modified α-Fe2O3 photoelectrode materials were prepared using hydrothermal, chemical bath deposition and h...

Synthesis and Properties of Proton Exchange Membranes via Single-Step Grafting PSBMA onto PVDF Modified by TMAH
ZHANG Jia-Han , GUO Gui-Bao , AN Sheng-Li , HAO Yan , ZHANG Dong , YAN Kai-Bo
2015, 31(10): 1905-1913  doi: 10.3866/PKU.WHXB201508261
[Abstract](389) [FullText HTML] [PDF 3573KB](137)
Abstract:

Poly(vinylidene fluoride)-graft-poly(sulfobetaine methacrylate) (PVDF-g-PSBMA) proton exchange membranes were synthesized via single-step grafting sulfobetaine methacrylate (SBMA) onto PVDF. Benzoyl peroxide (BPO) was the initiator, and the PVDF was ...

Synthesis of P(MEO2MA-co-OEGMA) Random Copolymers and Thermally Induced Phase Transition Behaviors in Aqueous Solutions
GUO Yi , LIU Heng-Jiang , CHEN Jie-Qiong , SHANG Ya-Zhuo , LIU Hong-Lai
2015, 31(10): 1914-1923  doi: 10.3866/PKU.WHXB201508263
[Abstract](787) [FullText HTML] [PDF 5624KB](83)
Abstract:

Random copolymers of 2-(2-methoxyethoxy)ethyl methacrylate (MEO2MA) and oli (ethylene glycol) methacrylate (OEGMA, Mn = 500 g·mol-1) were synthesized by atom transfer radical polymerization (ATRP). Thermally induced aggregation of the co-polymers P(M...

Effect of Benzyl-Substituted Alkyl Betaine on the Wettability of a Poly(tetrafluoroethylene) Surface
HU Song-Shuang , ZHANG Lei , XU Zhi-Cheng , NG Qing-Tao , JIN Zhi-Qiang , ZHANG Lu , ZHAO Sui
2015, 31(10): 1924-1931  doi: 10.3866/PKU.WHXB201509061
[Abstract](598) [FullText HTML] [PDF 907KB](69)
Abstract:

The wetting properties of aqueous solutions of zwitterionic surfactants, benzyl-substituted alkyl carboxylbetaine (BCB), and benzyl-substituted alkyl sulfobetaine (BSB) on a poly(tetrafluoroethylene) (PTFE) surface were investigated using sessile dro...

Preparation and Characterization of /Ag3PO4 Composite Photocatalyst and Its Visible Light Photocatalytic Performance
YU Chang-Lin , WEI Long-Fu , LI Jia-De , HE Hong-Bo , FANG Wen , ZHOU Wan-Qin
2015, 31(10): 1932-1938  doi: 10.3866/PKU.WHXB201509064
[Abstract](598) [FullText HTML] [PDF 7728KB](216)
Abstract:

Graphene oxide ( ) was fabricated from graphite powder by Hummers oxidation method and then, under ultrasonic irradiation, a series of /Ag3PO4 composite photocatalysts (4% (w, mass fraction) /Ag3PO4, 8% /Ag3PO4, 16% /Ag3PO4, 32% /Ag3PO4) were sy...

Hydrothermal Synthesis of Ag3PO4 Polyhedrons with Oriented {110} Facets and Visible-Light-Driven Photocatalytic Activity
LIU Chun-Mei , ZHANG Guo-Ying , ZHANG Xin , XU Yan-Yan , GAO Dong-Zhao
2015, 31(10): 1939-1948  doi: 10.3866/PKU.WHXB201508251
[Abstract](515) [FullText HTML] [PDF 14845KB](110)
Abstract:

Ag3PO4 polyhedrons were synthesized by a facile hydrothermal route using polyethylene glycol-6000 (PEG-6000). The effects of hydrothermal temperature, reaction time, and PEG-6000 dosage on the morphologies and structures of the products were systemat...

Preparation of Hierarchical Ni@CuS Composites and the Application of the Enhanced Catalysis for 4-Nitrophenol Reduction
MA Yi-Ran , ZHOU Wei , CAO Wei , ZHENG Jin-Long , GUO Lin
2015, 31(10): 1949-1955  doi: 10.3866/PKU.WHXB201509091
[Abstract](739) [FullText HTML] [PDF 16018KB](108)
Abstract:

Three types of hierarchical, flower-like CuS particles were prepared by a hydrothermal method and samples were formulated as thin nanosheets. The aggregation density of the sheets could be readily controlled with the aid of polyvinylpyrrolidone (PVP)...

Effect of Activated Carbon Pore Structure on the Adsorption of Pb(II) from Aqueous Solution
YANG Jie-Yang , HUANG Zhang-Gen , HAN Xiao-Jin , JING Wen , ZENG Ze-Quan
2015, 31(10): 1956-1962  doi: 10.3866/PKU.WHXB201508212
[Abstract](560) [FullText HTML] [PDF 4495KB](118)
Abstract:

Pb(II) adsorption by three activated carbons (ACs) with similar surface chemistry but different pore distributions was investigated by isothermal adsorption experiments. The ACs were characterized by scanning electron microscopy (SEM) and N2 adsorpti...

Asymmetric Polyimide Mixed Matrix Membranes with Porous Materials-Modified Surfaces for CO2/N2 and CO2/CH4 Separations
NG Jin-Hua , WANG Chen-Hui , BIAN Zi-Jun , YANG Li , HU Jun , LIU Hong-Lai
2015, 31(10): 1963-1970  doi: 10.3866/PKU.WHXB201508282
[Abstract](433) [FullText HTML] [PDF 7054KB](109)
Abstract:

Membranes with both od permeation and selectivity are highly desired for gas separations. We synthesized a polyimide (PI) asymmetric membrane using the phase-inversion method, and then modified the surface with a mixture of porous fillers and poly(a...

A Novel Molecule Based on 2,2'-Dipyridylamine Functionalized 9,9-Diarylfluorene with Steric Hindance: Design, Synthesis and Electro-Optical Property Research
ZHAO Xiang-Hua , LI Xiao-Sheng , ZHOU Li , WU Na-Na , YANG Xing-Kun , YUAN Shun-Dong , DING Dong-Xue , XU Hui
2015, 31(10): 1971-1976  doi: 10.3866/PKU.WHXB201509011
[Abstract](1635) [FullText HTML] [PDF 1300KB](100)
Abstract:

The bipolar molecule N-(4-(9-phenyl-fluoren-9-yl)phenyl)-2,2'-bipydylamine (PFPhDPy) with bulky steric hindrance was synthesized successfully by substituting 9-(4-anilino)-9-phenyl-fluorene with 2-bromopyridine via Ullmann reaction, which is expected...

Synthesis and Photoelectric Properties of Carbazole Sensitizing Dyes Based on a Benzoic Acid Acceptor
HAO Xue-Liang , ZHAO Jin-Ge , GAO Jian-Rong , HAN Liang
2015, 31(10): 1977-1984  doi: 10.3866/PKU.WHXB201509075
[Abstract](1577) [FullText HTML] [PDF 2705KB](103)
Abstract:

4-(6-(N-butylcarbazole-3-yl)-9-oxo-9H-fluoren-3-yl)benzoic acid (HXL-3W) and 4-(7-(Nbutylcarbazole-3-yl)-9-oxo-9H-fluoren-2-yl)benzoic acid (HXL-4Z), were designed and synthesized through the linking position variation of the fluorenone π-bridge with...

Peptide-Induced Budding and Leakage Behavior of Giant Vesicles
SUN Jian-Bo , XIA Yu-Qiong , YU Qiu-Hong , LIANG De-Hai
2015, 31(10): 1985-1990  doi: 10.3866/PKU.WHXB201508262
[Abstract](384) [FullText HTML] [PDF 9996KB](89)
Abstract:

The interactions between membrane proteins and cell membranes are critical in many life processes. Giant unilamellar vesicles (GUVs) and peptides are simple but effective models of membranes and membrane proteins, respectively. Here, we designed four...

Influence of Soldium Lignosulfonate with Different Molecular Weights on the Dispersion of Multiwalled Carbon Nanotubes
YE Huang-Qing , DENG Yong-Hong , YAN Yan , ZHANG Mei-Jie , QIAN Yong , QIU Xue-Qing
2015, 31(10): 1991-1996  doi: 10.3866/PKU.WHXB201509073
[Abstract](471) [FullText HTML] [PDF 5273KB](101)
Abstract:

The influence of sodium lignosulfonate (SLS) fractions with different molecular weights on the adsorption characteristics of multi-walled carbon nanotubes (MWCNTs) and their dispersion performance was studied using gel permeation chromatography (GPC)...

Preparation and Gas Sensing Properties of PdO, Au, CdO Coatings on SnO2 Nanofibers
HU Rui-Jin , WANG Jing , ZHU Hui-Chao
2015, 31(10): 1997-2004  doi: 10.3866/PKU.WHXB201508241
[Abstract](488) [FullText HTML] [PDF 4631KB](142)
Abstract:

SnO2 nanofibers fabricated by electrospinning were coated with PdO, Au, and CdO. X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectrometry (EDX), X-ray photoelectron spectroscopy (XPS), and Brunauer-Emmett-Tell...

Cavity-Tunable Cu2O Spherical Nanostructures and Their NO2 Gas Sensing Properties
ZHANG Dong-Feng , ZHANG Yan , ZHANG Hua , QI Juan-Juan , SHANG Yang , GUO Lin
2015, 31(10): 2005-2010  doi: 10.3866/PKU.WHXB201509071
[Abstract](368) [FullText HTML] [PDF 9528KB](82)
Abstract:

We report the preparation of cavity-controlled Cu2O nanospheres, having various mesoporous, hollow, and solid structures, by simply adjusting the OH- concentration and the release rate of Cu2+ with the assistance of polyvinyl pyrrolidone (PVP). It in...

Effect of Lauryl Sodium Sulfate on the In situ Crystallization of Small-Grain NaY
SUN Zhi-Guo , GAO Xiong-Hou , MA Jian-Tai , ZHANG Li , LIU Hong-Hai , WANG Bao-Jie
2015, 31(10): 2011-2015  doi: 10.3866/PKU.WHXB201508211
[Abstract](505) [FullText HTML] [PDF 2755KB](99)
Abstract:

The in situ crystallization of small-grain NaY in the presence of lauryl sodium sulfate was investigated. The product containing small-grain NaY was used as a matrix to prepare REUSY catalyst via ammonium ion exchange and rare earth ion exchange. X-r...

γ-Ray Induced Reduction of Graphene Oxide in Aqueous Solution
MA Hui-Ling , ZHANG Long , ZHANG You-Wei , LIU Di , SUN Chao , ZENG Xin-Miao , ZHAI Mao-Lin
2015, 31(10): 2016-2022  doi: 10.3866/PKU.WHXB201508102
[Abstract](419) [FullText HTML] [PDF 2260KB](133)
Abstract:

Graphene, a one-atom-thick, two-dimensional (2D) sheet of carbon packed in a honeycomb lattice, has striking electronic, mechanical, and thermal properties. Reduced graphene oxide (R ) and amine-modified reduced graphene oxide (R N) were obtained by ...

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