2010 Volume 26 Issue 7

Cover and Table of Contents for Vol.26 No. 07
2010, 26(07):
[Abstract](1442) [FullText HTML] [PDF 6320KB](1155)
Abstract:
庆祝唐有祺教授九十寿辰暨执教六十年
2010, 26(07): 1727-1736  doi: 10.3866/PKU.WHXB201007ZKPreface
[Abstract](2283) [FullText HTML] [PDF 11785KB](2205)
Abstract:
Autoxidation and Prooxidation Mechanisms of Danshensu
XU Yuan-Chao , YANG Yi , DU Li-Bo , SHEN Jian-Gang , WANG Guang-Qing , HE Zeng , TIAN Qiu , LIU Yang
2010, 26(07): 1737-1741  doi: 10.3866/PKU.WHXB20100710
[Abstract](2828) [FullText HTML] [PDF 226KB](1186)
Abstract:

A hydrogen peroxide (H2O2) electrode and electron spin resonance (ESR) methods were used to continuously monitor and analyze the autoxidation and prooxidation of Danshensu in aqueous solutions with various pH values. We found that Danshensu exhibited...

Computational Approaches to Estimating Octanol-Water Partition Coefficient and Water Solubility of Organic Compounds
WANG Yan-Ling , LI Jie , WANG Ren-Xiao
2010, 26(07): 1742-1754  doi: 10.3866/PKU.WHXB20100702
[Abstract](3896) [FullText HTML] [PDF 443KB](2126)
Abstract:

Octanol-water partition coefficient and water solubility are two important physicochemical properties of organic compounds in medicinal chemistry and environmental chemistry studies. They are used as critical parameters in quantitative structure-acti...

Mixed Quantum-Classical Approaches to Calculating Charge Transfer Rate Constants: Applications to Realistic Systems
NAN Guang-Jun , ZHENG Ren-Hui , SHI Qiang , SHUAI Zhi-Gang
2010, 26(07): 1755-1760  doi: 10.3866/PKU.WHXB20100735
[Abstract](3503) [FullText HTML] [PDF 204KB](1278)
Abstract:

Mixed quantum-classical methods are of great interest in simulating dynamic processes of complex molecular systems. We investigated the application of the Ehrenfest method, the surface hopping method, and the mixed quantum classical Liouville equatio...

Experimental and Theoretical Studies of the Reactions between Vanadium Oxide Cluster Anions and Small Hydrocarbon Molecules
MA Jia-Bi , WU Xiao-Nan , ZHAO Yan-Xia , HE Sheng-Gui , DING Xun-Lei
2010, 26(07): 1761-1767  doi: 10.3866/PKU.WHXB20100737
[Abstract](7025) [FullText HTML] [PDF 1277KB](1402)
Abstract:

Reactions between transition metal oxide clusters and hydrocarbon molecules were extensively studied to reveal the mechanisms of the related catalytic processes at a molecular level. Compared with transition metal oxide cluster cations, anions are us...

Rate Constants for the Gas Phase Reactions of Ozone with Diethylamine and Triethylamine
GAI Yan-Bo , GE Mao-Fa , WANG Wei-Gang
2010, 26(07): 1768-1772  doi: 10.3866/PKU.WHXB20100705
[Abstract](6948) [FullText HTML] [PDF 153KB](1433)
Abstract:

Kinetics of the reactions of ozone with diethylamine (DEA) and triethylamine (TEA) were investigated in a self-made Teflon chamber. Experiments were conducted under pseudo-first-order decay conditions using excess DEAand TEA. Cyclohexane was added to...

Preparation of Core-Shell SiO2/Pt Particles via Layer-by-Layer Assembly and Their Electrooxidation and In-situ Electrochemical FTIR Spectra for CO
LI Yong-Jun , ZHOU You-Chen , SUN Shi-Gang
2010, 26(07): 1773-1778  doi: 10.3866/PKU.WHXB20100514
[Abstract](2725) [FullText HTML] [PDF 776KB](1388)
Abstract:

Large-scale core-shell SiO2/Pt particles were synthesized via layer-by-layer assembly. The platinum shell was found to be about 26 nmthick and consisted of Pt nanoparticle aggregates. Cyclic voltammetry (CV) was employed to evaluate the electrocataly...

DNA Electrochemical Biosensor for Trace Hg2+ Detection
GE Fang , CAO Rui-Guo , ZHU Bin , LI Jing-Jian , XU Dong-Sheng
2010, 26(07): 1779-1783  doi: 10.3866/PKU.WHXB20100736
[Abstract](3778) [FullText HTML] [PDF 473KB](1711)
Abstract:

In this paper we demonstrated a novel type of electrochemical Hg2+ biosensor based on a DNA-modified electrode. Ferrocenyl-modified T-rich DNA (DNA-Fc) molecules were synthesized for use as electrochemical probes. We then fixed these DNA-Fc probes on...

Design of Organic/Polymeric π-Semiconductors: the Four-Element Principle
XIE Ling-Hai , CHANG Yong-Zheng , GU Ju-Fen , SUN Rui-Juan , LI Jie-Wei , ZHAO Xiang-Hua , HUANG Wei
2010, 26(07): 1784-1794  doi: 10.3866/PKU.WHXB20100713
[Abstract](3772) [FullText HTML] [PDF 1586KB](2424)
Abstract:

Organic semiconductors are charge carrier-transporting molecular solids with π-orbital channels. Organic semiconductors are π-systems that can be created via the molecular engineering of π-orbitals. In this review, we present a pattern in physical or...

70 Years of Crystallographic van der Waals Radii
HU Sheng-Zhi , XIE Zhao-Xiong , ZHOU Zhao-Hui
2010, 26(07): 1795-1800  doi: 10.3866/PKU.WHXB20100731
[Abstract](2348) [FullText HTML] [PDF 553KB](1181)
Abstract:

Significant data sets of crystallographic van der Waals radii for the noble gases, the non-metal elements, and the metal elements that have appeared within the last seven decades are summarized and examined systematically. From the most useful sets a...

Controlled Assembly of Organoimido Derivatized Polyoxometalates
WU Ping-Fan , ZHANG Jin , WEI Yong-Ge
2010, 26(07): 1801-1810  doi: 10.3866/PKU.WHXB20100719
[Abstract](2532) [FullText HTML] [PDF 2270KB](1575)
Abstract:

Recent advances in hybrid molecular materials based organoimido-substituted polyoxometalates (POMs) are reviewed. Related imidoylation and C-C coupling reactions developed in our group are highlighted.

One-Pot Formation of Aromatic Oli amide Macrocycles and the Corresponding Mechanism
HU Jin-Chuan , FENG Wen , LI Xiang-Hui , YANG Liu-Qing , YUAN Li-Hua , HE Lan , NG Bing
2010, 26(07): 1811-1822  doi: 10.3866/PKU.WHXB20100722
[Abstract](3510) [FullText HTML] [PDF 3084KB](1477)
Abstract:

In this review, we summarize a newly discovered one-pot process for the synthesis of aromatic oli amide and oli hydrazide macrocycles. A mechanism for these highly efficient one-pot macrocyclization reactions is presented and discussed. The unprecede...

Syntheses, Structures and Properties of Hemi-Hydrogarnet Sr6Sb4M3O14(OH)10 (M=Co,Mn)
LI Kuo , WANG Ying-Xia , SU Jie , LIN Jian-Hua
2010, 26(07): 1823-1831  doi: 10.3866/PKU.WHXB20100726
[Abstract](3321) [FullText HTML] [PDF 1773KB](1163)
Abstract:

Two new compounds, Sr6Sb4Co3O14(OH)10 (SSC) and Sr6Sb4Mn3O14(OH)10 (SSM), were synthesized under hydrothermal conditions in an alkaline medium. Their structures were determined by powder X-ray diffraction using Rietveld analysis, and the topology of ...

Inclusion Resolution of 1,1'-Bi-2-naphthol: Crystal Structure and CD Spectroscopy of the Inclusion Complexes
ZHAO Jun , ZHENG Ming-Xian , LIN Yi-Ji , CHEN Yuan-Chuan , RUAN Yuan-Ping , ZHANG Hui
2010, 26(07): 1832-1836  doi: 10.3866/PKU.WHXB20100633
[Abstract](5170) [FullText HTML] [PDF 809KB](1460)
Abstract:

A highly efficient and environmentally friendly method for the resolution of racemic 1,1'-bi-2-naphthol (BINOL) was developed by inclusion complexation with the cheap and readily accessible (R)/(S)-N,N,N-trimethyl-1-hydroxyl-3-methyl-2-butanaminiumio...

Powder X-Ray Diffraction Analyses for Molecule-Ion Adducts of β-Cyclodextrin with a Series of Inorganic Salts
DANG Zheng , SONG Le-Xin
2010, 26(07): 1837-1841  doi: 10.3866/PKU.WHXB20100703
[Abstract](2583) [FullText HTML] [PDF 1013KB](1247)
Abstract:

The molecule-ion interaction between a sugar and a salt is important and significant in biophysics and biochemistry. In this paper, powder X-ray diffraction (PXRD) technology was used to examine the molecule-ion adducts of a series of inorganic salts...

Interfacial Assembly of Diethyl Ester Glutamic Acid Terminated Bolaamphiphile at the Air/Water Interface: Chiral Interaction and Morphology
CAO Hai , JIANG Jian , ZHU Xue-Feng , DUAN Peng-Fei , LIU Ming-Hua
2010, 26(07): 1842-1846  doi: 10.3866/PKU.WHXB20100716
[Abstract](2890) [FullText HTML] [PDF 3586KB](1310)
Abstract:

We investigated the self-assembly behavior of bolaamphiphilic tetraethyl ester-di-L-glutamic acid-N,N'-hexadecanedioic amide (L-HDGE) and its enantiomer D-HDGE at the air/water interface. The self-assembled structures of the HDGE (L-HDGE or D-HDGE) m...

Interaction between [1,1'-Binaphthalene]-2,2'-diols and a Solid Supported Bilayer Lipid Membrane
AN Shen-Jing , GAN Li-Hua , CHEN Liu-Hua , LIU Ming-Xian , ZHU Da-Zhang , XU Zi-Jie , HAO Zhi-Xian , CHEN Long-Wu
2010, 26(07): 1847-1851  doi: 10.3866/PKU.WHXB20100612
[Abstract](2912) [FullText HTML] [PDF 460KB](1145)
Abstract:

The interaction between [1,1'-binaphthalene]-2,2'-diols (BINOL) and a solid supported bilayer lipid membrane (s-BLM) was studied by cyclic voltammetry and alternating current (AC) impedance measurements. Results indicate that BINOL interacts with s-B...

Hydrothermal Synthesis of Ordered Mesoporous Materials with High Stability at High Temperatures
LIU Si-Yu , MENG Xiang-Ju , XIAO Feng-Shou
2010, 26(07): 1852-1859  doi: 10.3866/PKU.WHXB20100738
[Abstract](3105) [FullText HTML] [PDF 2552KB](1484)
Abstract:

The hydrothermal synthesis of ordered mesoporous materials with high stability at high temperatures is currently a hot topic in the materials field. This review covers recent developments in the synthesis of ordered mesoporous silicas, titanosilicate...

Catalytic Activity of an Oxime Carbapalladacycle Complex Grafted onto Superparamagnetically Mesoporous Nanoparticles for the Heck Reaction
SHEN Bin , WANG Yong-An , WANG Zhi-Fei , ZHANG Ling
2010, 26(07): 1860-1866  doi: 10.3866/PKU.WHXB20100707
[Abstract](2949) [FullText HTML] [PDF 1214KB](1209)
Abstract:

A mesoporous SiO2@Fe3O4 nanocomposite was prepared by the sol-gel method. The nanocomposite was modified with a thiol and then a long carbon chain oxime carbapalladacycle complex as grafted by a—SCH2— linkage. The catalyst was characterized by transm...

Esterification and Transesterification on Al2O3-Doped Sulfated Tin Oxide Solid Acid Catalysts
ZHAI De-Wei , YUE Ying-Hong , HUA Wei-Ming , GAO Zi
2010, 26(07): 1867-1872  doi: 10.3866/PKU.WHXB20100709
[Abstract](2603) [FullText HTML] [PDF 716KB](1390)
Abstract:

A series of Al2O3-doped (0.5%-3.0%, molar fraction) sulfated tin oxide catalysts were prepared by a co-precipitation method. The structures and textural properties of these catalysts were characterized by N2 adsorption, thermogravimetric (TG) analysi...

Preparation o fMagnetic Sulfonated Carbon-Based Solid Acid Catalysts for the Hydrolysis of Cellulose
WANG Hua-Yu , ZHANG Chang-Bin , HE Hong , WANG Lian
2010, 26(07): 1873-1878  doi: 10.3866/PKU.WHXB20100721
[Abstract](3480) [FullText HTML] [PDF 676KB](2039)
Abstract:

Magnetic sulfonated carbon-based solid acid catalysts (Fe/C-SO3H) were prepared by the pyrolysis of cellulose and subsequent sulfonation. The catalyst samples were characterized by scanning electron microscopy (SEM), transmission electron microscopy ...

Effects of Zirconia Crystallite Phases on the Structures of MoOx/ZrO2 Catalysts and Their Properties in the Selective Oxidation of Methanol
ZHANG Sheng-Hong , ZHANG Hong-Peng , LI Wei-Zhen , ZHANG Wei , HUANG Hua , LIU Hai-Chao
2010, 26(07): 1879-1886  doi: 10.3866/PKU.WHXB20100732
[Abstract](2759) [FullText HTML] [PDF 304KB](1051)
Abstract:

MoOx supported on pure monoclinic zirconia (m-ZrO2) and tetra nal zirconia (t-ZrO2) with different Mo surface densities were prepared and their structures were characterized by X-ray diffraction, Raman spectroscopy and temperature-programmed reductio...

Influence of Carbon on Phase Transformation of Oxides in Carbon/Oxide Composites
GUO Ying , WANG Pei , YU Gang , WANG Yu , ZHU Yue-Xiang , XIE You-Chang
2010, 26(07): 1887-1892  doi: 10.3866/PKU.WHXB20100712
[Abstract](4177) [FullText HTML] [PDF 806KB](1302)
Abstract:

Carbon/alumina (titania) composites have unique physicochemical properties and have been widely used in adsorption and catalysis. Carbon in these composites greatly influences the sintering and phase transformation behavior of the oxides. Calcining c...

Fullerene Band-Like Assembly Induced by a Donor-π-Acceptor Molecular Template on Au(111) Electrode Surface
YAN Hui-Juan , WANG Dong , WEN Guo-Yong , ZHANG De-Qing , WAN Li-Jun
2010, 26(07): 1893-1897  doi: 10.3866/PKU.WHXB20100704
[Abstract](2845) [FullText HTML] [PDF 1972KB](1180)
Abstract:

Fullerene has been extensively used in functional devices requiring electron transfer between fullerene and functional molecules. The investigation of multi-component assembly structures of fullerene and functional molecules on electrode surfaces wil...

Micro/Nano Patterning of Phenolic Resin Using Hot Microcontact Printing
NI Wei , DUAN Li-Ting , XUE Mian-Qi , ZHAO Dan , CAO Ting-Bing
2010, 26(07): 1898-1902  doi: 10.3866/PKU.WHXB20100727
[Abstract](2641) [FullText HTML] [PDF 1659KB](1372)
Abstract:

We added 2,4,6-tris[bis(methoxymethyl)-amino]-1,3,5-triazine as a crosslinking agent and diphenyliodonium hexafluorophosphate as an acid generator to phenolic resin, which is a thermosensitive polymer. A topographically patterned polydimethylsiloxane...

Photolysis of n-C3H7I and i-C3H7I at 266 nm: Effect of Alkyl Radical Branching on the Dissociation Dynamics of the C—I Bond
ZHANG Feng , WANG Yan-Mei , ZHANG Bing , FENG Wen-Lin
2010, 26(07): 1903-1908  doi: 10.3866/PKU.WHXB20100630
[Abstract](2728) [FullText HTML] [PDF 816KB](1090)
Abstract:

Photodissociation dynamics of n-C3H7I and i-C3H7I at 266 nm were investigated using an ion imaging technique combined with resonance enhanced multiphoton ionization (REMPI). Information on energy disposal and a nonadiabatic transition between the dis...

Effect of Water on γ-Radiolysis and Pulse Radiolysis of Cyclohexane-Tributylphosphate System
DU Yi-Kui , WU Ji-Lan
2010, 26(07): 1909-1914  doi: 10.3866/PKU.WHXB20100720
[Abstract](2733) [FullText HTML] [PDF 286KB](1012)
Abstract:

To determine the origin of the radiolytic product singlet state of hydrocarbons, the effect of water on the γ-radiolysis and pulse radiolysis of cyclohexane (C6H12)-tributylphosphate (TBP) solution was studied. In the γ-radiolysis of C6H12-TBP soluti...

Solubility of Poly(N-isopropylacrylamide) in Aqueous Methanol from Raman Spectroscopy
ZHAO Rong-Li , LIN Ke , ZHOU Xiao-Guo , LIU Shi-Lin
2010, 26(07): 1915-1922  doi: 10.3866/PKU.WHXB20100728
[Abstract](3638) [FullText HTML] [PDF 1401KB](1248)
Abstract:

We measured the non-coincidence effect (NCE) in the Raman spectrum of poly(N-isopropylacrylamide) (PNIPAM) in aqueous methanol at -13 ℃ (below the lower critical solution temperature, LCST). This was done to investigate the solubility of PINPAM in aq...

Effect of Glass Silylation on the Adsorption Behavior of Rhodamine 6G and Methylene Blue
DENG Lin , QI Zhi-Mei
2010, 26(07): 1923-1928  doi: 10.3866/PKU.WHXB20100729
[Abstract](3441) [FullText HTML] [PDF 580KB](1324)
Abstract:

The silylation of thin-film glass sheets with hexamethyl disilazane results in hydrophobic glass surfaces with water contact angles larger than 90°. The adsorption behavior of Rhodamine 6G (R6G) and methylene blue (MB) molecules on the hydrophobic gl...

Aggregation Induced Fluorescence Blue-Shift of Zinc Bis(8-hydroxyquinoline) Modified with Cholesteryl
FENG Wen-Ke , KONG Sheng , XIAO Li-Xin , WANG Shu-Feng , NG Qi-Huang
2010, 26(07): 1929-1933  doi: 10.3866/PKU.WHXB20100724
[Abstract](3185) [FullText HTML] [PDF 244KB](1462)
Abstract:

Aggregation induced fluorescence blue-shift of the newly synthesized zinc bis (8-hydroxyquinoline) modified with cholesteryl (Zn(ChQ)2) is studied by static and picosecond transient emission spectroscopy. Fast solvent-induced charge transfer is found...

Synthesis and Spectral Stability of Blue Eletroluminescent Fluorene-Substituted Polyfluorenes
ZHANG Long , LIN Zong-Qiong , GU Ju-Fen , YIN Cheng-Rong , HOU Xiao-Ya , LIU Feng , LIU Yu-Yu , XIE Ling-Hai , CHEN Shu-Fen , HUANG Wei
2010, 26(07): 1934-1940  doi: 10.3866/PKU.WHXB20100739
[Abstract](2841) [FullText HTML] [PDF 591KB](1232)
Abstract:

A monomer of diarylfluorene containing triphenylamine and dialkylfluorene groups at the 9-position and its copolymers, TPAFF-co-F and TPAFF-co-P, were successfully synthesized by a Suzuki cross-coupling polycondensation to obtain stable and highly ef...

Reversible Photomodulation of Organic Transistor Performance by Conformation-Induced Capacitive Coupling
SHEN Qian , GAN Lin , LIU Song , CAO Yang , WANG Zhen-Xing , HUI Jing-Shu , GUO Xue-Feng
2010, 26(07): 1941-1946  doi: 10.3866/PKU.WHXB20100718
[Abstract](2861) [FullText HTML] [PDF 3456KB](1164)
Abstract:

Problems associated with intrinsically destructive sensing mechanisms of organic field-effect transistors constitute one of the main obstacles to using them for the practical applications in sensing and switching. Here we report a smart system, in wh...

Fuzzy Symmetry Characteristics of Polyyne, Cumulative Polyene and Full Carbon RingMolecules
XING Sheng-Kai , LI Yun , ZHAO Xue-Zhuang , SHANG Zhen-Feng , XU Xiu-Fang , CAI Zun-Sheng , WANG Gui-Chang , LI Rui-Fang
2010, 26(07): 1947-1958  doi: 10.3866/PKU.WHXB20100723
[Abstract](2852) [FullText HTML] [PDF 4744KB](1176)
Abstract:

We have previously studied molecular fuzzy symmetry and mainly focused on the fuzzy point group symmetry and less on the fuzzy space group symmetry. As a kind of one-dimensional linear fuzzy periodic molecule, polyynes have been studied by us. Althou...

Interactions between Anionic Surfactants and Cations
CAO Xu-Long , LV Kai , CUI Xiao-Hong , SHI Jing , YUAN Shi-Ling
2010, 26(07): 1959-1964  doi: 10.3866/PKU.WHXB20100706
[Abstract](5339) [FullText HTML] [PDF 1342KB](2263)
Abstract:

The ion-pairs of the anionic surfactants (dodecyl sulfonate, dodecyl carboxylate) and the cations (Na+, Ca2+, Mg2+) were optimized using density functional theory (DFT) at the B3LY/6-31G level and the interaction between the surfactants and ions were...

Phosphonylation and Activity Loss Mechanism of the Catalytic Triad of Fatty Acid Amide Hydrolase: Theoretical Study of a Model System
LI Qiang-Gen , XUE Ying , GUO Yong , YAN Guo-Sen
2010, 26(07): 1965-1975  doi: 10.3866/PKU.WHXB20100717
[Abstract](3212) [FullText HTML] [PDF 3885KB](1254)
Abstract:

Methyl arachidonyl fluorophosphonate (MAFP) is an inhibitor of the fatty acid amide hydrolase (FAAH). We studied the phosphonylation reaction of the serine241 (Ser241)-serine217 (Ser217)-lysine142 (Lys142) catalytic triad of FAAH by MAFP, which leads...

Enzyme Catalysis and Gene Expression Studies at Single Molecule Level
SU Xiao-Dong , JIN Jian-Shi , XIE Sunney Xiaoliang
2010, 26(07): 1976-1987  doi: 10.3866/PKU.WHXB20100740
[Abstract](2606) [FullText HTML] [PDF 6030KB](1448)
Abstract:

Over the last half century, the overwhelming advances in biological sciences have been greatly aided by the physical and technological innovations, such as X-ray diffraction methods, nuclear magnetic resonance (NMR) and mass spectroscopy, etc. In rec...

Protein-Protein Interactions: Interface Analysis, Binding Free Energy Calculation and Interaction Design
BAI Hong-Jun , LAI Lu-Hua
2010, 26(07): 1988-1997  doi: 10.3866/PKU.WHXB20100725
[Abstract](3506) [FullText HTML] [PDF 2904KB](2495)
Abstract:

Protein-protein interactions (PPI) play essential roles in biological processes. Understanding PPI from a structural, thermodynamic, and kinetic point of view gives us a better understanding about these building blocks of living systems. This review ...

Intermediate Structure and Slow HydrationWater Dynamics in Protein Folding Process
GAO Meng , YAO Xin-Qiu , SHE Zhen-Su , LIU Zhi-Rong , ZHU Huai-Qiu
2010, 26(07): 1998-2006  doi: 10.3866/PKU.WHXB20100733
[Abstract](2362) [FullText HTML] [PDF 1860KB](1215)
Abstract:

The slow dynamics of hydration water has long been recognized as a major determinant of protein stability, function, and folding. However, an atomic level mechanism is still lacking on the origin of the slow dynamics of hydration water and how it is ...

End Effects during the Binding of Protein to Linear DNA Fragments
YANG Xiao-Jing , LIU Xi-Li , LOU Chun-Bo , OUYANG Qi
2010, 26(07): 2007-2014  doi: 10.3866/PKU.WHXB20100701
[Abstract](2165) [FullText HTML] [PDF 1750KB](961)
Abstract:

Many in vitro techniques have been employed to elucidate the interaction between DNA and protein. However, one of the most significant differences between in vitro and in vivo studies is that DNA fragments used for in vitro experiments are usually mu...

Inhibition of Amyloid Fibrillization and Dissociation of Matured Amyloid Fibrils by Mj HSP16.5
CAO Ao-Neng , WANG Wei-Xue , YUWEN Tai-Ran , DENG Wei , LAI Lu-Hua
2010, 26(07): 2015-2020  doi: 10.3866/PKU.WHXB20100708
[Abstract](2397) [FullText HTML] [PDF 1873KB](1229)
Abstract:

The amyloid fibrillization of proteins and peptides is related to many human diseases including Alzheimer's disease. Currently there is no effective therapy for these diseases, because the mechanism of the amyloid fibrillization is still not clear. U...

Excitation Dynamics of the Light-Harvesting Complex 2 from Thermochromatium Tepidum
YANG Fan , YU Long-Jiang , WANG Peng , AI Xi-Cheng , WANG Zheng-Yu , ZHANG Jian-Ping
2010, 26(07): 2021-2030  doi: 10.3866/PKU.WHXB20100730
[Abstract](2977) [FullText HTML] [PDF 2715KB](1420)
Abstract:

Purple photosynthetic bacterium Thermochromatium (Tch.) tepidum is a moderate thermophile growing in an optimal temperature range of 48-50℃. Its light-harvesting complex 2 (LH2) possesses heterogeneous compositions of apoprotein and carotenoid (Car),...

Synthesis and Characterization of Europium Complex Nanoparticles with Long-Wavelength Sensitized Luminescence
SHAO Guang-Sheng , XUE Fu-Min , HAN Rong-Cheng , TANG Min-Xian , WANG Yuan
2010, 26(07): 2031-2036  doi: 10.3866/PKU.WHXB20100715
[Abstract](2563) [FullText HTML] [PDF 468KB](1326)
Abstract:

Luminescent nanoparticles (dav=35 nm) of Eu(tta)3dpbt (dpbt= 2-(N,N-diethylanilin-4-yl)-4,6-bis (3,5-dimethylpyrazol-1-yl)-1,3,5-triazine, tta=thenoyltrifluoroacetonato) protected by bovine serum albumin (BSA) were prepared by a precipitation method....

Growth Mechanism for Controlled Synthesis of Metal Nanotube and Nanowire Arrays Using Anodic Aluminum Oxide Templates
GUO Yuan-Yuan , WANG Ming , MAO Xiao-Bo , JIANG Yue-Xiu , WANG Chen , YANG Yan-Lian
2010, 26(07): 2037-2043  doi: 10.3866/PKU.WHXB20100734
[Abstract](3710) [FullText HTML] [PDF 2588KB](1946)
Abstract:

We report the controlled fabrication of Ni nanotube and nanowire arrays by electrodeposition using anodic aluminum oxide (AAO) as a template. Ni nanotube arrays or nanowire arrays were obtained by changing the concentration of the electrolyte and the...

Preparation of Highly b-Oriented Silicalite-1 Films
WANG Zhou-Xiang , YAN Wen-Fu , TIAN Da-Yong , CAO Xue-Jing , YU Ji-Hong , Xu Ru-Ren
2010, 26(07): 2044-2048  doi: 10.3866/PKU.WHXB20100714
[Abstract](3565) [FullText HTML] [PDF 2030KB](1175)
Abstract:

Using tetraethylorthosilicate (TEOS) as a silicon source and tetrapropylammonium hydroxide (TPAOH) as a structure-directing agent, we prepared highly b-oriented silicalite-1 thin films with smooth surfaces and excellent continuity by optimizing the p...

Preparation and Properties of Zinc Oxide Films by Spin-Coating Water Solution Precursor
WANG Xiao-Yan , DONG Gui-Fang , QIAO Juan , DUAN Lian , WANG Li-Duo , QIU Yong
2010, 26(07): 2049-2052  doi: 10.3866/PKU.WHXB20100631
[Abstract](4234) [FullText HTML] [PDF 1374KB](1857)
Abstract:

We successfully prepared ZnO thin films through spin-coating a mixture of zinc acetate dihydrate, poly(ethylene oxide) (PEO) and deionized H2O. Smooth and pure ZnOthin films were obtained by using PEO, because of its low thermal decomposition tempera...

Chitosan Rods Reinforced by N-Carboxyl Propionyl Chitosan Sodium
WANG Zheng-Ke , HU Qiao-Ling
2010, 26(07): 2053-2056  doi: 10.3866/PKU.WHXB20100711
[Abstract](2716) [FullText HTML] [PDF 969KB](1034)
Abstract:

N-carboxyl propionyl chitosan sodium (CPCS) was used to reinforce chitosan (CS) rods by an in-situ precipitation method. Fourier transforminfrared (FTIR) spectroscopy, X-ray diffraction (XRD), thermogravimetric (TG) analysis, scanning electron micros...

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