1994 Volume 10 Issue 1
The adsorption of Na~+ on γ-alumina surface at four coverages of Na_2CO_3 (5%, 10%, 15%, and 20% wt/wt) was characterized by solid-state ~(23)Na and ~(27)Al NMR spectroscopy. The experimental results suggest that two distinct adsorbed species are pre...
Layered double hydroxides (LDHs) pillared with heteropolyoxo-metalate have been synthesized via both restructuring of hydrotalcite-like compounds and direct anion exchange under microwave field. LDHs and their derivatives are both found to be efficie...
The time-of-flight mass spectra of carbon nanotube plasma produced by laser was first investigated in this paper. We found the hemi-spherical tips of carbon nanotube were easily fragmentated and aggregated into fullerenes between Coo arid C_(174) in ...
The substituent effect of the 1-1 elimination reaction of hydrogen fluoride from ethyl fluoride have been studied by ab initio method at the HF/3-21G level. The reactants are CH_3CH_2F, CH_3CHF_2, CH_2FCH_2F, CH_3CH_2CH_2F, CH_3CHFCH_3, CH_3CHFCN, CH...
The NiO dispersion phase on three different supports have been studied by EXAFS in combination with XRD quantitative phase analysis. The result of XRD shows the threshold of NiO/γ-Al_2O_3 system is larger than that of NiO/TiO_2 system and the thresho...
Energy-transfer reaction from metastable CO(a~3П) molecule to CN radical has been studied in a room-temperature flow reactor. The CN (B-X, △v=0, ±1, ±2) violet emission bands were obtained. The △v=0 sequence of CN(B) were analyzed by computer simulat...
The thermal decomposition of 2-nitropropene has been studied by using the quantum chemical method LCAO-MO-AM1. The result obtained indicates that 2-nitropropene may be decomposed via a stepwise process. In the first step, a four-membered ring interme...
The EHCO-ASED method has been used to investigate the reaction mechanism and the effect of side group (R) on it for the following thermal polymerization of diacetylenes in solid phase: MDA→PBT→PDA (R=Li, CH_3, F). The calculated results reveal that t...
FT-IR emission spectroscopy has been used to study the surface structure of V_2O_5/TiO_2 catalyst with V_2O_5 loadings of 0.4%, 2% and 10% wt. prepared by impregnation of TiO_2 in NH_4VO_3 solution. The IR emission spectra were recorded insitu durinb...
As the starting point of the thermodynamic theories of irreversible processes, local equihbrium assumption is usually believed to be applicable to most physicochemical processes under usual conditions. Based on the Boltzmann equation and the stochast...
Tantalum sulfide cluster ions (Ta_nS_m~+, n≤9, m≤30) were produced by direct laser ablation of a mixture of tantalum and sulfur powders and studied by a tandem timeof-flight mass spectrometer. It was found that the most stable tantalum sulfide cluste...
Alcohols extremely affect the formation of uniform colloidal particles in the hydrolysis of ferric ions for Fe(NO_3)_3-HNO_3 system. The affecting ability of the alcohols decreases by the order: 2-propanol, ethanol, t-butylalcohol, 1-propanol and n-b...
The surface and micelle property of C_7F_(15)COONa/C_3F_7CH_2OH aqueous solution are investigated by surface tension, conductance, electromotive force methods. The results show that when adding C_3F_7CH_2OH into C_7F_(15)COONa solution the surface ac...
In this work, the tunneling breakdown of n-InP electrode using large signal current density step has been investigated. The influence of current density on the tunneling breakdown is not obvious, but the light intensities affect the breakdown severel...
The title 1:1 adduct, has been prepared and a large single crystal with dimensions of 5 mm×50 mm×20 mm was obtained by slow-cooling method. It produces the green radiation at 532 nm under the irradiation of Nd~3+: YAG laser beam at 1064nm. The crysta...
The effect of temperature on the viscosity for aluminum stearate/benzene gels either with or without benzoic acid has been investigated. The experimental results show that the McAllister's equation can be used to describe the relation between the vis...
We have studied the relaxation of Na(110) and Na_2O(111) surfaces with LEED, and found that the best agreement between theory and experiment in such a structure, the surface layer distance d=0.291±0.01 nm (contracted 0.34%±0.01 nm) [for Na(110)]; and...
Quantified resonance theory (QRT) involving the use of weighting has been applied to ionization potential, electron affinity, energy of the lowest π→π~* transiton, charge density and bond order in excited state for odd π hydrocarbon radicals, anions ...
The enthalpy changes for the binding of two alkaloids with the bioactivity to inhibit monoamine oxidase, harmaline(HL) and harmine(HM) to calf thymus DNA have been determined calorimetrically in a 0.01 mol·L~(-1) piperazine-N、N -bis(2-ethanesulfonic ...
This paper, Using potentiometric method, first reports the oscillating behavior of five amino acids (L-methionine, L-cystine, L-tryptophan, L-serine, L-tyrosine) in a new oscillating system of amino acid-BrO_3~--Mn~(2+)-H_2SO_4-acetone. The effect of...
Using the results of quantum chemistry, thermodynamic and kinetic calculations for this experimentally well studied reaction has been carried out. The adaptability of the computational results of diffrent quantum chemistry schemes (considering electr...