2017 Volume 35 Issue 7

The Design of Second-order Nonlinear Optical Dendrimers: From "Branch Only" to "Root Containing"
Peng-yu Chen , Zhen Li
2017, 35(7): 793-798  doi: 10.1007/s10118-017-1949-y
[Abstract](722) [FullText HTML] [PDF 0KB](0)
Abstract:
Dendrimers are considered as a promising family of organic second-order nonlinear optical (NLO) polymers because of their well-defined structures, easily modified peripheral functional groups, interior branches and central cores. In order to obtain N...
Polymer/Metal Segmental Janus Nanoparticles
Lin Tang , Fu-xin Liang , Qian Wang , Xiao-zhong Qu , Bing-yin Jiang , Zhen-zhong Yang
2017, 35(7): 799-808  doi: 10.1007/s10118-017-1946-1
[Abstract](738) [FullText HTML] [PDF 0KB](0)
Abstract:
Polymer/metal composite segmental Janus nanoparticles (NPs) are synthesized by sequential growth against poly(4-vinylpyridine) (P4VP) crosslinked cP4VP-PS Janus NPs. A Janus cluster of poly(4-vinylpyridine)-block-polystyrene (P4VP-b-PS) diblock copol...
Excellent Hydrophilic and Anti-bacterial Fouling PVDF Membrane Based on Ag Nanoparticle Self-assembled PCBMA Polymer Brush
Jian-hua Li , De-bin Zhang , Xing-xing Ni , Hui Zheng , Qi-qing Zhang
2017, 35(7): 809-822  doi: 10.1007/s10118-017-1944-3
[Abstract](745) [FullText HTML] [PDF 0KB](0)
Abstract:
A silver nanoparticles-poly(carboxybetaine methacrylate) (AgNPs-PCBMA) nanocomposite was prepared on poly(vinylidene fluoride) (PVDF) membrane surface to improve its hydrophilicity and antifouling properties. Firstly, the PVDF membranes were grafted ...
Synthesis and Properties of Hydroxide Conductive Polymers Carrying Dense Aromatic Side-chain Quaternary Ammonium Groups
Guang-hui Nie , Wen-jun Wu , Xi Yue , Shi-jun Liao , Xiu-hua Li
2017, 35(7): 823-836  doi: 10.1007/s10118-017-1941-6
[Abstract](708) [FullText HTML] [PDF 0KB](0)
Abstract:
A series of hydroxide conductive polymers QTBMs carrying dense aromatic side-chain quaternary ammonium groups has been synthesized by using a new monomer of 3, 3'-di(3", 5"-dimethylphenyl)-4, 4'-difluorodiphenyl sulfone and other commercial monomers ...
Surface Treatment and Biomimetic Mineralization of Porous Microspheres Fabricated by Calcium Gluconate-g-Poly(D, L-lactide)
Le-yuan Song , Ni Jiang , Zhi-hua Gan
2017, 35(7): 837-845  doi: 10.1007/s10118-017-1940-7
[Abstract](728) [FullText HTML] [PDF 0KB](0)
Abstract:
Porous hybrid microspheres were fabricated by the synthesized calcium gluconate-g-poly(D, L-lactide) (CG-g-PDLLA) composites. These hybrid microspheres were treated with an alkaline solution for different period of time to control the amount of gener...
Polysulfone Membranes via Thermally Induced Phase Separation
Hong-qing Liang , Hao-nan Li , Hao-hao Yu , Yong-ting Zhou , Zhi-kang Xu
2017, 35(7): 846-856  doi: 10.1007/s10118-017-1943-4
[Abstract](784) [FullText HTML] [PDF 0KB](0)
Abstract:
Polysulfone (PSF) membranes have gained great attention in the fields of ultrafiltration, microfiltration, and thin film composite membranes for nanofiltration or reverse osmosis. For the first time, it is proposed to fabricate PSF membranes via ther...
A Facile and Environment-friendly Method for Fabrication of Polymer Brush
Xiao-min Kang , Wan-hao Cai , Hong-gang Gu , Shi-yuan Liu , Shu-xun Cui
2017, 35(7): 857-865  doi: 10.1007/s10118-017-1934-5
[Abstract](726) [FullText HTML] [PDF 0KB](0)
Abstract:
A novel environment-friendly system is proposed to fabricate polymer brush, which has the advantages including non-toxic and inexpensive initiator (eosin Y), visible-light exposure (λ= 515 nm), water medium and ambient environment. The experimental r...
Synthesis of Isotactic Polystyrene-block-Polyethylene by the Combination of Sequential Monomer Addition and Hydrogenation of 1, 4-Trans-polybutadiene Block
Hua-qing Liang , Qi-hua Zhou , Yong-jiang Long , Wan-chu Wei , Guo-dong Liang , Qing Wu , Hai-yang Gao , Fang-ming Zhu
2017, 35(7): 866-873  doi: 10.1007/s10118-017-1933-6
[Abstract](742) [FullText HTML] [PDF 0KB](0)
Abstract:
Herein, we demonstrate the synthesis of a well-defined diblock copolymer consisting of isotactic polystyrene (iPS) and linear polyethylene, isotactic polystyrene-block-polyethylene (iPS-b-PE), by the combination of sequential monomer addition and hyd...
Phase Behavior and Interfacial Properties of Diblock CopolymerHomopolymer Ternary Mixtures: Influence of Volume Fraction of Copolymers and Interaction Energy
Jian Wang , Jian-hui Song , Yu-yuan Lu , Yong-jin Ruan , Li-jia An
2017, 35(7): 874-886  doi: 10.1007/s10118-017-1915-8
[Abstract](759) [FullText HTML] [PDF 0KB](0)
Abstract:
We use a Monte Carlo method to study the phase and interfacial behaviors of A-b-B diblocks in a blend of homopolymers, A and B, which are confined between two asymmetric hard and impenetrable walls. Our results show that, when the interaction strengt...
Fouling-resistant Behavior of Liquid-infused Porous Slippery Surfaces
Dan Zhao , Xiao-dong Xu , Shuai-shuai Yuan , Shun-jie Yan , Xiang-hong Wang , Shi-fang Luan , Jing-hua Yin
2017, 35(7): 887-896  doi: 10.1007/s10118-017-1930-9
[Abstract](741) [FullText HTML] [PDF 0KB](0)
Abstract:
Marine economy is seriously affected by marine biofouling, which has plagued people for thousands of years. Although various strategies have been developed to protect artificial surfaces against marine biofouling, cost-effective biofouling-resistant ...
Layered Nanoparticles Modified by Chain End Functional PE and Their Nanocomposites with PE
Zhong-chuan Peng , Qian Li , Hua-yi Li , You-liang Hu
2017, 35(7): 897-908  doi: 10.1007/s10118-017-1931-8
[Abstract](706) [FullText HTML] [PDF 0KB](0)
Abstract:
Layered materials (MMT, LDH) were successfully modified by chain end functionalized polyethylene via an ion exchange method. The samples were characterized by using elemental analysis, Fourier transform infrared (FTIR) spectrum, X-ray diffraction (XR...
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