2017 Volume 35 Issue 1
2017, 35(1): 1-24
doi: 10.1007/s10118-017-1871-3
Abstract:
Structural DNA nanotechnology, an emerging technique that utilizes the nucleic acid molecule as generic polymer to programmably assemble well-defined and nano-sized architectures, holds great promise for new material synthesis and constructing functi...
Structural DNA nanotechnology, an emerging technique that utilizes the nucleic acid molecule as generic polymer to programmably assemble well-defined and nano-sized architectures, holds great promise for new material synthesis and constructing functi...
2017, 35(1): 25-35
doi: 10.1007/s10118-017-1869-x
Abstract:
A facile method to fabricate tough and highly stretchable polyacrylamide (PAM) nanocomposite physical hydrogel (NCP gel) was proposed. The hydrogels are dually crosslinked single network with the PAM grafted vinyl hybrid silica nanoparticles (VSNPs) ...
A facile method to fabricate tough and highly stretchable polyacrylamide (PAM) nanocomposite physical hydrogel (NCP gel) was proposed. The hydrogels are dually crosslinked single network with the PAM grafted vinyl hybrid silica nanoparticles (VSNPs) ...
2017, 35(1): 36-45
doi: 10.1007/s10118-017-1873-1
Abstract:
A series of cis-5-norbornene-endo-2,3-dicarboxylic anhydride (NDCA, M1) derivatives (M2-M4) with different types of nonpolar substituted groups were synthesized and characterized by 1H/13C-NMR and mass spectrometry (MS). Ring-opening metathesis polym...
A series of cis-5-norbornene-endo-2,3-dicarboxylic anhydride (NDCA, M1) derivatives (M2-M4) with different types of nonpolar substituted groups were synthesized and characterized by 1H/13C-NMR and mass spectrometry (MS). Ring-opening metathesis polym...
2017, 35(1): 46-53
doi: 10.1007/s10118-016-1857-6
Abstract:
The complexation between circular DNA and individual chains of PEO-b-P4VP with a relatively long PEO block and a short P4VP block is highly controllable when the interaction between DNA and the polymer is weak enough. When one circular DNA chain is t...
The complexation between circular DNA and individual chains of PEO-b-P4VP with a relatively long PEO block and a short P4VP block is highly controllable when the interaction between DNA and the polymer is weak enough. When one circular DNA chain is t...
2017, 35(1): 54-65
doi: 10.1007/s10118-016-1858-5
Abstract:
A series of well-defined core cross-linked star (CCS) polymeric ionic liquids (PILs) were synthesized via a three-step approach. First, the styrenic imidazole-based CCS polymer (S-PVBnIm) was prepared by the RAFT-mediated heterogeneous polymerization...
A series of well-defined core cross-linked star (CCS) polymeric ionic liquids (PILs) were synthesized via a three-step approach. First, the styrenic imidazole-based CCS polymer (S-PVBnIm) was prepared by the RAFT-mediated heterogeneous polymerization...
2017, 35(1): 66-77
doi: 10.1007/s10118-016-1859-4
Abstract:
The doubly thermo-responsive triblock copolymer nanoparticles of polystyrene-block-poly(N-isopropylacrylamide)-block-poly[N,N-(dimethylamino) ethyl methacrylate] (PS-b-PNIPAM-b-PDMAEMA) are successfully prepared through the seeded RAFT polymerization...
The doubly thermo-responsive triblock copolymer nanoparticles of polystyrene-block-poly(N-isopropylacrylamide)-block-poly[N,N-(dimethylamino) ethyl methacrylate] (PS-b-PNIPAM-b-PDMAEMA) are successfully prepared through the seeded RAFT polymerization...
2017, 35(1): 78-86
doi: 10.1007/s10118-017-1872-2
Abstract:
The influence of crystallization temperature (Tc) on the number of spiral growths on poly(butylene succinate) (PBS) single crystals, obtained by self-seeding method, was systematically studied. The studies show that the statistical average number of ...
The influence of crystallization temperature (Tc) on the number of spiral growths on poly(butylene succinate) (PBS) single crystals, obtained by self-seeding method, was systematically studied. The studies show that the statistical average number of ...
2017, 35(1): 87-97
doi: 10.1007/s10118-016-1856-7
Abstract:
Shape persistent conformations reduce the complexity of polymer materials. Herein, we propose a concept on the nanopolymer that is a nanoscale polymer chain with the repeat units of nanomonomers. In this article, a soluble organic nanopolymer of wide...
Shape persistent conformations reduce the complexity of polymer materials. Herein, we propose a concept on the nanopolymer that is a nanoscale polymer chain with the repeat units of nanomonomers. In this article, a soluble organic nanopolymer of wide...
2017, 35(1): 98-107
doi: 10.1007/s10118-017-1868-y
Abstract:
The self-consistent field theory has been employed to numerically study the response of bi-disperse flexible polyelectrolyte (PE) brushes grafted on an electrode to electric fields generated by opposite surface charges on the PE-grafted electrode and...
The self-consistent field theory has been employed to numerically study the response of bi-disperse flexible polyelectrolyte (PE) brushes grafted on an electrode to electric fields generated by opposite surface charges on the PE-grafted electrode and...
2017, 35(1): 108-122
doi: 10.1007/s10118-017-1880-2
Abstract:
The hierarchical crystalline morphologies and orientation structures across the thickness direction in high-density polyethylene (HDPE) molded bars were investigated via a novel melt-penetrating processing method named multi-melt multi-injection mold...
The hierarchical crystalline morphologies and orientation structures across the thickness direction in high-density polyethylene (HDPE) molded bars were investigated via a novel melt-penetrating processing method named multi-melt multi-injection mold...
2017, 35(1): 123-129
doi: 10.1007/s10118-017-1874-0
Abstract:
Controlled and homogeneous free-radical polymerization of acrylamide (AM) in aqueous phase was realized by using S,S'-bis(α,α'-dimethyl-α''-acetic acid)-trithiocarbonate as a reversible addition-fragmentation transfer (RAFT) agent. Linear increases i...
Controlled and homogeneous free-radical polymerization of acrylamide (AM) in aqueous phase was realized by using S,S'-bis(α,α'-dimethyl-α''-acetic acid)-trithiocarbonate as a reversible addition-fragmentation transfer (RAFT) agent. Linear increases i...
2017, 35(1): 130-140
doi: 10.1007/s10118-017-1887-8
Abstract:
Mg-Al mixed oxides with different Mg/Al molar ratio were prepared by thermal decomposition of hydrotalcite-like precursors at 500℃ for 5.0 h and used as catalysts for the transesterification of diphenyl carbonate with 1,4-butanediol to synthesize hig...
Mg-Al mixed oxides with different Mg/Al molar ratio were prepared by thermal decomposition of hydrotalcite-like precursors at 500℃ for 5.0 h and used as catalysts for the transesterification of diphenyl carbonate with 1,4-butanediol to synthesize hig...