2005 Volume 23 Issue 5

NUMERICAL SIMULATION OF MORPHOLOGY OF POLYMER CHAIN COILS IN COMPLEX FLOWS
Hong Zheng , Wei Yu , Chi-xing Zhou
2005, 23(5): 453-462
[Abstract](604) [FullText HTML] [PDF 0KB](0)
Abstract:
A new coupled finite element formulation is proposed to calculate a conformation tensor model in two complex flows: a planar contraction flow and a planar flow around a symmetrically placed cylinder. The components of conformation tensor are first co...
SYNTHESIS AND PROPERTIES OF ACRYLIC-BASED SUPERABSORBENT WITH ENHANCED CROSSLINKING ON PARTICLE SURFACE
Jian Huang , Zhi-ming Huang , Yong-zhong Bao , Zhi-xue Weng
2005, 23(5): 463-469
[Abstract](554) [FullText HTML] [PDF 0KB](0)
Abstract:
A series of acrylic-based superabsorbent resins were synthesized by inverse suspension polymerization, using potassium persulfate as the initiator, N, N-methylene bisacrylamide (BIS) and divinylbenzene (DVB) as the multiple crosslinking agents. The m...
PROPERTIES AND MORPHOLOGY OF UNSATURATED POLYESTER/ACRYLATE-TERMINATED POLYURETHANE/ORGANO-MONTMORILLONITE NANOCOMPOSITES
Chang-jiang You , Jin-guo Xu , Song Xi , Xiao-xia Duan , Jie Shen , De-min Jia
2005, 23(5): 471-478
[Abstract](526) [FullText HTML] [PDF 0KB](0)
Abstract:
Unsaturated polyester resin (UPR)/acrylate-terminated polyurethane (ATPU)/organo-modified montmorillonite (OMMT) nanocomposites were prepared by the in situ intercalative polymerization method. Samples were prepared by the sequential mixing, i.e. mix...
INFLUENCES OF ACID POST-TREATMENT ON THE MORPHOLOGY OF SOAP-FREE P(MMA-EA-MAA) PARTICLES PREPARED BY SEEDED EMULSION POLYMERIZATION
Kai Kang , Cheng-you Kan , Yi Du , De-shan Liu
2005, 23(5): 479-485
[Abstract](544) [FullText HTML] [PDF 0KB](0)
Abstract:
Soap-free poly(methyl methacrylate-ethyl acrylate-methacrylic acid) latex particles with narrow size distribution were synthesized by seeded emulsion polymerization, and the porous particles were created by a stepwise alkali/acid treatment method. Ef...
SYNTHESIS OF POLYMER-STABILIZED PLATINUM/RUTHENIUM BIMETALLIC COLLOIDS AND THEIR CATALYTIC PROPERTIES FOR SELECTIVE HYDROGENATION OF CROTONALDEHYDE
Wei-xia Tua , Han-fan Liu
2005, 23(5): 487-495
[Abstract](589) [FullText HTML] [PDF 0KB](0)
Abstract:
Polymer-stabilized platinum/ruthenium bimetallic colloids (Pt/Ru) were synthesized by polyol reduction with microwave irradiation and characterized by TEM and XPS. The colloidal nanoparticles have small and narrow size distributions. Catalytic perfor...
VARIATION OF PHYSICO-CHEMICAL PROPERTIES OF RADIATION CROSS-LINKED RUBBER WITH STORAGE TIME
N.C. Dafader , M.E. Haque , F. Akhtar
2005, 23(5): 497-501
[Abstract](556) [FullText HTML] [PDF 0KB](0)
Abstract:
The effect of storage on physico-chemical properties of non-irradiated natural rubber and radiation vulcanized natural rubber (RVNR) were evaluated. The rubber films were stored under two different conditions, namely in open air and sealed polyethyle...
BINARY COMPETITIVE AND COOPERATIVE ADSORPTION OF AROMATIC COMPOUNDS ON POLYMERIC RESINS
Wei-ming Zhang , Jin-long Chen , Bing-cai Pan , Quan-xing Zhang
2005, 23(5): 503-511
[Abstract](567) [FullText HTML] [PDF 0KB](0)
Abstract:
The adsorption behaviors of 2-naphthalenesulfonic acid and aniline on a conventional macroporous resin Amberlite XAD4 and the other two newly-developed hypercrosslinked resins NDA101 and NDA100 were investigated in a single or binary batch system at ...
THERMAL-SENSITIVE BETA-CYCLODEXTRIN-CONTAINED POLY(N-ISOPROPYLACRYLAMIDE) HYDROGELS CROSS-LINKED BY Si―O―Si BONDS
Jian-tao Zhang , Shi-wen Huang , Ya-nan Xue , Ji Liu , Ren-xi Zhuo
2005, 23(5): 513-519
[Abstract](546) [FullText HTML] [PDF 0KB](0)
Abstract:
A series of novel p(N-isopropylacrylamide) (PNIPAM) hydrogels were synthesized by radical copolymerization of N-isopropylacrylamide (NIPAM) and 3-methacryloxypropyltrimethoxysilane (MPTMS). The copolymers were then crosslinked through hydrolysis of t...
HETEROAROMATIC POLYMERS — HIGH TEMPERATURE POLYPYRROLONES DERIVED FROM 2,6-BIS(3',4'-DIAMINOPHENYL)-4-BIPHENYLPYRIDINE AND VARIOUS AROMATIC DIANHYDRIDES
Hai-xia Yang , Jin-gang Liu , Xiao-juan Zhao , Yan-feng Li , Lin Fan , Shi-yong Yang
2005, 23(5): 521-529
[Abstract](592) [FullText HTML] [PDF 0KB](0)
Abstract:
A new type of aromatic tetraamine containing biphenyl moiety in the side chain was synthesized via a modified Chichibabin’s reaction. 3-Nitro-4-acetamidoacetophenone was reacted with 4-phenyl benzaldehyde in the presence of ammonium acetate to obtain...
EFFECT OF PROCESSING METHOD ON THE IMPACT STRENGTH OF POM/TPU/CaCO3 TERNARY COMPOSITES
Xiao-ling Gao , Cheng Qu , Qin Zhang , Rong-ni Du , Qiang Fu
2005, 23(5): 531-537
[Abstract](549) [FullText HTML] [PDF 0KB](0)
Abstract:
Polyoxymethylene (POM)/elastomer/filler ternary composites were prepared, in which thermoplastic polyurethane (TPU) and inorganic filler, namely, CaCO3, were used to achieve balanced mechanical properties of POM. The dispersion and phase morphology o...
PREPARATION OF POLYETHERSULFONE ULTRAFILTRATION MEMBRANES FOR MILK CONCENTRATION AND EFFECTS OF ADDITIVES ON THEIR MORPHOLOGY AND PERFORMANCE
S.S. Madaeni , A. Rahimpour
2005, 23(5): 539-548
[Abstract](551) [FullText HTML] [PDF 0KB](0)
Abstract:
Polyethersulfone membranes were prepared from quaternary systems containing N,N-dimethylacetamide (DMAc) as solvent, polyvinylpyrrolidone (PVP) as constant additive and acetic acid, acetone and water as variable additives. Phase inversion via immersi...
SYNTHESIS OF MAIN CHAIN LIQUID CRYSTALLINE COPOLYESTERS WITH X-SHAPED TWO-DIMENSIONAL MESOGENIC UNIT AND CROWN ETHER CYCLE
Jing-wu Wang , Shi-jun Zheng , Xiao-hui Xu , Xing-qi Zhu , Shu-yuan Zhang , Tie-sheng Li , Zi-fa Li
2005, 23(5): 549-556
[Abstract](546) [FullText HTML] [PDF 0KB](0)
Abstract:
A novel series of main chain liquid crystalline copolyesters with X-shaped two-dimensional mesogenic unit and crown ether cycle of cis-4,4-bis(4-hydroxyphenylazo) dibenzo-18-crown-6 was prepared via solution condensation polymerization from 4,4-(a,w-...
INTERMOLECULAR AND INTRAMOLECULAR INTERACTIONS OF POLYMER GUAR GUM IN SOLUTIONS
Yun-fei Yan , Hai-yang Yang , Wen-yong Liu , Ping-ping Zhu , Ping-sheng He
2005, 23(5): 557-559
[Abstract](554) [FullText HTML] [PDF 0KB](0)
Abstract:
The tetrahedral borate ion can crosslink with polymer guar gum in aqueous solutions. If the concentration of guar gum is less than 0.045 g/dL, the intramolecular interaction between guar gum and borate ion increases due to the formation of crosslinks...
MICRO-PHASE SEPARATION IN EPOXY RESIN WATERBORNE PARTICLES DURING CURING PROCESS
Xi-yan Liu , Dong Qiu , Mei-li Guo , Zhen-zhong Yang
2005, 23(5): 561-566
[Abstract](524) [FullText HTML] [PDF 0KB](0)
Abstract:
Sub-micron sized phenolic epoxy resin waterborne particles were prepared by phase inversion emulsification. Micro-phase separation occurred during the curing process at high temperature. The as-prepared samples possessed one glass transition temperat...
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