2023 Volume 42 Issue 1

Recent progress on sulfide infrared nonlinear optical materials with large SHG response and wide band gap
Linan Wang , Qi Sun , Junjie Li
2023, 42(1): 100013  doi: 10.1016/j.cjsc.2023.100013
[Abstract](190) [FullText HTML] [PDF 0KB](0)
Abstract:
In this review, the progress of high-performance sulfide IR NLO materials since 2018 has been highlighted, and 13 cases of chalcogenides with balanced optical properties of SHG (≥ 1.0 × AGS) and band gap (≥ 3.0 eV) have been summarized and discussed in detail.
Recent advances in F-containing Iodate Nonlinear Optical Materials
Dong Gao , Hongping Wu , Zhanggui Hu , Jiyang Wang , Yicheng Wu , Hongwei Yu
2023, 42(1): 100014  doi: 10.1016/j.cjsc.2023.100014
[Abstract](184) [FullText HTML] [PDF 0KB](0)
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This paper summarizes the research achievements of F-containing NLO iodates reported until now, focusing on their crystal structures, NLO properties, and structure-property relationships. Meanwhile, various structure designing strategies for F-containing iodates with different valence center cations are also highlighted.
Deep-Ultraviolet Nonlinear-Optical Crystal BaNa2[PO3(OH)]2 with Large Birefringence and Strong Second-Harmonic-Generation Response
Yuanyu Yang , Yao Guo , Yi-Gang Chen , Chengbo Li , Xian-Ming Zhang
2023, 42(1): 100015  doi: 10.1016/j.cjsc.2023.100015
[Abstract](197) [FullText HTML] [PDF 0KB](0)
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Deep-ultraviolet nonlinear-optical crystal BaNa2[PO3(OH)]2 featuring two-dimensional [NaPO3(OH)]∞ alveolate layers can realize a good balance of nonlinear properties.
From Cs8Sb4Nb5O5F35 to Cs6Sb4Mo3O5F26: The First Noncentrosymmetric Fluoroantimonite with d0 Transition Metal
Jia-Hang Wu , Bo Zhang , Ting-Kun Jiang , Fang Kong , Jiang-Gao Mao
2023, 42(1): 100016  doi: 10.1016/j.cjsc.2023.100016
[Abstract](244) [FullText HTML] [PDF 0KB](0)
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Evaluating refractive index and birefringence of nonlinear optical crystals: Classical methods and new developments
Qi Shi , Lingyun Dong , Ying Wang
2023, 42(1): 100017  doi: 10.1016/j.cjsc.2023.100017
[Abstract](182) [FullText HTML] [PDF 0KB](0)
Abstract:
In this review, we describe how to obtain the refractive index and birefringence of NLO materials from crystals sub-millimeters to centimeters in size, and summarize the recently developed methods for rapid assessment of birefrin-gence. In addition, representative examples of birefringent measurements are also presented.
Compounds Consisting of Coplanar π-conjugated B3O6-typed Structures: An Emerging Source of Ultraviolet Nonlinear Optical Materials
Lingli Wu , Huixin Fan , Chensheng Lin , Min Luo
2023, 42(1): 100019  doi: 10.1016/j.cjsc.2023.100019
[Abstract](210) [FullText HTML] [PDF 0KB](0)
Abstract:
This review focuses on the NLO materials with B3O6-typed groups, and we roughly divide these groups into several categories, including cyanurates (HxC3N3O3)x-3 (x = 0-3), barbiturates (HxC3N3O3) x-3 (x = 2, 3), melamines (C3H7N6)+, (C5H6ON)+ and (C4H6N3)+ groups.
Recent Advances on the Synthesis of Sb(III)-Based Inorganic Ultraviolet Nonlinear Optical Materials
Gangji Yi , Guohong Zou
2023, 42(1): 100020  doi: 10.1016/j.cjsc.2023.100020
[Abstract](207) [FullText HTML] [PDF 0KB](0)
Abstract:
A brief summary on the synthesis of Sb(III)-based compounds is presented in this review, which includes flux method, solution reaction, hydrothermal synthesis, ionothermal synthesis and solvent-free synthesis.
Accurate Design and Synthesis of Nonlinear Optical Crystals Employing the KBe2BO3F2 as Structural Template
Tao Ouyang , Yaoguo Shen , Sangen Zhao
2023, 42(1): 100024  doi: 10.1016/j.cjsc.2023.100024
[Abstract](231) [FullText HTML] [PDF 0KB](0)
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It is still very challenging to realize accurate design and synthesis of second-order nonlinear optical (NLO) crystals and evaluate the overall performance of new ultraviolet NLO materials. We, from the perspective of microscopic crystal struc-ture based on KBBF, elaborate the accurate design and synthesis of high-performance NLO materials and analyze which atoms and groups can be replaced.
AIO3∙H6TeO6 (A=NH4, Rb): Two Telluric Acid and Iodate Co-Crystalline Compounds with Second Harmonic Generation Response
Shunye Yu , Yi Shui , Shuo Liu , Gan Huang , Canxiao Huang , Chunhui Geng , Lili Liu , Hongming Liu
2023, 42(1): 100025  doi: 10.1016/j.cjsc.2023.100025
[Abstract](194) [FullText HTML] [PDF 0KB](0)
Abstract:
The co-crystallization of telluric acid and iodate gives rise to two noncentrosymmetric crystals AIO3·H6TeO6 (A = Rb+, NH4+). They show different intensity of SHG responses due to the slight change of the orientation of [IO3] and [Te(OH)6] groups induced by different cations in A-site.
Polymorphism of LiCdBO3: Crystal Structures, Phase Transitions and Optical Characterizations
Qingxiong Liu , Qian Wu , Tianyu Wang , Lei Kang , Zheshuai Lin , Yonggang Wang , Mingjun Xia
2023, 42(1): 100026  doi: 10.1016/j.cjsc.2023.100026
[Abstract](212) [FullText HTML] [PDF 0KB](0)
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