2023 Volume 42 Issue 11

Pd-based nanocatalysts for oxygen reduction reaction: Preparation, performance, and in-situ characterization
Guan-Nan Xing , Di-Ye Wei , Hua Zhang , Zhong-Qun Tian , Jian-Feng Li
2023, 42(11): 100021  doi: 10.1016/j.cjsc.2023.100021
[Abstract](181) [FullText HTML] [PDF 0KB](0)
Abstract:
Electrochemical energy devices such as fuel cells have received extensive concern in recent decades. However, the commercial applications of fuel cells have been restricted by the slow kinetics of oxygen reduction reaction (ORR). Pd-based fuel cell c...
Mo doped Ru-based cluster to promote alkaline hydrogen evolution with ultra-low Ru loading
Haibin Yang , Duowen Ma , Yang Li , Qinghe Zhao , Feng Pan , Shisheng Zheng , Zirui Lou
2023, 42(11): 100031  doi: 10.1016/j.cjsc.2023.100031
[Abstract](211) [FullText HTML] [PDF 0KB](0)
Abstract:
Green hydrogen energy developed through electrochemistry is one of the solutions to current energy problems. The less noble metal ruthenium (Ru) plays an important role in alkaline electrocatalytic hydrogen evolution reaction (HER) as an effective el...
Revealing the reason for the unsuccessful fabrication of Li3Zr2Si2PO12 by solid state reaction
Zizhuo Liang , Fuming Du , Ning Zhao , Xiangxin Guo
2023, 42(11): 100108  doi: 10.1016/j.cjsc.2023.100108
[Abstract](176) [FullText HTML] [PDF 0KB](0)
Abstract:
NASICON type Li3Zr2Si2PO12 can be synthesized via cation exchange method with Na3Zr2Si2PO12 as precursor, which retains the skeleton structure and achieves an ionic conductivity higher than 3 mS cm-1 at room temperature. However, large-scale fabricat...
Metal-organic framework derived MnO@C/CNTs composite for high-rate lithium-based semi-solid flow batteries
Benjian Xin , Rui Wang , Lili Liu , Zhiqiang Niu
2023, 42(11): 100116  doi: 10.1016/j.cjsc.2023.100116
[Abstract](169) [FullText HTML] [PDF 0KB](0)
Abstract:
Lithium-based semi-solid flow battery (LSSFB) is expected to be applied in the field of large-scale energy storage. However, the rate performance of LSSFBs is unsatisfied due to the poor conductivity of active materials and the unstable contact with ...
Alloy nanocrystals: Synthesis paradigms and implications
Zhaojun Liu , Zerui Mu , Chuanbo Gao
2023, 42(11): 100156  doi: 10.1016/j.cjsc.2023.100156
[Abstract](205) [FullText HTML] [PDF 0KB](0)
Abstract:
In this perspective, we embark on a brief exploration of recent advancements in the synthesis of alloy nanocrystals, with a particular focus on enhancing compositional homogeneity and tunability. We discuss the progress made in typical synthesis para...
Depositing the PtNi nanoparticles on niobium oxide to enhance the activity and CO-tolerance for alkaline methanol electrooxidation
Xinyi Hu , Riguang Zhang , Zhao Jiang
2023, 42(11): 100157  doi: 10.1016/j.cjsc.2023.100157
[Abstract](179) [FullText HTML] [PDF 0KB](0)
Abstract:
Direct methanol fuel cells have the advantages of simple system, convenient operation, high conversion rate and low carbon emission, which are considered as the environmental and friendly energy conversion devices. However, the low activity, CO-toler...
Core-shell gold-copper nanoparticles: Evolution of copper shells on gold cores at different gold/copper precursor ratios
Shaonan Tian , Yu Zhang , Qing Zeng , Junyu Zhong , Hui Liu , Lin Xu , Jun Yang
2023, 42(11): 100160  doi: 10.1016/j.cjsc.2023.100160
[Abstract](170) [FullText HTML] [PDF 0KB](0)
Abstract:
Core-shell nanostructures usually exhibit tunable catalytic properties in comparison with their single core or shell counterpart due to electronic interaction and lattice strain between the core and shell regions. Herein, we report the intriguing evo...
Synergized oxygen vacancies with Mn2O3@CeO2 heterojunction as high current density catalysts for Li–O2 batteries
Renshu Huang , Jinli Chen , Xingfa Chen , Tianqi Yu , Huyi Yu , Kaien Li , Bin Li , Shibin Yin
2023, 42(11): 100171  doi: 10.1016/j.cjsc.2023.100171
[Abstract](176) [FullText HTML] [PDF 0KB](0)
Abstract:
The application of Li–O2 batteries (LOBs) with ultra-high theoretical energy density is limited due to the slow redox kinetics and serious side reactions, especially in high-rate cycles. Herein, CeO2 is constructed on the surface of Mn2O3 through an ...
Fluorinated metal-organic framework for methane purification from a ternary CH4/C2H6/C3H8 mixture
Ke-Ai Zhou , Lian Huang , Xing-Ping Fu , Li-Ling Zhang , Yu-Ling Wang , Qing-Yan Liu
2023, 42(11): 100172  doi: 10.1016/j.cjsc.2023.100172
[Abstract](184) [FullText HTML] [PDF 0KB](0)
Abstract:
Herein we present a fluorinated metal-organic framework of {(Me2NH2)[Ni3(μ3-OH)(CF3-BPDC-CF3)3(tpt)]}n (1) constructed from 2,2'-bis(trifluoromethyl)biphenyl-4,4'-dicarboxylic (CF3-BPDC-CF32-) and 2,4,6-tri(4-pyridyl)-1,3,5-triazine (tpt) ligands, wh...
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