2022 Volume 41 Issue 6

Preface to Solar Photocatalysis
Jiaguo Yu , Xin Li , Zhiliang Jin , Hua Tang , Enzhou Liu
2022, 41(6): 220600  doi: 10.14102/j.cnki.0254-5861.2022-0158
[Abstract](358) [FullText HTML] [PDF 390KB](3)
Abstract:
Molecular-level Engineering of S-scheme Heterojunction: the Site-specific Role for Directional Charge Transfer
Jianjun Zhang , Linxi Wang , Mitra Mousavi , Jahan B. Ghasemi , Jiaguo Yu
2022, 41(6): 220600  doi: 10.14102/j.cnki.0254-5861.2022-0150
[Abstract](448) [FullText HTML] [PDF 1135KB](9)
Abstract:
The promising S-scheme heterojunction photocatalysts are considered as a novel frontier due to their superiority in various solar-driven energy-related applications. Recently, a novel atom-specific tailoring strategy has been introduced on the constr...
Enhanced Photocatalytic H2-production Activity of CdS Nanoflower using Single Atom Pt and Graphene Quantum Dot as Dual Cocatalysts
Yi Yang , Jinsong Wu , Bei Cheng , Liuyang Zhang , Ahmed Abdullah Al-Ghamdi , Swelm Wageh , Youji Li
2022, 41(6): 220600  doi: 10.14102/j.cnki.0254-5861.2022-0124
[Abstract](429) [FullText HTML] [PDF 3180KB](9)
Abstract:
Single-atom catalysts have high catalytic activity due to their unique quantum size effects and optimal atom utilization. Herein, visible-light-responsive photocatalysts were designed by coupling CdS with graphene quantum dots (GQDs) and platinum sin...
S-scheme Porous g-C3N4/Ag2MoO4 Heterojunction Composite for CO2 Photoreduction
Zhongliao Wang , Ruilian Liu , Jinfeng Zhang , Kai Dai
2022, 41(6): 220601  doi: 10.14102/j.cnki.0254-5861.2022-0108
[Abstract](486) [FullText HTML] [PDF 2704KB](7)
Abstract:
Utilizing solar energy to achieve artificial photosynthesis of chemical fuel is prevalent in tackling excessive CO2 emission and fossil fuel depletion. Grievous charge recombination and weak redox capability aggravate the CO2 photoreduction performan...
Simultaneous Photocatalytic Oxygen Production and Hexavalent Chromium Reduction in Ag3PO4/C3N4 S-scheme Heterojunction
Tao Yang , Pengke Deng , Lele Wang , Jie Hu , Qinqin Liu , Hua Tang
2022, 41(6): 220602  doi: 10.14102/j.cnki.0254-5861.2022-0062
[Abstract](523) [FullText HTML] [PDF 3738KB](9)
Abstract:
The low separation/migration efficiency is a major obstacle that limits the practical application of semiconductor-photocatalysts. Constructing S-scheme heterojunction is an ideal strategy for providing high photocatalytic activity via accelerating c...
Pyrene-benzothiadiazole-based Polymer/CdS 2D/2D Organic/Inorganic Hybrid S-scheme Heterojunction for Efficient Photocatalytic H2 Evolution
Ruiqi Gao , Huan He , Junxian Bai , Lei Hao , Rongchen Shen , Peng Zhang , Youji Li , Xin Li
2022, 41(6): 220603  doi: 10.14102/j.cnki.0254-5861.2022-0096
[Abstract](1310) [FullText HTML] [PDF 2904KB](50)
Abstract:
Nowadays, conjugated polymers have garnered numerous attention as a new class of organic photocatalysts due to their tunable electronic properties, low cost, excellent stability and sufficient light-absorption performance. In particular, pyrene-benzo...
Ag2S Quantum Dots Decorated on Porous Cubic-CdS Nanosheets-assembled Flowers for Photocatalytic CO2 Reduction
Wei Fu , Jiajie Fan , Quanjun Xiang
2022, 41(6): 220603  doi: 10.14102/j.cnki.0254-5861.2022-0090
[Abstract](295) [FullText HTML] [PDF 3214KB](3)
Abstract:
The production of renewable fossil fuels such as CH4 and CO by photocatalytic CO2 reduction has attracted more and more attention. However, single photocatalyst is less efficient for photocatalytic reduction of CO2 due to the fast recombination of ph...
Molecular Engineering of g-C3N4 with Dibenzothiophene Groups as Electron Donor for Enhanced Photocatalytic H2-Production
Shanren Tao , Sijie Wan , Qinyang Huang , Chengming Li , Jiaguo Yu , Shaowen Cao
2022, 41(6): 220604  doi: 10.14102/j.cnki.0254-5861.2022-0068
[Abstract](419) [FullText HTML] [PDF 2542KB](10)
Abstract:
The construction of donor-acceptor (D-A) molecular structure is an attractive strategy to enhance the photocatalytic performance of polymeric semiconductors. Herein, dibenzothiophene (DBT)-4-carbaldehyde as the precursor is introduced into g-C3N4 (TC...
Asymmetric Structure Awakened n-π* Electron Transition in Sulfur and Selenium Co-doped g-C3N4 with Efficient Photocatalytic Performance
Tian Liu , Yunfeng Li , Hejia Sun , Min Zhang , Zhiling Xia , Qing Yang
2022, 41(6): 220605  doi: 10.14102/j.cnki.0254-5861.2022-0152
[Abstract](327) [FullText HTML] [PDF 3097KB](6)
Abstract:
Sulfur and selenium co-doped graphitic carbon nitride (SSCN) with efficient photocatalytic activity was synthesized by synchronously introducing sulfur and selenium atoms into the melon structure of g-C3N4 (GCN) via a facile solid-phase thermal react...
K2HPO4-mediated Photocatalytic H2 Production over NiCoP/RP Heterojunction
Junfeng Huang , Chenyang Li , Xiaoyun Hu , Jun Fan , Binran Zhao , Enzhou Liu
2022, 41(6): 220606  doi: 10.14102/j.cnki.0254-5861.2021-0055
[Abstract](418) [FullText HTML] [PDF 1597KB](10)
Abstract:
In this work, bimetallic NiCoP nanoparticles (NPs) were firstly prepared by a solvothermal method using red phosphorus (RP) as P source, and it was combined with RP nanosheets via a physical grinding process. Investigation indicates that NiCoP has be...
Bi and S Co-doping g-C3N4 to Enhance Internal Electric Field for Robust Photocatalytic Degradation and H2 Production
Yan Hu , Xibao Li , Weiwei Wang , Fang Deng , Lu Han , Xiaoming Gao , Zhijun Feng , Zhi Chen , Juntong Huang , Fanyan Zeng , Fan Dong
2022, 41(6): 220606  doi: 10.14102/j.cnki.0254-5861.2022-0103
[Abstract](398) [FullText HTML] [PDF 3961KB](11)
Abstract:
By adjusting the type and proportion of doping elements in the g-C3N4-based photocatalyst, the internal electric field (IEF) strength of the semiconductor can be regulated. This can effectively enhance the driving force of charge separation in the ph...
Ingenious Design of CoAl-LDH p-n Heterojunction Based on CuI as Holes Receptor for Photocatalytic Hydrogen Evolution
Yue Cao , Hongqian Gou , Pengfei Zhu , Zhiliang Jin
2022, 41(6): 220607  doi: 10.14102/j.cnki.0254-5861.2022-0042
[Abstract](564) [FullText HTML] [PDF 1596KB](11)
Abstract:
Reasonable design of heterojunction can greatly improve the photocatalytic hydrogen evolution activity of materials. Herein, p-n heterojunction of 2D/3D structure is constructed by the nanosheet of CoAl-LDH and rock-like CuI. The introduction of CuI ...
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