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2016 Volume 37 Issue 1
2016, 37(1): 1-2
doi: 10.1016/S1872-2067(15)61027-0
Abstract:
2016, 37(1): 3-15
doi: 10.1016/S1872-2067(15)60901-9
Abstract:
ZrO2-based mixed metal oxide catalysts for the industrially important dehydrogenation process of ethylbenzene to styrene monomer have been explored by our group for the past 20 years. These efforts were subjected to the activation of CO2 over mixed m...
ZrO2-based mixed metal oxide catalysts for the industrially important dehydrogenation process of ethylbenzene to styrene monomer have been explored by our group for the past 20 years. These efforts were subjected to the activation of CO2 over mixed m...
2016, 37(1): 16-26
doi: 10.1016/S1872-2067(15)60965-2
Abstract:
The benzene alkylation process for the production of ethylbenzene has undergone significant improvements during recent decades. Various environmentally benign zeolite-catalyzed ethylbenzene processes, including ZSM-5-zeolite-based vapor-phase ethylbe...
The benzene alkylation process for the production of ethylbenzene has undergone significant improvements during recent decades. Various environmentally benign zeolite-catalyzed ethylbenzene processes, including ZSM-5-zeolite-based vapor-phase ethylbe...
2016, 37(1): 27-31
doi: 10.1016/S1872-2067(15)61026-9
Abstract:
Three-dimensional (3D) ordered mesoporous MnO2 was prepared using KIT-6 mesoporous molecular sieves as a hard template. The material was used for catalytic oxidation of HCHO. The material has high surface areas and the mesoporous characteristics of t...
Three-dimensional (3D) ordered mesoporous MnO2 was prepared using KIT-6 mesoporous molecular sieves as a hard template. The material was used for catalytic oxidation of HCHO. The material has high surface areas and the mesoporous characteristics of t...
2016, 37(1): 32-42
doi: 10.1016/S1872-2067(15)60909-3
Abstract:
Mesoporous LaMnO3 perovskite catalysts with high surface area were synthesized by using the recently developed hard templating method designated as “nanocasting”. Ordered mesoporous silica designated as SBA-15 was used as the hard template. It was fo...
Mesoporous LaMnO3 perovskite catalysts with high surface area were synthesized by using the recently developed hard templating method designated as “nanocasting”. Ordered mesoporous silica designated as SBA-15 was used as the hard template. It was fo...
2016, 37(1): 43-53
doi: 10.1016/S1872-2067(15)60878-6
Abstract:
The deposition onto an ordered mesoporous carbon (OMC) support of well dispersed PtM (M = Ru, Fe, Mo) alloy nanoparticles (NPs) were synthesized by a direct replication method using SBA-15 as the hard template, furfuryl alcohol and trimethylbeneze as...
The deposition onto an ordered mesoporous carbon (OMC) support of well dispersed PtM (M = Ru, Fe, Mo) alloy nanoparticles (NPs) were synthesized by a direct replication method using SBA-15 as the hard template, furfuryl alcohol and trimethylbeneze as...
A Pd-metalated porous organic polymer as a highly efficient heterogeneous catalyst for C-C couplings
2016, 37(1): 54-60
doi: 10.1016/S1872-2067(15)60952-4
Abstract:
An efficient catalyst system based on a Pd-metalated porous organic polymer bearing phenanthroline ligands was designed and synthesized. This catalyst was applied to various C-C bond-forming reactions, including the Suzuki, Heck and Sonogashira coupl...
An efficient catalyst system based on a Pd-metalated porous organic polymer bearing phenanthroline ligands was designed and synthesized. This catalyst was applied to various C-C bond-forming reactions, including the Suzuki, Heck and Sonogashira coupl...
2016, 37(1): 61-72
doi: 10.1016/S1872-2067(15)60917-2
Abstract:
Simultaneously controlling the size of Au nanoparticles and immobilizing their location to specific active sites while hindering migration and sintering at elevated temperatures is a current challenge within materials chemistry. Typical methods requi...
Simultaneously controlling the size of Au nanoparticles and immobilizing their location to specific active sites while hindering migration and sintering at elevated temperatures is a current challenge within materials chemistry. Typical methods requi...
2016, 37(1): 73-82
doi: 10.1016/S1872-2067(15)60951-2
Abstract:
Recently, a one-pot self-assembly method was proposed for the synthesis of mesoporous Al2O3 and MOx-Al2O3 composite materials. However, few attempts have been made to use mesoporous MOx-Al2O3 composites to support metal oxides for catalysis. In the p...
Recently, a one-pot self-assembly method was proposed for the synthesis of mesoporous Al2O3 and MOx-Al2O3 composite materials. However, few attempts have been made to use mesoporous MOx-Al2O3 composites to support metal oxides for catalysis. In the p...
2016, 37(1): 83-90
doi: 10.1016/S1872-2067(15)60913-5
Abstract:
Developing efficient supported Pd catalysts and understanding their catalytic mechanism in CO oxidation are challenging research topics in recent years. This paper describes the synthesis of Pd nanoparticles supported on CeO2 nanotubes via an alcohol...
Developing efficient supported Pd catalysts and understanding their catalytic mechanism in CO oxidation are challenging research topics in recent years. This paper describes the synthesis of Pd nanoparticles supported on CeO2 nanotubes via an alcohol...
2016, 37(1): 91-97
doi: 10.1016/S1872-2067(15)60940-8
Abstract:
Ni@Pd core-shell nanoparticles with a mean particle size of 8-9 nm were prepared by solvothermal reduction of bivalent nickel and palladium in oleylamine and trioctylphosphine. Subsequently, the first-ever deposition of Ni@Pd core-shell nanoparticles...
Ni@Pd core-shell nanoparticles with a mean particle size of 8-9 nm were prepared by solvothermal reduction of bivalent nickel and palladium in oleylamine and trioctylphosphine. Subsequently, the first-ever deposition of Ni@Pd core-shell nanoparticles...
2016, 37(1): 98-101
doi: 10.1016/S1872-2067(15)61008-7
Abstract:
2016, 37(1): 102-122
doi: 10.1016/S1872-2067(15)61007-5
Abstract:
Formaldehyde (HCHO) is carcinogenic and teratogenic, and is therefore a serious danger to human health. It also adversely affects air quality. Catalytic oxidation is an efficient technique for removing HCHO. The development of highly efficient and st...
Formaldehyde (HCHO) is carcinogenic and teratogenic, and is therefore a serious danger to human health. It also adversely affects air quality. Catalytic oxidation is an efficient technique for removing HCHO. The development of highly efficient and st...
2016, 37(1): 123-134
doi: 10.1016/S1872-2067(15)61012-9
Abstract:
Flower-like 3D CuO microspheres were synthesized and used to photo-catalyze water oxidation under visible light. The structure of the CuO microspheres was characterized by scanning electron microscopy, transmission electron microscopy, infrared, powd...
Flower-like 3D CuO microspheres were synthesized and used to photo-catalyze water oxidation under visible light. The structure of the CuO microspheres was characterized by scanning electron microscopy, transmission electron microscopy, infrared, powd...
2016, 37(1): 135-145
doi: 10.1016/S1872-2067(15)61010-5
Abstract:
The degradation of 4-chloro-3-methylphenol (PCMC) using zeolite-encapsulated iron(III), nickel(II), and copper(II) complexes of N,N'-disalicylidene-1,2-phenylenediamine as catalysts, in a heterogeneous Fenton-like advanced oxidation process, was stud...
The degradation of 4-chloro-3-methylphenol (PCMC) using zeolite-encapsulated iron(III), nickel(II), and copper(II) complexes of N,N'-disalicylidene-1,2-phenylenediamine as catalysts, in a heterogeneous Fenton-like advanced oxidation process, was stud...
2016, 37(1): 146-152
doi: 10.1016/S1872-2067(15)61005-1
Abstract:
We demonstrate a superficial method for the synthesis of N-substituted 1,8-dioxo-decahydroacridines using β-cyclodextrin as a supramolecular, biodegradable, and reusable catalyst in aqueous medium. The reaction product is in excellent yield with mode...
We demonstrate a superficial method for the synthesis of N-substituted 1,8-dioxo-decahydroacridines using β-cyclodextrin as a supramolecular, biodegradable, and reusable catalyst in aqueous medium. The reaction product is in excellent yield with mode...
2016, 37(1): 153-158
doi: 10.1016/S1872-2067(15)61001-4
Abstract:
Mesoporous MCM-41 was used as a support for the uniform dispersion of ruthenium nanoparticles having an average particle size of ~5 nm. The obtained nanocomposite, MCM-41-Ru, was characterized using inductively coupled plasma, transmission electron m...
Mesoporous MCM-41 was used as a support for the uniform dispersion of ruthenium nanoparticles having an average particle size of ~5 nm. The obtained nanocomposite, MCM-41-Ru, was characterized using inductively coupled plasma, transmission electron m...
2016, 37(1): 159-168
doi: 10.1016/S1872-2067(15)60990-1
Abstract:
We prepared a novel nickel (II) hydroxide-modified carbon paste electrode (Ni(OH)2-X/CPE) for the electrocatalytic oxidation of formaldehyde. The electrode was prepared by a simple method without the use of linking chemicals. The prepared Ni(OH)2-X/C...
We prepared a novel nickel (II) hydroxide-modified carbon paste electrode (Ni(OH)2-X/CPE) for the electrocatalytic oxidation of formaldehyde. The electrode was prepared by a simple method without the use of linking chemicals. The prepared Ni(OH)2-X/C...
2016, 37(1): 169-176
doi: 10.1016/S1872-2067(15)60982-2
Abstract:
The growth mechanisms of carbon nanofibers on Ni catalysts and nitrogen-doped carbon nanofibers on Ni and Ni-Cu catalysts were studied. The growth of both types of nanofibers was found to occur by a mechanism that included the formation of surface no...
The growth mechanisms of carbon nanofibers on Ni catalysts and nitrogen-doped carbon nanofibers on Ni and Ni-Cu catalysts were studied. The growth of both types of nanofibers was found to occur by a mechanism that included the formation of surface no...
2016, 37(1): 177-183
doi: 10.1016/S1872-2067(15)60976-7
Abstract:
Lactic acid is produced as a major byproduct during sorbitol hydrogenolysis under alkaline conditions. We investigated the effects of two different alkaline additives, Ca(OH)2 and La(OH)3, on lactic acid formation during sorbitol hydrogenolysis over ...
Lactic acid is produced as a major byproduct during sorbitol hydrogenolysis under alkaline conditions. We investigated the effects of two different alkaline additives, Ca(OH)2 and La(OH)3, on lactic acid formation during sorbitol hydrogenolysis over ...
2016, 37(1): 184-192
doi: 10.1016/S1872-2067(15)60983-4
Abstract:
The effects of calcination temperature on the physicochemical properties of manganese oxide catalysts prepared by a precipitation method were assessed by X-ray diffraction, N2 adsorption-desorption, X-ray photoelectron spectroscopy, H2 temperature-pr...
The effects of calcination temperature on the physicochemical properties of manganese oxide catalysts prepared by a precipitation method were assessed by X-ray diffraction, N2 adsorption-desorption, X-ray photoelectron spectroscopy, H2 temperature-pr...
2016, 37(1): 193-198
doi: 10.1016/S1872-2067(15)60969-X
Abstract:
Low-temperature CO oxidation has attracted extensive interest in heterogeneous catalysis because of the potential applications in fuel cells, air cleaning, and automotive emission reduction. In the present study, theoretical investigations have been ...
Low-temperature CO oxidation has attracted extensive interest in heterogeneous catalysis because of the potential applications in fuel cells, air cleaning, and automotive emission reduction. In the present study, theoretical investigations have been ...
