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2015 Volume 36 Issue 4
2015, 36(4): 700-710
doi: 10.6023/cjoc201511008
Abstract:
As a kind of important three-carbon building block, vinamidinium salts have been widely used in organic synthesis. In this paper the synthetic methods of vinamidinium salts are summarized, and its applications in the synthesis of aldehydes, aromatic ...
As a kind of important three-carbon building block, vinamidinium salts have been widely used in organic synthesis. In this paper the synthetic methods of vinamidinium salts are summarized, and its applications in the synthesis of aldehydes, aromatic ...
2015, 36(4): 711-723
doi: 10.6023/cjoc201510002
Abstract:
Benzo[b][1, 4]diazepine derivatives is a class of benzo and seven-number heterocyclic compounds containing double nitrogen atoms. It was concerned for its special structural features, strong physiological and pharmacological activity. Therefore, the ...
Benzo[b][1, 4]diazepine derivatives is a class of benzo and seven-number heterocyclic compounds containing double nitrogen atoms. It was concerned for its special structural features, strong physiological and pharmacological activity. Therefore, the ...
2015, 36(4): 724-735
doi: 10.6023/cjoc201510022
Abstract:
Ocotillol-type saponins are a kind of tetracyclic triterpenoid ginsenoside with a tetrahydrofuran ring in the side chain. Ocotillol-type saponins mainly exist in panax plants and possess anti-inflammatory, antibacterial, morphine-antagonis-tic, neuro...
Ocotillol-type saponins are a kind of tetracyclic triterpenoid ginsenoside with a tetrahydrofuran ring in the side chain. Ocotillol-type saponins mainly exist in panax plants and possess anti-inflammatory, antibacterial, morphine-antagonis-tic, neuro...
2015, 36(4): 736-743
doi: 10.6023/cjoc201511011
Abstract:
Currently, the majority of the chemotherapy for type 2 diabetes mellitus (T2DM) functions through glycemic control by administration of oral or injectable hypoglycemic drugs. Though a range of anti-diabetic drugs with different modes of action have b...
Currently, the majority of the chemotherapy for type 2 diabetes mellitus (T2DM) functions through glycemic control by administration of oral or injectable hypoglycemic drugs. Though a range of anti-diabetic drugs with different modes of action have b...
2015, 36(4): 774-781
doi: 10.6023/cjoc201510028
Abstract:
A novel fluorescent dye naphthalene imide-fluorine boron two pyrrole 1-(2-(4-(1, 3, 5, 7-tetramethyl fluorine boron pyrrole)phenoxy)ethyl)-4-(4-N-butyl-1, 8-naphthalene imide)-1, 2, 3-triazole (NP-BODIPY) has been synthesized by Click reaction and ch...
A novel fluorescent dye naphthalene imide-fluorine boron two pyrrole 1-(2-(4-(1, 3, 5, 7-tetramethyl fluorine boron pyrrole)phenoxy)ethyl)-4-(4-N-butyl-1, 8-naphthalene imide)-1, 2, 3-triazole (NP-BODIPY) has been synthesized by Click reaction and ch...
2015, 36(4): 782-786
doi: 10.6023/cjoc201511009
Abstract:
Three chiral fluorescence chemosensors L-1, D-1 and L-2 based on acridine were synthesized. The structures of these compounds were characterized by IR, NMR and MS. The chiral recognition property of such sensors was studied by UV-vis and fluorescence...
Three chiral fluorescence chemosensors L-1, D-1 and L-2 based on acridine were synthesized. The structures of these compounds were characterized by IR, NMR and MS. The chiral recognition property of such sensors was studied by UV-vis and fluorescence...
2015, 36(4): 787-794
doi: 10.6023/cjoc201511016
Abstract:
Zinc ion (Zn2+) is one of the most important transition-metal ions in the human body which is involved in many important life activities and many diseases can be displayed by its situation. Thus, monitoring of Zn2+ is very meaningful to diagnosis of ...
Zinc ion (Zn2+) is one of the most important transition-metal ions in the human body which is involved in many important life activities and many diseases can be displayed by its situation. Thus, monitoring of Zn2+ is very meaningful to diagnosis of ...
2015, 36(4): 795-802
doi: 10.6023/cjoc201509002
Abstract:
Based on the combination principle, twelve novel oleanolic acid and ursolic acid derivatives were designed and synthesized through introduction of piperazine, N-methyl piperazine and morpholine moiety in C-28 position. Structures of all target compou...
Based on the combination principle, twelve novel oleanolic acid and ursolic acid derivatives were designed and synthesized through introduction of piperazine, N-methyl piperazine and morpholine moiety in C-28 position. Structures of all target compou...
2015, 36(4): 803-811
doi: 10.6023/cjoc201510008
Abstract:
Based on 10-methyl-10H-phenothiazine-5, 5-dioxide unit as an acceptor and 9, 10-dihydro-9, 9-dimethyl-acridine (DMAC) or phenoxazine (PXZ) as donors, four intramolecular charge transfer (ICT) compounds were designed and synthesized by Buchwald-Hartwi...
Based on 10-methyl-10H-phenothiazine-5, 5-dioxide unit as an acceptor and 9, 10-dihydro-9, 9-dimethyl-acridine (DMAC) or phenoxazine (PXZ) as donors, four intramolecular charge transfer (ICT) compounds were designed and synthesized by Buchwald-Hartwi...
2015, 36(4): 812-817
doi: 10.6023/cjoc201510038
Abstract:
A novel binaphthol-based monomer, 3-hydroxydiphenylmethyl-3'-vinyl-2, 2'-dihydroxy-1, 1'-binaphthyl was synthesized and polymerized using azodiisobutyrodinitrile (AIBN) as an initiator to afford the polymer P-5. Polarimetry, UV-Vis and circular dichr...
A novel binaphthol-based monomer, 3-hydroxydiphenylmethyl-3'-vinyl-2, 2'-dihydroxy-1, 1'-binaphthyl was synthesized and polymerized using azodiisobutyrodinitrile (AIBN) as an initiator to afford the polymer P-5. Polarimetry, UV-Vis and circular dichr...
2015, 36(4): 838-843
doi: 10.6023/cjoc201510010
Abstract:
An efficient method for the synthesis of benzopyran derivatives and pyrano[2, 3-c]pyrazole derivatives via multicomponent reaction in the presence of agarose hydrogel entrapped trisodium citrate (gel-citrate) as catalyst is developed. The protocol pr...
An efficient method for the synthesis of benzopyran derivatives and pyrano[2, 3-c]pyrazole derivatives via multicomponent reaction in the presence of agarose hydrogel entrapped trisodium citrate (gel-citrate) as catalyst is developed. The protocol pr...
2015, 36(4): 844-849
doi: 10.6023/cjoc201511029
Abstract:
A new ether-based benzoxazine monomer having a benzoyl moiety in the side chain is reported. This monomer showed good solubility in common organic solvents and low melting point ( < 125 ℃). Upon heating at high temperature, the monomer converted to a...
A new ether-based benzoxazine monomer having a benzoyl moiety in the side chain is reported. This monomer showed good solubility in common organic solvents and low melting point ( < 125 ℃). Upon heating at high temperature, the monomer converted to a...
2015, 36(4): 855-861
doi: 10.6023/cjoc201510030
Abstract:
Dibenzo-24-crown-8 (DB24C8) and dibenzylammonium (DBA) are always utilized for the construction of supramolecular assemblies. We reported a new kind supramolecular assembly polymer constructed by M1 which was synthesized from tetraphenylethene (TPE) ...
Dibenzo-24-crown-8 (DB24C8) and dibenzylammonium (DBA) are always utilized for the construction of supramolecular assemblies. We reported a new kind supramolecular assembly polymer constructed by M1 which was synthesized from tetraphenylethene (TPE) ...
2015, 36(4): 862-866
doi: 10.6023/cjoc201510027
Abstract:
A green and efficient protocol for the synthesis of phenols using recyclable chitosan@copper as catalyst was developed. Phenols can be obtained in moderate to excellent yields. The catalyst can be recycled and reused for five times without significan...
A green and efficient protocol for the synthesis of phenols using recyclable chitosan@copper as catalyst was developed. Phenols can be obtained in moderate to excellent yields. The catalyst can be recycled and reused for five times without significan...
2015, 36(4): 867-871
doi: 10.6023/cjoc201511023
Abstract:
We report selective detection of homocysteine (Hcy) through luminescent poly methyl vinyl ether-alt-maleic acid (PMVEM) silver nanoclusters (Ag NCs), which were synthesized using PMVEM as scaffold. The as-developed PMVEM-Ag NCs have two emission peak...
We report selective detection of homocysteine (Hcy) through luminescent poly methyl vinyl ether-alt-maleic acid (PMVEM) silver nanoclusters (Ag NCs), which were synthesized using PMVEM as scaffold. The as-developed PMVEM-Ag NCs have two emission peak...
