以梦为,诗“酒”趁年华
张天龙, 宋晨佳, 赵文敏, 汤宏胜, 李延, 李华
【大学化学】doi: 10.12461/PKU.DXHX202403076
酒,乃天地之精华,文化之载体,品一杯佳酿,如同品一段历史,品一份人生。白酒在各种场合中发挥着重要作用,它不仅仅是一种饮品,还寄托着人们对美好生活的向往和追求。本文采用生动形象的对话形式,通俗易懂地描述了白酒酿制的五个主要过程——选料、糖化、发酵、蒸馏和陈酿,重点介绍了其中的主要化学成分以及酿制过程中的化学反应,白酒的酿造过程体现了匠心独运的精神以及酒文化的博大精深。通过品味白酒,可以更好地感悟人生的哲理和智慧。好酒需要陈放才能更加醇香,人生也需要经历岁月的沉淀才能更加丰富多彩。
关键词: 白酒, 酿制, 科普, 化学物质
甘蓝色素稳定性研究
付世涛, 张剑鸣, 曹灿灿, 汪志慧, 秦超然, 张建, 熊辉
【大学化学】doi: 10.3866/PKU.DXHX202401059
本文以紫甘蓝蔬菜为原料,进行了pH、金属离子和各种食品添加剂等一系列稳定性分析,探索紫甘蓝色素的最佳存储和使用环境。研究表明,紫甘蓝色素对pH敏感,随着pH增大,色素保留率逐渐减小;不同金属离子对紫甘蓝色素的稳定性也有影响,Fe3+会破坏紫甘蓝色素的结构,降低稳定性,保留率仅为8.68%;而Ca2+能提高其稳定性。添加剂蔗糖也可提高其稳定性,其中20 g·L-1的蔗糖水溶液可将保留率提升至119.48%;而食盐、苯甲酸钠和山梨酸钾均会降低其稳定性。
关键词: 紫甘蓝色素, 影响因素, 稳定性
含甲基精单元的多酸杂化材料对β-氨基醇的高效催化合成
李梦洋, 徐昊, 牛中豪, 宫春华, 钟为慧, 谢景力
【无机化学学报】doi: 10.11862/CJIC.20250080
以1,1′-二甲基-4,4′-联吡啶(甲基紫精,MV)二氯化物和Keggin型多酸单元合成的晶态材料(MV)2[HPW2W10O40]·2H2O为催化剂,在无有机溶剂、室温条件下合成了一系列β-氨基醇类化合物。该催化剂不仅能够高效催化β-氨基醇的合成,而且具有良好的稳定性及可回收性。经过6次循环使用后,催化剂活性未出现明显下降,表明其具有较好的循环利用潜力。与传统方法相比,该反应体系不使用有机溶剂并具有反应条件温和、操作简单、环境友好等优点。
关键词: 紫精, 多酸, 催化应用, β-氨基醇
Syntheses, structures, photochromic and photocatalytic properties of two viologen-polyoxometalate hybrid materials
Huirong LIU, Hao XU, Dunru ZHU, Junyong ZHANG, Chunhua GONG, Jingli XIE
【无机化学学报】doi: 10.11862/CJIC.20240066
Two new viologen-polyoxometalate hybrid crystalline materials: (MV)2[HPW2W10O40] ·2H2O (1) and (EV)2[Mo8O26] (2) have been synthesized by using the cations of 1, 1'-dimethyl-4, 4'-bipyridinium dichloride (methyl viologen, MV) and 1, 1'-diethyl-4, 4'-bipyridinium dibromide (ethyl viologen, EV) as the electron acceptors, and the electron-rich polyoxometalate anions as the electron donors. The structures of compounds 1 and 2 have been determined by single-crystal X-ray crystallography. Hydrogen bond interactions exist between the cations and the anions in 1 and 2. Interestingly, 2 has a photochromic performance with a light response time within 1 min. The photochromic mechanism of compound 2 has been investigated by solid-state diffuse reflection, electron paramagnetic resonance and theoretical calculation. 1 and 2 show good catalytic performance in the photocatalytic degradation of several organic dyes (methylene blue, pararosaniline hydrochloride and rhodamine 6G).
关键词: viologen, polyoxometalate, photochromism, photocatalysis
A viologen‐based Cd(Ⅱ) coordination polymer: Self‐assembly, thermochromism, and electrochemical property
Xiaonan LI, Hui HAN, Yihan ZHANG, Jing XIONG, Tingting GUO, Juanzhi YAN
【无机化学学报】doi: 10.11862/CJIC.20240376
Under the condition of solvothermal synthesis, the viologen ligand 1, 1′‐bis(3‐carboxyphenyl)‐(4, 4′‐bipyri‐ dine) dichloride (H2bcbpy·2Cl) and KI are coordinated with the metal cadmium ions. A case of thermochromic coor‐ dination polymer [Cd(bcbpy)I2] ·2H2O (1) was constructed. Complex 1 displays a 1D chain structure and exhibits thermochromic behavior. Under different temperature stimulation, the complex (ground) slowly changed from green to yellow‐green, and with the increase of temperature, the color of complex 1 gradually deepened, and finally became orange‐yellow. Therefore, complex 1 was prepared as a thermochromic film. In addition, we also performed electrochemical tests on complex 1, which showed that the complex is a semiconductor material.
关键词: coordination polymer, viologen, thermochromism, electrochemical property

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