Ultrafine platinum clusters achieved by metal-organic framework derived cobalt nanoparticle/porous carbon: Remarkable catalytic performance in dehydrogenation of ammonia borane
Xinnan XIE, Boyu ZHANG, Jianxun YANG, Yi ZHONG, Younis Osama, Jianxiao YANG, Xinchun YANG
【无机化学学报】doi: 10.11862/CJIC.20250025
Ultrafine, highly dispersed Pt clusters were immobilized onto the Co nanoparticle surfaces by one-step pyrolysis of the precursor Pt(Ⅱ)-encapsulating Co-MOF-74. Owing to the small size effects of Pt clusters as well as the strongly enhanced synergistic interactions between Pt and Co atoms, the obtained Pt-on-Co/C400 catalysts exhibited excellent catalytic activity toward the hydrolysis of ammonia borane with an extremely high turnover frequency (TOF) value of 3 022 min-1 at 303 K. Durability test indicated that the obtained Pt-on-Co/C400 catalysts possessed high catalytic stability, and there were no changes in the catalyst structures and catalytic activities after 10 cycles.
关键词: ammonia borane, hydrogen generation, Pt cluster, porous carbon, metal-organic framework
仪器分析实验课程思政案例设计与实践——以气质联用实验为例
邵伟, 张万群, 朱平平, 胡万群, 周强, 李维维, 杨凯平, 王细胜
【大学化学】doi: 10.3866/PKU.DXHX202309048
中国科学技术大学化学国家级实验教学中心所开设的“仪器分析实验”为安徽省课程思政示范课程,在实验项目“气质联用法测定饮料中塑化剂含量”的教学过程中,课程组针对课程的特点和教学过程,对该项目进行思政示范教学案例设计。思政案例库的建设,有助于教师充分挖掘专业课程中的德育元素,激发学生的学习兴趣,培养学生的自主创新意识,取得了良好的教学效果。
关键词: 课程思政, 思政案例, 仪器分析, 质谱, 诺贝尔奖, 塑化剂, 食品安全

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