通过碱处理，优化了硅藻土(DIA)的孔隙结构，提高了孔隙率，增加了石蜡(paraffin)负载量。通过直接浸渍法制备了新型性状稳定的石蜡/碱改性DIA/膨胀石墨(EG-alDIAP)复合材料，并研究了其结构与性能的关系。结果表明，复合相变材料的石蜡负载量从47.4%提高到了61.1%，进而提高了复合材料的储热性能；向改性DIA中添加膨胀石墨(EG)提高了复合材料的传热能力，添加质量分数10% EG时导热系数提高了113%(从0.276 W·m^-1·K^-1提高到了0.589 W·m^-1·K^-1)。随着EG含量的升高，复合相变材料的相变潜热有所增加，但化学相容性、稳定性等无明显变化。含10% EG的石蜡/碱改性DIA复合材料具有可靠的储能性能、良好的温度调节性能和蓄放热能力。

Herein, a layered chiral coordination polymer, [Cd₂(D-cam)₂(2, 2'-bipy)₂]_n (Cd-CP), was synthesized using a solvothermal method with camphoric acid (D-H₂cam), 2, 2'-bipyridine (2, 2'-bipy) and Cd²⁺, and Tb³⁺@Cd-CP was in-situ synthesized introducing Tb³⁺ ions. The fluorescence experiments revealed that compared to Cd-CP, Tb³⁺@Cd-CP exhibited ultra-high fluorescence performance. The luminescence sensing performance demonstrated that Tb³⁺@Cd-CP could distinguish R/S-propylene glycol (R/S-PG) by fluorescence responses, with fluorescence quenching constant of 5.3×10³ and 2.0×10³ L·mol^-1 respectively and the enantioselectivity factor (α) of 2.65. Moreover, Tb³⁺@Cd-CP demonstrated limits of detection of 9.3 and 19.0 μmol·L^-1 for R-PG and S-PG, respectively, and showed good reproducibility.