A Novel Fused Phosphorus Heterocycle:4-(1', 2', 3', 4'-Tetrahydro-1, 3, 2-benzodiazaphosphorin-2'-sulfide)-3, 4b, 4a-thiazphosphaphenanthridine Derivative

Jun Min HUANG Hui CHEN Ru Yu CHEN

引用本文: Jun Min HUANG,  Hui CHEN,  Ru Yu CHEN. A Novel Fused Phosphorus Heterocycle:4-(1', 2', 3', 4'-Tetrahydro-1, 3, 2-benzodiazaphosphorin-2'-sulfide)-3, 4b, 4a-thiazphosphaphenanthridine Derivative[J]. Chinese Chemical Letters, 2002, 13(2): 125-128. shu
Citation:  Jun Min HUANG,  Hui CHEN,  Ru Yu CHEN. A Novel Fused Phosphorus Heterocycle:4-(1', 2', 3', 4'-Tetrahydro-1, 3, 2-benzodiazaphosphorin-2'-sulfide)-3, 4b, 4a-thiazphosphaphenanthridine Derivative[J]. Chinese Chemical Letters, 2002, 13(2): 125-128. shu

A Novel Fused Phosphorus Heterocycle:4-(1', 2', 3', 4'-Tetrahydro-1, 3, 2-benzodiazaphosphorin-2'-sulfide)-3, 4b, 4a-thiazphosphaphenanthridine Derivative

  • 基金项目:

    The project was supported by the National Natural Science Foundation of China and Foundation for University Key Teacher by the Ministry of Education.

摘要: The first example of fused phosphorus heterocyclic 4-[l'-(β-bromoethyl)-4'-oxo-3'-prop yl-1', 2', 3', 4-tetrahydro-1, 3, 2-benzodiazaphosphorin-2'-sulfide]-1, 2, 3, 4, 4a, 4b, 5, 6-octahydro-6-oxo-5-propyl-3, 4b, 4a-thiazphosphaphenanthridine 4a, 2'-dioxide was synthesized in excellent yield by refluxing a mixture of 1-(2-bromoethyt)-2, 3-dihydro-3-propyl-l, 3, 2-benzodiazaphos phorin-4(1H)-one 2-oxide with carbon disulfide in benzene in the presence of triethylamine.

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  • 收稿日期:  2001-06-11
通讯作者: 陈斌, bchen63@163.com
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