引用本文:
Huan Ming CHEN, Zhi Da MIN. SELECTIVE REDUCTION OF CLERODANE DITERPENOIDS[J]. Chinese Chemical Letters,
1996, 7(5): 411-414.
Citation: Huan Ming CHEN, Zhi Da MIN. SELECTIVE REDUCTION OF CLERODANE DITERPENOIDS[J]. Chinese Chemical Letters, 1996, 7(5): 411-414.
Citation: Huan Ming CHEN, Zhi Da MIN. SELECTIVE REDUCTION OF CLERODANE DITERPENOIDS[J]. Chinese Chemical Letters, 1996, 7(5): 411-414.
SELECTIVE REDUCTION OF CLERODANE DITERPENOIDS
摘要:
The α,β-unsaturated γ-lactones of neo-clerodane diterpenoids teucvidin,teupernin E and ajugacumbin A were selectively transformed into saturated γ-lactones and unsaturated diol derivatives with NaBH4.These transformations are of interest due to their selective reduction as compared with catalytic hydrogenation and LiAlH4 reduction of these diterpenoid compounds.
English
SELECTIVE REDUCTION OF CLERODANE DITERPENOIDS
Abstract:
The α,β-unsaturated γ-lactones of neo-clerodane diterpenoids teucvidin,teupernin E and ajugacumbin A were selectively transformed into saturated γ-lactones and unsaturated diol derivatives with NaBH4.These transformations are of interest due to their selective reduction as compared with catalytic hydrogenation and LiAlH4 reduction of these diterpenoid compounds.
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