引用本文:
Wen PEI, Chen SHEN. Heck Arylation of Cyclohexene Promoted by Ultrasonic and Micro wave in Ionic Liquid: a Novel Method of the Synthesis of 3-Naphthylcyclohexene[J]. Chinese Chemical Letters,
2006, 17(12): 1534-1536.
Citation: Wen PEI, Chen SHEN. Heck Arylation of Cyclohexene Promoted by Ultrasonic and Micro wave in Ionic Liquid: a Novel Method of the Synthesis of 3-Naphthylcyclohexene[J]. Chinese Chemical Letters, 2006, 17(12): 1534-1536.

Citation: Wen PEI, Chen SHEN. Heck Arylation of Cyclohexene Promoted by Ultrasonic and Micro wave in Ionic Liquid: a Novel Method of the Synthesis of 3-Naphthylcyclohexene[J]. Chinese Chemical Letters, 2006, 17(12): 1534-1536.

Heck Arylation of Cyclohexene Promoted by Ultrasonic and Micro wave in Ionic Liquid: a Novel Method of the Synthesis of 3-Naphthylcyclohexene
摘要:
Synthesis of 3-naphthylcyclohexene by the Heck reactions of bromonaphthalene and naphthyl triflates with cyclohexene catalyzed by palladiun and nickel complex (promoted by ultrasonic and microwave in ionic liquid of [bmim][BF4]) were performed with high yield and good regioselectivity. This method has advantages of environmentally benign, generality, simplicity and potential for recycling of ionic liquid and catalyat.
English
Heck Arylation of Cyclohexene Promoted by Ultrasonic and Micro wave in Ionic Liquid: a Novel Method of the Synthesis of 3-Naphthylcyclohexene
Abstract:
Synthesis of 3-naphthylcyclohexene by the Heck reactions of bromonaphthalene and naphthyl triflates with cyclohexene catalyzed by palladiun and nickel complex (promoted by ultrasonic and microwave in ionic liquid of [bmim][BF4]) were performed with high yield and good regioselectivity. This method has advantages of environmentally benign, generality, simplicity and potential for recycling of ionic liquid and catalyat.
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Key words:
- Naphthylcyclohexene
- / palladium and nickel complex
- / ionic liquid
- / Heck reaction
- / synthesis

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