引用本文:
Jing Song YOU, Xiao Qi YU, Xiao Ling ZHANG, Ru Gang XIE. Enantioselective Hydrolysis of α-Amino Acid Ester by Chiral Metallomicelles[J]. Chinese Chemical Letters,
1998, 9(4): 335-337.
Citation: Jing Song YOU, Xiao Qi YU, Xiao Ling ZHANG, Ru Gang XIE. Enantioselective Hydrolysis of α-Amino Acid Ester by Chiral Metallomicelles[J]. Chinese Chemical Letters, 1998, 9(4): 335-337.
Citation: Jing Song YOU, Xiao Qi YU, Xiao Ling ZHANG, Ru Gang XIE. Enantioselective Hydrolysis of α-Amino Acid Ester by Chiral Metallomicelles[J]. Chinese Chemical Letters, 1998, 9(4): 335-337.
Enantioselective Hydrolysis of α-Amino Acid Ester by Chiral Metallomicelles
摘要:
A series of chiral lipophilic Cu(Ⅱ) complexes were investigated as catalysts for the enantioselective hydrolysis of R(S)-p-nitrophenyl N-dodecanoyl-phenylalaninate in micelles. The highest enantioselectivity (kR/kS=7.81) was observed in a mixed micellar system composed of 1-Cu(Ⅱ) and Brij35.
English
Enantioselective Hydrolysis of α-Amino Acid Ester by Chiral Metallomicelles
Abstract:
A series of chiral lipophilic Cu(Ⅱ) complexes were investigated as catalysts for the enantioselective hydrolysis of R(S)-p-nitrophenyl N-dodecanoyl-phenylalaninate in micelles. The highest enantioselectivity (kR/kS=7.81) was observed in a mixed micellar system composed of 1-Cu(Ⅱ) and Brij35.
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Key words:
- micelle
- / chiral metallomicelle
- / enantioselective hydrolysis
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